Magnetodielectric Y-phase strontium hexagonal ferrite materials formed by sodium substitution

Patent metadata

Field	Value
Publication number	US-11551837-B2
Application number	US-202117203598-A
Country	US
Kind code	B2
Filing date	Mar 16, 2021
Priority date	Oct 24, 2014
Publication date	Jan 10, 2023
Grant date	Jan 10, 2023

Abstract

Disclosed herein are embodiments of an enhanced resonant frequency hexagonal ferrite material and methods of manufacturing. The hexagonal ferrite material can be Y-phase strontium hexagonal ferrite material. In some embodiments, sodium can be added into the crystal structure of the hexagonal ferrite material in order to achieve high resonance frequencies while maintaining high permeability.

First claim

What is claimed is:

1. A modified sodium substituted strontium hexagonal ferrite comprising:
a Y-phase strontium hexagonal ferrite crystal structure including elements strontium, sodium, cobalt, iron, oxygen and a trivalent ion, the trivalent ion configured to charge balance for the sodium substituting at least partially for the strontium in the crystal structure.

2. The modified sodium substituted strontium hexagonal ferrite of claim 1 wherein the trivalent ion is selected from the group consisting of Al, Ga, Sc, Cr, Mn, In, Yb, Er, Y and the other lanthanide elements.

3. The modified sodium substituted strontium hexagonal ferrite of claim 2 wherein the trivalent ion is scandium.

4. The modified sodium substituted strontium hexagonal ferrite of claim 1 wherein the modified sodium substituted strontium hexagonal ferrite has a composition Sr 1.75 Na 0.25 Co 1.75 M 0.25 Fe 12 O 22 , M being the trivalent ion selected from the group consisting of Al, Ga, Sc, Cr, Mn, In, Yb, Er, Y and the other lanthanide elements.

5. The modified sodium substituted strontium hexagonal ferrite of claim 1 wherein the modified sodium substituted strontium hexagonal ferrite has a composition Sr 1.5 Na 0.5 Co 0.5 M 0.5 Fe 12 O 22 , M being the trivalent ion selected from the group consisting of Al, Ga, Sc, Cr, Mn, In, Yb, Er, Y and the other lanthanide elements.

6. The modified sodium substituted strontium hexagonal ferrite of claim 1 wherein the composition of the Y-phase strontium hexagonal ferrite crystal structure is Sr 2-x Na x Co 2-x M x Fe 12 O 22 , M being the trivalent ion, 0<x≤1.5.

7. An antenna comprising:
a Y-phase strontium hexagonal ferrite crystal structure including elements strontium, sodium, cobalt, iron, oxygen and a trivalent ion, the trivalent ion configured to charge balance for the sodium substituting at least partially for the strontium in the crystal structure.

8. The antenna of claim 7 wherein the sodium substituted strontium hexagonal ferrite has a composition Sr 1.75 Na 0.25 Co 1.75 M 0.25 Fe 12 O 22 , M being the trivalent ion selected from the group consisting of Al, Ga, Sc, Cr, Mn, In, Yb, Er, Y and the other lanthanide elements.

9. The antenna of claim 7 wherein the sodium substituted strontium hexagonal ferrite has a composition Sr 1.5 Na 0.5 Co 0.5 M 0.5 Fe 12 O 22 , M being the trivalent ion selected from the group consisting of Al, Ga, Sc, Cr, Mn, In, Yb, Er, Y and the other lanthanide elements.

10. The antenna of claim 7 wherein the trivalent ion is incorporated into the crystal structure, the trivalent ion being scandium.

11. The antenna of claim 7 wherein the crystal structure contains the trivalent ion and greater than zero and less than or equal to 1.5 of the trivalent ion is included in the crystal structure.

12. The antenna of claim 7 wherein the trivalent ion is selected from the group consisting of Al, Ga, Sc, Cr, Mn, In, Yb, Er, Y and the other lanthanide elements.

13. The antenna of claim 7 wherein the composition of the Y-phase strontium hexagonal ferrite crystal structure is Sr 2-x Na x Co 2-x M x Fe 12 O 22 , M being the trivalent ion, 0<x≤1.5.

14. A modified sodium substituted strontium hexagonal ferrite comprising:
a Y-phase strontium hexagonal ferrite crystal structure including elements strontium, sodium, cobalt, iron, oxygen and a tetravalent ion, the tetravalent ion configured to charge balance for the sodium substituting at least partially for the strontium in the crystal structure.

15. The modified sodium substituted strontium hexagonal ferrite of claim 14 wherein the tetravalent ion is selected from the group consisting of Si, Ge, Ti, Zr, Sn, Ce, Pr, Hf, and Tb.

16. The modified sodium substituted strontium hexagonal ferrite of claim 14 , wherein the composition of the Y-phase strontium hexagonal ferrite crystal structure is Sr 2-2-2x Na 2x Co 2x N x Fe 12 O 22 , N being the tetravalent ion, 0<x≤0.75.

17. An antenna comprising:
a Y-phase strontium hexagonal ferrite crystal structure including elements strontium, sodium, cobalt, iron, oxygen and a tetravalent ion, the tetravalent ion configured to charge balance for the sodium substituting at least partially for the strontium in the crystal structure.

18. The antenna of claim 17 wherein the crystal structure contains the tetravalent ion and greater than zero and less than or equal to 0.75 of the tetravalent ion is included in the crystal structure.

19. The antenna of claim 17 wherein the tetravalent ion is selected from the group consisting of Si, Ge, Ti, Zr, Sn, Ce, Pr, Hf, and Tb.

20. The antenna of claim 17 wherein the composition of the Y-phase strontium hexagonal ferrite crystal structure is Sr 2-2-2x Na 2x Co 2x N x Fe 12 O 22 , N being the tetravalent ion, 0<x≤0.75.

Assignees

• Skyworks Solutions Inc

Inventors

• Hill Michael David

Classifications

• C04B2235/3244

  Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof · CPC title

• C04B2235/3232

  Titanium oxides or titanates, e.g. rutile or anatase · CPC title

• C04B35/622

  Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products · CPC title

• C04B2235/3213

  Strontium oxides or oxide-forming salts thereof · CPC title

• C04B2235/3217

  Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina · CPC title