Increased resonant frequency alkali-doped Y-phase hexagonal ferrites
US-10032547-B2 · Jul 24, 2018 · US
US10461436B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10461436-B2 |
| Application number | US-201615371521-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 7, 2016 |
| Priority date | Dec 11, 2015 |
| Publication date | Oct 29, 2019 |
| Grant date | Oct 29, 2019 |
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A hexagonal ferrite material includes a Y phase hexagonal ferrite material having the composition Sr 2 Co 2 Fe 12 O 22 or Sr 2-x Na x Co 2-x Sc x Fe 12 O 22 , 0<x<2, doped with a trivalent element, a tetravalent element, and/or a transition metal.
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What is claimed is: 1. A hexagonal ferrite material comprising a Y phase hexagonal ferrite material having the composition Sr 2-x Na x Co 2-x Sc x Fe 12 O 22 , 0<x<2, doped with up to 10 weight percent of a tetravalent element. 2. The hexagonal ferrite material of claim 1 wherein the tetravalent element substitutes for Fe 3+ ions on tetrahedral sites of the Y phase hexagonal ferrite material. 3. A hexagonal ferrite material comprising a Y phase hexagonal ferrite material having the composition Sr 2 Co 2 Fe 12 O 22 doped with up to 10 weight percent of a tetravalent element that substitutes for Fe 3+ ions on tetrahedral sites of the Y phase hexagonal ferrite material. 4. A hexagonal ferrite material comprising a Y phase hexagonal ferrite material having the composition Sr 2 Co 2 Fe 12 O 22 doped with up to 10 weight percent of a tetravalent element that is one of Si and Ge. 5. A hexagonal ferrite material comprising a Y phase hexagonal ferrite material having the composition Sr 2-x Na x Co 2-x Sc x Fe 12 O 22 , 0<x<2, doped with up to 10 weight percent of a transition metal or Zn. 6. The hexagonal ferrite material of claim 5 wherein the transition metal is one of Mn and Ni. 7. The hexagonal ferrite material of claim 6 wherein the transition metal or Zn substitutes for Co ions on octahedral sites of the Y phase hexagonal ferrite material. 8. A hexagonal ferrite material comprising a Y phase hexagonal ferrite material having the composition Sr 2 Co 2 Fe 12 O 22 doped with up to 10 weight percent of one or more of Nb, Ta, W, and Mo. 9. A hexagonal ferrite material comprising a Y phase hexagonal ferrite material having the composition Sr 2-x Na x Co 2-x Sc x Fe 12 O 22 , 0<x<2, doped with up to 10 weight percent of one or more of Nb, Ta, V, W and Mo. 10. The hexagonal ferrite material of claim 9 wherein the one or more of Nb, Ta, V, W, and Mo substitutes for one of Co ions and Fe ions in the Y phase hexagonal ferrite material. 11. A hexagonal ferrite material comprising a Y phase hexagonal ferrite material having the composition Sr 2 Co 2 Fe 12 O 22 doped with up to 10 weight percent of one of a trivalent dopant selected from the group including Sc, Mn, In, Cr, Ga, Co, Ni, Fe, Yb, or a lanthanide ion and a tetravalent dopant selected from the group consisting of Si, Ge, Ti, Zr, Sn, Ce, Pr, Hf, or Tb. 12. A hexagonal ferrite material comprising a Y phase hexagonal ferrite material having the composition Sr 2-x Na x Co 2-x Sc x Fe 12 O 22 , 0<x<2, doped with up to 10 weight percent of at least one of a trivalent dopant selected from the group including Sc, Mn, In, Cr, Ga, Co, Ni, Fe, Yb, or a lanthanide ion and a tetravalent dopant selected from the group consisting of Si, Ge, Ti, Zr, Sn, Ce, Pr, Hf, or Tb. 13. The material of claim 12 having a deviation from the Y-phase stoichiometry of between about zero and about five weight percent of one or more of Sr, Co, or Fe and and/or one or more of the dopant components. 14. The material of claim 12 wherein x is about 0.4. 15. The material of claim 14 having a quality factor of up to about 20 at about 1 GHz. 16. The material of claim 15 having a real permeability of greater than about four at about 1 GHz. 17. A radio frequency circuit element formed from the material of claim 16 . 18. The radio frequency circuit element of claim 17 including one or more of an antenna, a circulator, an isolator, and an inductor. 19. A radio frequency circuit module including the radio frequency circuit element of claim 17 . 20. An electronic device including the radio frequency circuit module of claim 19 .
Chromium oxides, chromates, or oxide-forming salts thereof · CPC title
Nickel oxides, nickalates, or oxide-forming salts thereof · CPC title
Zinc oxides, zincates, cadmium oxides, cadmiates, mercury oxides, mercurates or oxide forming salts thereof · CPC title
Hexagonal symmetry, e.g. beta-Si3N4, beta-Sialon, alpha-SiC or hexa-ferrites · CPC title
Manganese oxides, manganates, rhenium oxides or oxide-forming salts thereof, e.g. MnO · CPC title
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