Cryogenic air separation apparatus

Patent metadata

Field	Value
Publication number	US-11549747-B2
Application number	US-202016840065-A
Country	US
Kind code	B2
Filing date	Apr 3, 2020
Priority date	Apr 8, 2019
Publication date	Jan 10, 2023
Grant date	Jan 10, 2023

Abstract

A cryogenic air separation apparatus comprises: a heat exchanger, a first rectification column, a first condenser, a second rectification column, a third rectification column, a second condenser, a high-purity oxygen rectification column, a third condenser, a nitrogen compressor, and a compressed recycled gas line L 52 for introducing product nitrogen gas compressed by the first nitrogen compressor into a warm end (heat source) of an ultra-high-purity oxygen vaporizer as a compressed recycled gas.

First claim

What is claimed is:

1. A cryogenic air separation apparatus comprising:
a heat exchanger configured to subject feed air to heat exchange;
a first rectification column in fluid communication with the heat exchanger such that the first rectification column is configured to receive the feed air from the heat exchanger, said first rectification column comprising a first column bottom portion in which an oxygen-rich liquid is stored, a first rectification portion for rectifying the feed air, and a first column top portion which is disposed at an upper portion of the first rectification portion and stores a first vaporized gas;
a first condenser disposed above the first column top portion, the first condenser being configured to use the first vaporized gas in the first column top portion as a heat source;
a second rectification column comprising a second column bottom portion, an intermediate portion comprising a second rectification portion, and a second column top portion from which a first nitrogen gas is drawn;
a third rectification column configured to rectify argon that is in fluid communication with the intermediate portion of the second rectification column, said third rectification column comprising a third column bottom portion that is configured to receive a crude argon feed gas from the intermediate portion of the second rectification portion of the second rectification column, a third rectification portion configured to rectify the crude argon feed gas, and a third column top portion configured to store argon;
a second condenser disposed above the third column top portion and configured to use the argon in the third column top portion as a heat source;
a high-purity oxygen rectification column configured to rectify ultra-high-purity oxygen, said high-purity oxygen rectification column comprising: a high-purity oxygen column bottom portion having an ultra-high-purity oxygen vaporizer disposed in a lower region of the high-purity oxygen rectification column, an oxygen rectification portion that is configured to receive an oxygen-rich liquid drawn from an intermediate portion of the third rectification portion of the third rectification column, and a high-purity oxygen column top portion that is in fluid communication with the intermediate portion of the third rectification column, such that an oxygen vaporized gas can be sent from the high-purity oxygen column top portion to the intermediate portion of the third rectification portion of the third rectification column;
a third condenser disposed above the high-purity oxygen column top portion and configured to use the oxygen vaporized gas in the high-purity oxygen column top portion as a heat source;
a first nitrogen compressor configured to compress a second nitrogen gas drawn from an upper region of the third condenser and the first nitrogen gas drawn from the second column top portion of the second rectification column, after said second nitrogen gas and said first nitrogen gas have been made to pass through the heat exchanger; and
a compressed recycled gas line configured to introduce product nitrogen gas compressed by the first nitrogen compressor into a warm end of the ultra-high-purity oxygen vaporizer as a compressed recycled gas.

2. The cryogenic air separation apparatus according to claim 1 , further comprising a second nitrogen compressor for compressing the second nitrogen gas which is drawn from the upper region of the third condenser and has passed through the heat exchanger.

3. The cryogenic air separation apparatus according to claim 1 , wherein the third rectification column is divided into an upper crude argon column and a lower crude argon column at a point where the oxygen-rich liquid introduced into the ultra-high-purity oxygen rectification column is drawn.

4. The cryogenic air separation apparatus according to claim 1 , further comprising an expansion turbine for expanding at least one gas out of: a mixed gas comprising two or more gases from among a feed air gas, nitrogen gas recovered from the second rectification column, oxygen gas drawn from an upper portion of the first condenser, and waste gas discharged from any of the first rectification column, second rectification column or third rectification column; and nitrogen gas pressure-boosted by the first nitrogen compressor and/or the second nitrogen compressor.

5. The cryogenic air separation apparatus according to claim 1 , further comprising a supply line for supplying liquid nitrogen to the first rectification column or to the second rectification column as a cold source.

Assignees

• Air Liquide
• Lair Liquide Sa Pour Letude Et Lexploitation Des Procedes Geordes Claude

Inventors

• Hirose Kenji
• Tomita Shinji

Classifications

• F25J3/04709

  as an auxiliary column system in at least a dual pressure main column system · CPC title

• F25J3/04412

  in a classical double column flowsheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column · CPC title

• F25J2245/02

  Recycle of a stream in general, e.g. a by-pass stream · CPC title

• F25J2210/42

  Nitrogen · CPC title

• F25J3/04678

  cooled by oxygen enriched liquid from high pressure column bottoms · CPC title