System and method for recovery of neon and helium from an air separation unit

Patent metadata

Field	Value
Publication number	US-10408536-B2
Application number	US-201715695320-A
Country	US
Kind code	B2
Filing date	Sep 5, 2017
Priority date	Sep 5, 2017
Publication date	Sep 10, 2019
Grant date	Sep 10, 2019

Abstract

A system and method for neon recovery in a double column or triple column air separation unit is provided. The neon recovery system comprises a non-condensable stripping column configured to produce a liquid nitrogen-rich liquid column bottoms and a non-condensable gas containing overhead and one or more condensing units arranged to produce a crude neon vapor stream that contains greater than about 50% mole fraction of neon with the overall neon recovery exceeding 95%. In addition, there is minimal liquid nitrogen consumption and since much of the liquid nitrogen is recycled back to the lower pressure column of the air separation unit, there is minimal impact on the recovery of other products from the air separation unit.

First claim

What is claimed is:

1. A neon recovery system for an air separation unit, the air separation unit comprising a main air compression system, a pre-purification system, a heat exchanger system, and a rectification column system having a higher pressure column and a lower pressure column linked in a heat transfer relationship via a main condenser-reboiler, the neon recovery system comprising:
a non-condensable stripping column configured to receive a portion of a liquid nitrogen stream from the main condenser-reboiler and a stream of nitrogen rich shelf vapor from the higher pressure column, the non-condensable stripping column further configured to produce a liquid nitrogen column bottoms and a non-condensable gas containing overhead;
a stripping column condenser configured to receive the non-condensable gas containing overhead from the non-condensable stripping column and a first condensing medium, the stripping column condenser further configured to produce a first condensate that is released into or directed to the non-condensable stripping column and a first stream formed from the vaporization or partial vaporization of the first condensing medium; and
a neon upgrader configured to receive a non-condensable containing vent stream from the stripping column condenser and a second condensing medium, the neon upgrader further configured to produce a second condensate that is released into or directed to the non-condensable stripping column, a boil off stream formed from the vaporization or partial vaporization of the second condensing medium, and a crude neon vapor stream that contains greater than about 50% mole fraction of crude neon vapor;
wherein all or a portion of the liquid nitrogen column bottoms is subcooled to produce a subcooled liquid nitrogen stream and the second condensing medium is a portion of the subcooled liquid nitrogen stream.

2. The neon recovery system of claim 1 , wherein the crude neon vapor stream further contains greater than about 10% mole fraction of helium.

3. The neon recovery system of claim 1 , wherein the first condensing medium is a kettle boiling stream from the higher pressure column of the air separation unit.

4. The neon recovery system of claim 3 , wherein the first stream formed from the partial vaporization of the first condensing medium is directed to an argon condenser of the air separation unit.

5. The neon recovery system of claim 1 , wherein the first condensing medium is a kettle boiling stream from an argon condenser of the air separation unit.

6. The neon recovery system of claim 5 , wherein the first stream formed from the partial vaporization of the first condensing medium is directed to a phase separator configured to produce a vapor stream and a liquid stream that are returned to intermediate locations of the lower pressure column of the air separation unit.

7. The neon recovery system of claim 1 , wherein a first portion of the subcooled liquid nitrogen stream is directed to the neon upgrader as the second condensing medium and a second portion of the subcooled liquid nitrogen stream is directed to the lower pressure column of the air separation unit as a reflux stream.

8. The neon recovery system of claim 1 , wherein a first portion of the subcooled liquid nitrogen stream is directed to the neon upgrader as the second condensing medium; a second portion of the subcooled liquid nitrogen stream is directed to the lower pressure column as a reflux stream; and a third portion is taken as a liquid nitrogen product stream.

9. The neon recovery system of claim 1 , wherein the subcooled liquid nitrogen stream is subcooled via indirect heat exchange with a nitrogen column overhead of the lower pressure column of the air separation unit.

10. The neon recovery system of claim 1 , wherein the vapor portion of the boil off stream formed from the vaporization or partial vaporization of the second condensing medium is combined with a waste nitrogen stream of the air separation unit.

11. A method of recovering neon from an air separation unit, the air separation unit comprising a main air compression system, a pre-purification system, a heat exchanger system, and a rectification column system having a higher pressure column and a lower pressure column linked in a heat transfer relationship via a main condenser-reboiler, the method comprising the steps of:
directing a stream of liquid nitrogen from the main condenser-reboiler and a stream of nitrogen rich shelf vapor from the higher pressure column to a non-condensable stripping column configured to produce a liquid nitrogen column bottoms and a non-condensable gas containing overhead;
subcooling all or a portion of the liquid nitrogen column bottoms to produce a subcooled liquid nitrogen stream;
condensing nitrogen from the non-condensable gas containing overhead against a first condensing medium and a first portion of the subcooled liquid nitrogen stream in a stripping column condenser while vaporizing or partially vaporizing the first condensing medium to produce a first stream and also producing a non-condensable containing vent stream;
releasing or directing the condensed nitrogen from the stripping column condenser into the non-condensable stripping column;
condensing nitrogen from the non-condensable containing vent stream in a neon upgrader against a second condensing medium;
releasing or directing the condensed nitrogen from the neon upgrader into the non-condensable stripping column; while vaporizing or partially vaporizing the second condensing medium to produce a boil off stream and also producing a crude neon vapor stream that contains greater than about 50% mole fraction of crude neon vapor.

12. The method of recovering neon of claim 11 , wherein the crude neon vapor stream further contains greater than about 10% mole fraction of helium.

13. The method of recovering neon of claim 11 , further comprising the step of directing a kettle boiling stream from the higher pressure column of the air separation unit to the stripping column condenser as the first condensing medium.

14. The method of recovering neon of claim 13 , further comprising the step of directing the first stream formed from the vaporization or partial vaporization of the first condensing medium to an argon condenser of the air separation unit.

15. The method of recovering neon of claim 11 , further comprising the step of directing a kettle boiling stream from an argon condenser of the air separation unit to the stripping column condenser as the first condensing medium.

16. The method of recovering neon of claim 15 , further comprising the steps of:
phase separating the first stream formed from the vaporization or partial vaporization of the first condensing medium to produce a vapor stream and a liquid stream; and
directing the vapor stream and the liquid stream to intermediate locations of the lower pressure column of the air separation unit.

17. The method of recovering neon of claim 11 , further comprising the step of directing a second portion of the subcooled liquid nitrogen stream to the lower pressure column of the air separation unit as a reflux stream.

18. The method of recovering neon of claim 17 , further comprising the step of taking a third portion of the subcooled liquid nitrogen stream as a liquid nitrogen product stream.

19. The method of recovering neon of claim 11 , wherein the step of subcooling all or a portion of the liquid nitrogen column bottoms to produce the subcooled liquid nitrogen stream further comprises subcooling the liquid nitrogen column botto

Assignees

• Shelat Maulik R
• Tuo Hanfei
• Degenstein Nick J
• Dray James R
• Praxair Technology Inc

Inventors

• Shelat Maulik R
• Tuo Hanfei
• Degenstein Nick J
• Dray James R

Classifications

• F25J2250/10

  Boiler-condenser with superposed stages · CPC title

• F25J2250/02

  Bath type boiler-condenser using thermo-siphon effect, e.g. with natural or forced circulation or pool boiling, i.e. core-in-kettle heat exchanger · CPC title

• F25J2200/32

  using a side column fed by a stream from the high pressure column · CPC title

• F25J3/04872

  Vertical layout of cold equipments within in the cold box, e.g. columns, heat exchangers etc. · CPC title

• F25J3/04678

  cooled by oxygen enriched liquid from high pressure column bottoms · CPC title