Process for increasing low pressure pure nitrogen production by revamping original apparatus for cryogenic air separation

Patent metadata

Field	Value
Publication number	US-10508859-B2
Application number	US-201715817977-A
Country	US
Kind code	B2
Filing date	Nov 20, 2017
Priority date	Nov 25, 2016
Publication date	Dec 17, 2019
Grant date	Dec 17, 2019

Abstract

The object of the present invention is to provide a different solution for revamping existing producing apparatuses so as to increase the production of low pressure pure nitrogen while controlling as far as possible the capital and operation expenditures. The revamping solution comprises increasing the diameter and/or height of a pure nitrogen column to thereby improve the production capacity thereof; choosing to switch the conduits where the waste liquid nitrogen and pure liquid nitrogen are passed through in the subcooler according to the increment of the low pressure pure nitrogen production; adding an additional heat exchanger to conduct a heat exchange between a portion of the medium pressure air and the increased low pressure pure nitrogen; or simultaneously switching the main parts of the conduits which transfer the pure liquid nitrogen and waste liquid nitrogen from a first column of higher pressure to a second column of lower pressure while performing the above revamping. The stepwise revamping solution of the present invention can be used not only to control the cost but also increase the low pressure pure nitrogen production while ensuring a stable operation of the air separation unit.

First claim

What is claimed is:

1. A process of revamping an original apparatus for the separation of air by cryogenic distillation so as to increase the production of low pressure pure nitrogen, the original apparatus for the separation of air by cryogenic distillation comprising:
a. a first column operated under a first pressure and a second column operated under a relatively lower second pressure, a condensation evaporator disposed on top of the first column and an original pure nitrogen column connected to a top of the second column and having a smaller diameter than the second column,
b. a main compressor, an air purification and cooling system, a main heat exchanger, an expander and a conduit conveying system for compressing, purifying, and cooling feed air, and transferring said feed air to at least the first column,
c. a subcooler for indirect heat exchange between fluids to be cooled, which comprise an oxygen enriched liquid air, original waste liquid nitrogen and original pure liquid nitrogen produced from the first column and possibly pure liquid oxygen from the second column, and fluids to be warmed, which comprise the original low pressure pure nitrogen and original waste nitrogen produced from the second column, the subcooler comprising a first group of passages through which the original waste liquid nitrogen is passed and a second group of passages through which the original pure liquid nitrogen is passed, and the total heat exchange area of the first group of passages being greater than the total heat exchange area of the second group of passages,
d. a first conduit having a diameter D that transfers the original waste liquid nitrogen from the first column to the first group of passages in the subcooler and a second conduit having a diameter D′ that transfers the original waste liquid nitrogen from the first group of passages in the subcooler to an upper part of the second column as well as a third conduit having a diameter d that transfers the original pure liquid nitrogen from the first column to the second group of passages in the subcooler and a fourth conduit having a diameter d′ that transfers the original pure liquid nitrogen from the second group of passages in the subcooler to the top of original pure nitrogen column, wherein D>d, D′>d′,
wherein the process comprises the steps of:
substituting the original pure nitrogen column with a revamped pure nitrogen column having an increased diameter and/or height as compared to the original pure nitrogen column to thereby improve the production capacity of the low pressure pure nitrogen in the revamped pure nitrogen column and/or installing an additional pure nitrogen column in parallel to the original pure nitrogen column in order to improve the overall production capacity; and
physically switching the first and third conduits having diameters D and d at a hot end of the subcooler, and physically switching the second and fourth conduits having diameters D′ and d′ at a cold end of the subcooler, thereby allowing the pure liquid nitrogen after revamping to be passed through the first group of passages in the subcooler, and the waste liquid nitrogen after revamping to be passed through the second group of passages in the subcooler.

2. The revamping process according to claim 1 , further comprising the steps of:
adding an additional heat exchanger; and
dividing the low pressure pure nitrogen after revamping that has been warmed in the subcooler into two portions, with the first portion entering the cold end of the original main heat exchanger and the second portion entering the cold end of the additional heat exchanger, and also dividing the pressurized and purified air into two portions, with the first portion entering the hot end of the original main heat exchanger and the second portion entering the hot end of the additional heat exchanger, and being respectively subjected to indirect heat exchange with the first and second portions of the low pressure pure nitrogen after revamping.

3. The revamping process according to claim 1 , wherein during the step of physically switching the first and third conduits having diameters D and d at a hot end of the subcooler, and physically switching the second and fourth conduits having diameters D′ and d′ at a cold end of the subcooler
the waste liquid nitrogen from the first column after revamping is passed successively through the first conduit having a diameter D, the third conduit having a diameter d, the second group of passages in the subcooler, the fourth conduit having a diameter d′, a first throttle valve, the second conduit having a diameter D′, and finally to the upper part of the second column, and
the pure liquid nitrogen from the first column after revamping is passed successively through the third conduit having a diameter d, the first conduit having a diameter D, the first group of passages in the subcooler, the second conduit having a diameter D′, a second throttle valve, the fourth conduit having a diameter d′, and finally to the top of the pure nitrogen column.

4. The revamping process according to claim 3 , wherein the first and second conduits are switched at a distance of not less than 100 mm away from an outer surface of the first column, wherein the third and fourth conduits are switched at a distance of not less than 100 mm away from the second columns.

5. The revamping process according to claim 1 , wherein the first group of passages has: a) a larger number of passages; and/or b) a greater volume; and/or c) denser fins than the second group of passages in the subcooler.

6. A process for revamping an existing apparatus for the separation of air by cryogenic distillation so as to increase the production of low pressure pure nitrogen, the original apparatus for the separation of air by cryogenic distillation comprising:
a. a first column operated under a first pressure and a second column operated under a relatively lower second pressure, a condensation evaporator disposed on top of the first column and an original pure nitrogen column connected to a top of the second column and having a smaller diameter than the second column,
b. a main compressor, an air purification and cooling system, a main heat exchanger, an expander and a conduit conveying system for compressing, purifying, and cooling feed air, and transferring said feed air to at least the first column,
c. a subcooler for indirect heat exchange between fluids to be cooled, which comprise an oxygen enriched liquid air, a waste liquid nitrogen and a pure liquid nitrogen produced from the first column, and fluids to be warmed, which comprise a low pressure pure nitrogen and a waste nitrogen produced from the second column, the subcooler comprising a first group of passages through which a flow of the waste liquid nitrogen is passed and a second group of passages through which a flow of the pure liquid nitrogen is passed, wherein the first group of passages has a higher thermal capacity as compared to the second group of passages,
wherein the process comprises the steps of:
substituting the original pure nitrogen column with a revamped pure nitrogen column having an increased diameter and/or height as compared to the original pure nitrogen column to thereby improve the production capacity of the low pressure pure nitrogen in the revamped pure nitrogen column and/or installing an additional pure nitrogen column in parallel to the original pure nitrogen column in order to improve the overall production capacity; and
altering the flow of the waste liquid nitrogen and the pure liquid nitrogen such that the waste liquid nitrogen flows through the second group of passages instead of the first group of passages, and the pure liquid nitrogen flows through the first group of passages instead of the second group of passages.

Assignees

• Air Liquide

Inventors

• Cao jian-wei
• Zhao Xin

Classifications

• F25J3/04969

  Retrofitting or revamping of an existing air fractionation unit · CPC title

• F25J3/04787

  Heat exchange, e.g. main heat exchange line; Subcooler, external reboiler-condenser (F25J3/04793 and F25J3/0486 take precedence) · CPC title

• F25J3/04303

  Lachmann expansion, i.e. expanded into oxygen producing or low pressure column · CPC title

• F25J3/0423

  Subcooling of liquid process streams · CPC title

• F25J3/04218

  Parallel arrangement of the main heat exchange line in cores having different functions, e.g. in low pressure and high pressure cores (F25J3/04503 takes precedence) · CPC title