Process for preparing liquid hydrocarbons by the Fischer-Tropsch process integrated into refineries

Patent metadata

Field	Value
Publication number	US-11479728-B2
Application number	US-201917274647-A
Country	US
Kind code	B2
Filing date	Sep 11, 2019
Priority date	Sep 11, 2018
Publication date	Oct 25, 2022
Grant date	Oct 25, 2022

Abstract

The present invention relates to a process for preparing liquid hydrocarbons by the Fischer-Tropsch process integrated into refineries, in particular comprising recycling streams from the steam reforming hydrogen production process as the feedstock for the Fischer-Tropsch process.

First claim

The invention claimed is:

1. A process for preparing liquid hydrocarbons by the Fischer-Tropsch process integrated into refining units, wherein the process comprises recycling the gaseous stream from the steam-reforming hydrogen generation process as feedstock in the Fischer-Tropsch process, in which the carbon dioxide content is at least 20% and the hydrogen content is lower than 50% v/v; and wherein the gaseous stream from the steam-reforming hydrogen generation process is from the pressure swing absorption (PSA) section.

2. The process of claim 1 , wherein the gaseous stream from the steam-reforming hydrogen generation process is a purge gas stream comprising 25 to 35% hydrogen, 35 to 55% carbon dioxide, 10 to 30% methane, and 8 to 15% carbon monoxide.

3. The process of claim 2 , wherein the H 2 :CO ratio is of about 1.2 and about 5.5 mol/mol.

4. The process of claim 1 , wherein the Fischer-Tropsch process comprises:
compression of the feedstock, coming from the steam-reforming hydrogen generation process, with pressure lower than about 0.5 kgf/cm 2 (0.049 MPa) to about 4 to 40 kgf/cm 2 (0.39 MPA to 3.92 MPa),
feeding said compressed feedstock into a Fischer-Tropsch reactor and contact with a catalyst, and
optionally, separation of the liquid products obtained in an oleaginous stream, comprising liquid hydrocarbons, and an aqueous stream.

5. The process of claim 2 , wherein part of the uncompressed purge gas stream is sent to comprise the reformer fuel.

6. The process of claim 1 , wherein the unconverted residual gaseous fraction containing light hydrocarbons returns to the hydrogen generation process with the fuel from the reformer, or optionally, the unconverted residual gaseous fraction containing light hydrocarbons is sent to a light olefins recovery section.

7. The process of claim 4 , wherein the catalyst used in the Fischer-Tropsch reaction is selected from cobalt compounds based on alumina, titanium, aluminates, silica, zirconia, or mixtures thereof.

8. The process of claim 7 , wherein said catalyst additionally contains noble metals selected from Pt, Re or Ru as promoters.

9. The process of claim 4 , wherein the catalyst used in the Fischer-Tropsch reaction is selected from iron compounds containing, optionally, the promoters of silica, copper, noble metals and alkaline metals selected from potassium oxide, copper oxides, silica, zinc oxide, or a combination thereof.

10. The process of claim 4 , wherein the Fischer-Tropsch reactor is selected from slurry, fluidized, fixed-bed, or moveable bed-type reactors.

11. The process of claim 1 , wherein the Fischer-Tropsch reaction temperature is between about 180° C. and 300° C., and pressures between about 4 and 30 kgf/cm 2 (0.39 and 2.94 MPa).

12. The process of claim 1 , wherein the Fischer-Tropsch reaction temperature is between about 250° C. and 400° C.

13. The process of claim 1 , wherein the liquid hydrocarbons are gasoline, diesel, or lubricants.

14. The process of claim 1 , wherein the gaseous stream from the steam-reforming hydrogen generation process is from already-existing refining units.

15. The process of claim 4 , wherein the oleaginous stream containing liquid hydrocarbons obtained in the Fischer-Tropsch process are recycled into the existing refinery sections.

16. The process of claim 4 , wherein the aqueous stream generated in the Fischer-Tropsch process is recycled to an existing acid water unit of the refinery.

17. The process of claim 10 , wherein the Fischer-Tropsch reactor is a mili or micro-channel type compact reactor.

18. The process of claim 11 , wherein the Fischer-Tropsch reaction temperature is between about 190° C. and 250° C.

19. The process of claim 15 , wherein the oleaginous stream containing liquid hydrocarbons obtained in the Fischer-Tropsch process are recycled into distillation, hydrotreatment and effluent treatment sections.

Assignees

• Petroleo Brasileiro S A —Petrobras

Inventors

• Pontes Bittencourt Roberto Carlos

Classifications

• C10G2/00

  Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon · CPC title

• C01B3/48

  followed by reaction of water vapour with carbon monoxide · CPC title

• C01B2203/0233

  the reforming step being a steam reforming step · CPC title

• C10G2400/10

  Lubricating oil · CPC title

• C10G2/50

  from carbon dioxide with hydrogen · CPC title