Method for start-up and operation of a Fischer-Tropsch reactor

Patent metadata

Field	Value
Publication number	US-9822312-B2
Application number	US-201515126364-A
Country	US
Kind code	B2
Filing date	Mar 16, 2015
Priority date	Mar 17, 2014
Publication date	Nov 21, 2017
Grant date	Nov 21, 2017

Abstract

The invention relates to a method for start-up and operation of a Fischer-Tropsch reactor comprising the steps of: (a) providing a reactor with a fixed bed of reduced Fischer-Tropsch catalyst that comprises cobalt as catalytically active metal; (b) supplying a gaseous feed stream comprising carbon monoxide and hydrogen to the reactor, wherein the gaseous feed stream initially comprises a nitrogen-containing compound other than molecular nitrogen in an initial concentration in the range of from 0.1 to 50 ppmv based on the volume of the gaseous feed stream; (c) converting carbon monoxide and hydrogen supplied with the gaseous feed stream to the reactor into hydrocarbons at an initial reaction temperature, wherein the initial reaction temperature is set at a value of at least 200° C. and hydrocarbons are produced at a first yield; (d) maintaining the initial reaction temperature at the set value and maintaining the first yield by decreasing the concentration of the nitrogen-containing compound in the gaseous feed stream supplied to the reactor; (e) optionally increasing the reaction temperature after the concentration of the nitrogen-containing compound in the gaseous feed stream has decreased to a value below 100 ppbv.

First claim

That which is claimed is:

1. A method for start-up and operation of a Fischer-Tropsch reactor comprising the steps of:
(a) providing a reactor with a fixed bed of reduced Fischer-Tropsch catalyst that comprises cobalt as catalytically active metal;
(b) supplying a gaseous feed stream comprising carbon monoxide and hydrogen to the reactor, wherein the gaseous feed stream initially comprises a nitrogen-containing compound selected from the group consisting of ammonia, HCN, NO, an amine and combinations or two or more thereof, in an initial concentration in the range of from 0.1 to 50 ppmv based on the volume of the gaseous feed stream;
(c) converting carbon monoxide and hydrogen supplied with the gaseous feed stream to the reactor into hydrocarbons at an initial reaction temperature, wherein the initial reaction temperature is set at a value of at least 200° C. and hydrocarbons are produced at a first yield;
(d) maintaining the initial reaction temperature at the set value and maintaining the first yield by decreasing the concentration of the nitrogen-containing compound in the gaseous feed stream supplied to the reactor;
(e) optionally increasing the reaction temperature after the concentration of the nitrogen-containing compound in the gaseous feed stream has decreased to a value below 100 ppbv.

2. A method according to claim 1 , wherein the catalyst is a fresh catalyst.

3. A method according to claim 1 , wherein the nitrogen-containing compound is ammonia.

4. A method according to claim 1 , wherein the initial reaction temperature is set at a value of at least 203° C.

5. A method according to claim 1 , wherein the initial concentration of the nitrogen-containing compound is in the range of from 0.2 to 20 ppmv.

6. A method according to claim 1 , wherein the concentration of the nitrogen-containing compound is gradually decreased in step (d).

7. A method according to claim 1 , wherein the reactor is provided with a fixed bed of reduced catalyst in step (a) by reducing a fixed bed of catalyst precursor in the reactor.

8. A method according to claim 7 , wherein the fixed bed of catalyst precursor is reduced by contacting the catalyst precursor with a hydrogen-containing gas comprising nitrogen or ammonia at a reduction temperature and pressure.

9. A method according to claim 8 , wherein the hydrogen-containing gas comprises in the range of from 1 to 60 vol % nitrogen.

10. A method according to claim 8 , wherein the hydrogen-containing gas comprises in the range of from 2 to 1,000 ppmv ammonia.

11. A method according to claim 1 , wherein the catalyst does not comprise a noble metal.

Assignees

• Shell Oil Co

Inventors

• Bezemer Gerrit Leendert
• Mesters Carolus Matthias Anna Maria
• Den Breejen Johan Peter

Classifications

• C10G2/341

  with stationary catalyst bed · CPC title

• C10G2300/4031

  Start up or shut down operations · CPC title

• B01J2219/00231

  at the reactor inlet · CPC title

• C10G2300/4006

  Temperature · CPC title

• B01J2208/00628

  Controlling the composition of the reactive mixture · CPC title