Production of xylenes from syngas

Patent metadata

Field	Value
Publication number	US-10053633-B2
Application number	US-201715722808-A
Country	US
Kind code	B2
Filing date	Oct 2, 2017
Priority date	Jul 24, 2014
Publication date	Aug 21, 2018
Grant date	Aug 21, 2018

Abstract

This disclosure relates to the production of xylenes from syngas, in which the syngas is converted to an aromatic product by reaction with a Fischer-Tropsch catalyst and an aromatization catalyst. The Fischer-Tropsch catalyst and aromatization catalyst may be different catalysts or combined into a single catalyst. The aromatic product is then subjected to selective alkylation with methanol and/or carbon monoxide and hydrogen to increase its p-xylene content.

First claim

The invention claimed is:

1. A catalyst system for the production of para-xylene comprising:
(a) a first catalyst comprising 1 to 50 wt. % Fe, and
(b) a second catalyst comprising at least one medium pore size molecular sieve and at least one metal or compound thereof, wherein the metal is selected from Groups 10-14 of the Periodic Table,
wherein the first and second catalysts are located within the same reactor bed, and
wherein the second catalyst is selectivated by contacting the second catalyst with steam at a temperature of at least 950° C. for about 10 minutes to 10 hours.

2. The catalyst system of claim 1 wherein the first and second catalysts are physically mixed in the same reactor bed.

3. The catalyst system of claim 1 wherein the first and second catalysts are combined into a single multi-functional catalyst.

4. The catalyst system of claim 1 , wherein the first catalyst comprises at least one support selected from the group consisting of zinc oxide, manganese oxide, alumina, silica, carbon, and mixtures thereof.

5. The catalyst system of claim 1 , wherein the second catalyst comprises at least one metal or compound thereof, wherein the metal is selected from the group consisting of Ga, In, Zn, Cu, Re, Mo, W, La, Fe, Ag, Pt, and Pd.

6. The catalyst system of claim 1 , wherein the metal of the second catalyst is present in an amount of about 0.1 to 10 wt %.

7. The catalyst system of claim 1 , wherein the second catalyst comprises silica-selectivated ZSM-5.

8. The catalyst system of claim 1 , wherein first catalyst further comprises at least one stabilizer selected from an element or a compound thereof, wherein the element is selected from Groups 1 to 4 of the Periodic Table of the Elements.

9. The catalyst system of claim 8 , wherein the element from Groups 1 to 4 of the Periodic Table is selected from the group consisting of Cs, K, and Ca.

10. The catalyst system of claim 1 , wherein the second catalyst comprises at least one molecular sieve having a Constraint Index of 1-12.

11. The catalyst system of claim 1 , wherein the first catalyst further comprises 0.1 to 20 wt. % of Cu.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Beech Jr James H
• Soultanidis Nikolaos
• Silverberg Steven E

Classifications

• B01J23/34

  Manganese · CPC title

• C10G2400/30

  Aromatics · CPC title

• B01J29/48

  containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium · CPC title

• C07C2529/40

  of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 · CPC title

• B01J29/42

  containing iron group metals, noble metals or copper · CPC title