Method for manufacturing bacterium-produced cellulose carbon

Patent metadata

Field	Value
Publication number	US-11472707-B2
Application number	US-201917046993-A
Country	US
Kind code	B2
Filing date	Apr 15, 2019
Priority date	Apr 16, 2018
Publication date	Oct 18, 2022
Grant date	Oct 18, 2022

Abstract

There is provided a method for manufacturing a bacterium-produced cellulose carbon having a sufficient specific surface area, and a high mechanical strength. The method manufactures a bacterium-produced cellulose carbon by carbonizing cellulose produced by thermally treating, and the method includes a cellulose forming step S 1 of forming bacterium- produced cellulose whereby cellulose nanofibers are dispersed using a bacterium; an impregnating step S 2 for impregnating the bacterium-produced cellulose with a supercritical fluid; a drying step S 3 of vaporizing the supercritical fluid from the bacterium-produced cellulose containing the supercritical fluid and obtaining a dry product; and a carbonizing step S 4 of heating and carbonizing the dry product in an atmosphere not causing combustion of the dry product.

First claim

The invention claimed is:

1. A method for manufacturing a cellulose carbon from a starting cellulose material, the method comprising:
providing a starting cellulose material, wherein the starting cellulose material is produced by acetic acid bacteria and wherein nanofibers of the starting cellulose material are dispersed;
impregnating the starting cellulose material with a supercritical fluid to obtain an impregnated cellulose material, wherein the supercritical fluid comprises carbon dioxide, water, methane, ethane, propane, ethylene, propylene, methanol, ethanol, acetone, fluorine-based compounds, hydrofluoro ether, or combinations thereof, and wherein the supercritical fluid is in a supercritical state;
vaporizing the supercritical fluid from the impregnated cellulose material to obtain a dry product; and
carbonizing the dry product in an inert atmosphere, not causing combustion of the dry product, to obtain the cellulose carbon.

2. The method of claim 1 , further comprising: crushing the dry product.

3. The method of claim 2 , further comprising: crushing the starting cellulose material prior to impregnating the starting cellulose material; and mixing the crushed dry product and the crushed starting cellulose material.

4. The method of claim 3 , further comprising: removing a liquid from a mixture obtained by mixing the crushed dry product and the crushed starting cellulose material.

5. The method of claim 1 , wherein the cellulose nanofibers of the starting cellulose material have a diameter of 1 nm to 1 μm and a length of 10 or more times the diameter.

6. The method of claim 1 , wherein the starting cellulose material is provided in a gel disperse medium prior to impregnation with supercritical fluid, wherein the gel disperse medium comprises one or more of water (H2O), carboxylic acid, methanol (CH3OH), ethanol (C2H5OH), propanol (C3H7OH), n-butanol, isobutanol, n-butyl amine, dodecane, unsaturated fatty acid, ethylene glycol, heptane, hexadecane, isoamyl alcohol, octanol, isopropanol, acetone, or glycerine.

7. The method of claim 1 , wherein the cellulose carbon has a specific surface area of 300 m 2 /g or more.

8. The method of claim 1 , wherein the starting cellulose material is generated from Acetobacter bacteria.

9. The method of claim 1 , wherein the starting cellulose material is generated from Acetobacter xylinum subsp. sucrofermentans, Acetobacter xylinum ATCC23768, Acetobacter xylinum ATCC23769, Acetobacter pasteurianus ATCC10245, Acetobacter xylinum ATCC14851, Acetobacter xylinum ATCC11142, or Acetobacter xylinum ATCC10821.

10. The method of claim 1 , wherein vaporizing the supercritical fluid comprises reducing the pressure in a container in which the impregnated cellulose material is placed.

11. The method of claim 1 , wherein carbonizing the dry product comprises heating to a temperature of 500° C. to 2,000° C.

12. The method of claim 1 , wherein carbonizing the dry product comprises heating to a temperature of 900° C. to 1,800° C.

13. The method of claim 1 , wherein the inert atmosphere comprises nitrogen, argon, carbon dioxide, carbon monoxide, or combination thereof.

Assignees

• Nippon Telegraph & Telephone

Inventors

• Nohara Masaya
• Sakamoto Shuhei
• Iwata Mikayo
• Hayashi Masahiko
• Komatsu Takeshi

Classifications

• Y02P20/54

  using solvents, e.g. supercritical solvents or ionic liquids · CPC title

• C12P19/04

  Polysaccharides, i.e. compounds containing more than five saccharide radicals attached to each other by glycosidic bonds · CPC title

• C01B32/05 Primary

  Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30 · CPC title

• C12R2001/01

  Bacteria or Actinomycetales {; using bacteria or Actinomycetales} · CPC title

• C12N1/205

  Bacterial isolates · CPC title