Method of preparing minute carbonized cellulose and method of preparing catalyst support using the same

Patent metadata

Field	Value
Publication number	US-10276876-B2
Application number	US-201615285043-A
Country	US
Kind code	B2
Filing date	Oct 4, 2016
Priority date	Oct 5, 2015
Publication date	Apr 30, 2019
Grant date	Apr 30, 2019

Abstract

Disclosed is a method of manufacturing carbonized fine cellulose, which enables the formation of carbonized nano-sized cellulose by subjecting cellulose to drying, carbonization, and pulverization by means of shock waves using ultrasonic waves and microbubbles, thus realizing mass producibility, making it possible to fabricate a carbonized nano-sized material having uniform quality, and reducing the manufacturing costs. The carbonized fine cellulose is in the form of a nano-sized uniform carbon powder, and can thus be utilized as a catalyst support in various forms, such as fuel cell electrodes, electrodes of energy storage devices such as supercapacitors or secondary batteries, catalyst supports for micro-nano hybrid reactors, etc.

First claim

What is claimed is:

1. A method of manufacturing a carbonized fine cellulose, comprising:
preparing a cellulose sample (S 10 );
drying the cellulose sample (S 20 );
carbonizing the dried cellulose sample, thus forming a carbonized cellulose (S 30 );
mixing the carbonized cellulose with a fluid, thus obtaining a carbonized cellulose-mixed fluid (S 40 ); and
applying shock waves using ultrasonic waves and microbubbles to the carbonized cellulose-mixed fluid to pulverize the carbonized cellulose, thereby forming a carbonized nano-sized cellulose (S 50 ).

2. The method of claim 1 , further comprising loading a metal nano-catalyst on a surface of the carbonized nano-sized cellulose (S 60 ).

3. The method of claim 1 , further comprising inserting the carbonized nano-sized cellulose into microchannels in a carbonized cellulose fiber having a microchannel structure, thus forming a micro-nano catalyst support (S 70 ); and
loading a metal nano-catalyst on the micro-nano catalyst support (S 80 ).

4. The method of claim 1 , wherein the cellulose sample is selected from the group consisting of cotton, hemp, flax, jute, kenaf, henequen, Setaria viridis , acacia, pine, Ceramium kondoi, laver, Gelidium amansii, Pterocladiella capillacea, Acanthopeltis sp., Gracilaria verrucosa, Hypnea charoides, Ceramium boydenii, Gigartina tenella, Campylaephora hypnaeoides, Grateloupia filicina , wool, and silk.

5. The method of claim 1 , wherein the drying the cellulose sample (S 20 ) is performed using a lyophilization process.

6. The method of claim 1 , wherein the forming the carbonized cellulose (S 30 ) is performed through carbonization at a temperature ranging from 500 to 1500° C. in an inert gas atmosphere or is performed through primary carbonization at a temperature ranging from 500 to 700° C. in an inert gas atmosphere and secondary carbonization at a temperature ranging from 700 to 2000° C. in an inert gas atmosphere.

7. The method of claim 1 , wherein the fluid comprises at least one selected from the group consisting of acetone, acetyl glycol, isopropyl alcohol, hexane, dichloromethane, ethanol, methanol, hexadecane, dodecane, dimethylsulfoxide, benzene, xylene, methyl chloride, chloroform, toluene, and dimethylformamide.

8. The method of claim 2 , wherein the metal nano-catalyst is platinum, gold, silver, nickel, cobalt, ruthenium, palladium, or molybdenum.

Assignees

• Korea Institue Of Energy Res
• Korea Inst Energy Res

Inventors

• Kim Hee-Yeon
• Han Seong Ok
• Han In-Sub
• Kim Se-Young
• Seong Young-Hoon
• Seo Doo-Won
• Kwon Guk Hyeon

Classifications

• C01B32/15 Primary

  Nano-sized carbon materials · CPC title

• H01M4/9083

  on carbon or graphite · CPC title

• C10B53/02

  of cellulose-containing material (production of pyroligneous acid C10C5/00) · CPC title

• H01M4/926

  on carbon or graphite · CPC title

• C10B57/10

  Drying · CPC title