Cellulose derivative particles, cosmetic composition, and method for producing cellulose derivative particles

Patent metadata

Field	Value
Publication number	US-11434348-B2
Application number	US-202016818619-A
Country	US
Kind code	B2
Filing date	Mar 13, 2020
Priority date	Mar 22, 2019
Publication date	Sep 6, 2022
Grant date	Sep 6, 2022

Abstract

Cellulose derivative particles including an alkoxy group having 2 or more carbons or an acyl group having 3 or more carbons, wherein the cellulose derivative particles have an average particle size of 80 nm or greater and 100 μm or less, a sphericity of 70% or greater and 100% or less, and a surface smoothness of 80% or greater and 100% or less; and a total substitution degree of the cellulose derivative is 0.7 or greater and 3 or less.

First claim

The invention claimed is:

1. Cellulose derivative particles comprising an alkoxy group having 2 or more carbons or an acyl group having 3 or more carbons,
wherein the cellulose derivative particles have an average particle size of 80 nm or greater and 100 μm or less, a sphericity of 90% or greater and 100% or less, and a surface smoothness of 80% or greater and 100% or less; and
a total substitution degree of the cellulose derivative is 0.7 or greater and 3 or less.

2. The cellulose derivative particles according to claim 1 , wherein the total substitution degree of the cellulose derivative is 2.0 or greater and less than 2.6.

3. The cellulose derivative particles according to claim 2 , wherein the acyl group has 3 or more and 18 or less carbons.

4. The cellulose derivative particles according to claim 2 , wherein the alkoxy group has 2 or more and 8 or less carbons.

5. The cellulose derivative particles according to claim 2 , wherein a true specific gravity is 1.04 or greater.

6. The cellulose derivative particles according to claim 2 ,
wherein the cellulose derivative particles contain a plasticizer, and
a content of the plasticizer is greater than 0 wt. % and 40 wt. % or less relative to a weight of the cellulose derivative particles.

7. The cellulose derivative particles according to claim 1 , wherein the acyl group has 3 or more and 18 or less carbons.

8. The cellulose derivative particles according to claim 7 , wherein the alkoxy group has 2 or more and 8 or less carbons.

9. The cellulose derivative particles according to claim 7 , wherein a true specific gravity is 1.04 or greater.

10. The cellulose derivative particles according to claim 1 , wherein the alkoxy group has 2 or more and 8 or less carbons.

11. The cellulose derivative particles according to claim 10 , wherein a true specific gravity is 1.04 or greater.

12. The cellulose derivative particles according to claim 1 , wherein a true specific gravity is 1.04 or greater.

13. The cellulose derivative particles according to claim 1 ,
wherein the cellulose derivative particles contain a plasticizer, and
a content of the plasticizer is greater than 0 wt. % and 40 wt. % or less relative to a weight of the cellulose derivative particles.

14. The cellulose derivative particles according to claim 13 , wherein the plasticizer is a glycerin ester-based plasticizer.

15. A cosmetic composition containing the cellulose derivative particles according to claim 1 .

16. A method for producing cellulose derivative particles according to claim 1 , the method comprising the steps of:
mixing a plasticizer and a cellulose derivative having a total substitution degree of 0.7 or greater and 3 or less and containing an alkoxy group having 2 or more carbons or an acyl group having 3 or more carbons to obtain a cellulose derivative impregnated with the plasticizer;
kneading the cellulose derivative impregnated with the plasticizer and a water-soluble polymer at 200° C. or higher and 280° C. or lower to obtain a dispersion containing the water-soluble polymer as a dispersion medium and the cellulose derivative as a dispersoid; and
removing the water-soluble polymer from the dispersion,
wherein the water-soluble polymer is selected from the group consisting of polyvinyl alcohol, polyethylene glycol, sodium polyacrylate, polyvinylpyrrolidone, polypropylene oxide, polyglycerin, polyethylene oxide, vinyl acetate, modified starch, thermoplastic starch, methyl cellulose, ethyl cellulose, hydroxyethyl cellulose, and hydroxypropyl cellulose.

17. The method for producing cellulose derivative particles according to claim 16 ,
wherein the step of mixing the cellulose derivative and the plasticizer to obtain the cellulose derivate impregnated with the plasticizer is conducted by melt-kneading at a temperature in a range of 20° C. or higher and lower than 200° C.

18. The method for producing cellulose derivative particles according to claim 17 , wherein the plasticizer is a glycerin ester-based plasticizer.

19. The method for producing cellulose derivative particles according to claim 17 , wherein the plasticizer is triacetin.

20. The method for producing cellulose derivative particles according to claim 16 , wherein the water-soluble polymer is polyvinyl alcohol or thermoplastic starch.

Assignees

• Daicel Corp

Inventors

• Kobayashi Keiko
• Omura Masaya

Classifications

• C08J2429/04

  Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids · CPC title

• C08K5/103

  with polyalcohols · CPC title

• C08B11/193

  Mixed ethers, i.e. ethers with two or more different etherifying groups · CPC title

• C08L101/14

  the macromolecular compounds being water soluble or water swellable, e.g. aqueous gels · CPC title

• A61K2800/412

  Microsized, i.e. having sizes between 0.1 and 100 microns · CPC title