Agglomerated zeolite catalyst for cement slurry yield enhancement

Patent metadata

Field	Value
Publication number	US-11427745-B2
Application number	US-201916639820-A
Country	US
Kind code	B2
Filing date	Apr 17, 2019
Priority date	Apr 17, 2019
Publication date	Aug 30, 2022
Grant date	Aug 30, 2022

Abstract

A method of cementing may include preparing a cement composition comprising water, a hydraulic cement, and an agglomerated zeolite catalyst; placing the cement composition in a wellbore.

First claim

What is claimed is:

1. A method of cementing comprising:
preparing a cement composition comprising water, a hydraulic cement, and an agglomerated zeolite catalyst, wherein the agglomerated zeolite catalyst comprises a matrix, a filler, a binder, and zeolite crystals; and
placing the cement composition in a wellbore.

2. The method of claim 1 wherein the cement composition has a density of about 11 lb/gal (1318 kg/m 3 ) to about 16 lb/gal (1917 kg/m 3 ).

3. The method of claim 1 wherein the hydraulic cement is selected from the group consisting of Portland cements, pozzolana cements, gypsum cements, alumina based cements, silica cements, and any combination thereof.

4. The method of claim 1 wherein the agglomerated zeolite catalyst is a spent agglomerated zeolite catalyst, the spent agglomerated zeolite catalyst being a product of fluidized catalytic cracking.

5. The method of claim 1 wherein the matrix comprises type x, type y, ultra-stable type y, ZSM-5, SAPO-11, silicate-1, mordenite, ferrierite, beta, or combinations thereof.

6. The method of claim 1 wherein the agglomerated zeolite catalyst is present in an amount of about 1% to about 80% by weight of the cement composition.

7. A method of reducing a cement density comprising:
providing a cement composition comprising water and a hydraulic cement, the cement composition having an initial density;
adding additional water and an agglomerated zeolite catalyst to the cement composition until the cement composition reaches a target density, wherein the agglomerated zeolite catalyst comprises a matrix, a filler, a binder, and zeolite crystals; and
placing the cement composition in a wellbore.

8. The method of claim 7 wherein the hydraulic cement is selected from the group consisting of Portland cements, pozzolana cements, gypsum cements, alumina based cements, silica cements, and any combination thereof.

9. The method of claim 7 wherein the agglomerated zeolite catalyst is a spent agglomerated zeolite catalyst, the spent agglomerated zeolite catalyst being a product of fluidized catalytic cracking.

10. The method of claim 7 wherein the matrix comprises type x, type y, ultra-stable type y, ZSM-5, SAPO-11, silicate-1, mordenite, ferrierite, beta, or combinations thereof.

11. The method of claim 7 wherein the target cement density is about 10 lb/gal to about 13 lb/gal.

12. A cement composition comprising:
a cementitious component comprising at least 80% by weight agglomerated zeolite catalyst, wherein the agglomerated zeolite catalyst comprises a matrix, a filler, a binder, and zeolite crystals;
lime; and
water, wherein an agglomerated zeolite catalyst to lime weight ratio is about 1:3 to about 1:5.

13. The composition of claim 12 wherein the cementitious component further comprises a hydraulic cement selected from the group consisting of Portland cements, pozzolana cements, gypsum cements, alumina based cements, silica cements, and any combination thereof.

14. The composition of claim 12 wherein the agglomerated zeolite catalyst is a spent agglomerated zeolite catalyst, the spent agglomerated zeolite catalyst being a product of fluidized catalytic cracking.

15. The composition of claim 12 wherein the matrix comprises type x, type y, ultra-stable type y, ZSM-5, SAPO-11, silicate-1, mordenite, ferrierite, beta, or combinations thereof.

16. The composition of claim 12 wherein the matrix is an amorphous solid comprising kaolin filler and silica sol binder, wherein the filler is clay, and wherein the binder is an aluminate compound.

17. The composition of claim 12 wherein the agglomerated zeolite catalyst is present in an amount greater than about 90% by weight of the cement component.

Assignees

• Halliburton Energy Services Inc

Inventors

• Stacey Juan Pablo
• Pisklak Thomas Jason
• Singh John Paul Bir

Classifications

• B01J35/40

  characterised by dimensions, e.g. grain size (in a colloidal state B01J35/23; crystallite size B01J35/77) · CPC title

• C04B14/047 Primary

  Zeolites · CPC title

• B01J2229/42

  Addition of matrix or binder particles · CPC title

• C04B28/04

  Portland cements · CPC title

• C09K8/473 Primary

  Density reducing additives, e.g. for obtaining foamed cement compositions · CPC title