Process for degrading plastic products

Patent metadata

Field	Value
Publication number	US-11377533-B2
Application number	US-202017008683-A
Country	US
Kind code	B2
Filing date	Sep 1, 2020
Priority date	May 19, 2016
Publication date	Jul 5, 2022
Grant date	Jul 5, 2022

Abstract

The present invention relates to processes for degrading plastic products and the uses thereof. The processes of the invention particularly comprise a step of amorphizing a plastic product prior to a step of depolymerization. The processes of the invention are particularly useful for degrading a plastic product comprising polyethylene terephthalate and/or polylactic acid. The invention also relates to a method of producing monomers and/or oligomers from a plastic product comprising at least one polyester, particularly polyethylene terephthalate and/or polylactic acid, comprising submitting the plastic product both to an amorphization step and to a depolymerization step.

First claim

We claim:

1. A process for degrading a plastic product comprising at least one semi-crystalline thermoplastic polyester comprising the steps of:
a) amorphizing at least partially said at least one semi-crystalline thermoplastic polyester of the plastic product by heating the plastic product at a temperature above the crystallization temperature (Tc) of said semi-crystalline thermoplastic polyester, and further cooling the plastic product at a temperature below the glass transition temperature (Tg) of said semi-crystalline thermoplastic polyester, and
b) depolymerizing said at least partially amorphized polyester of the plastic product into monomers and/or oligomers.

2. The process of claim 1 , wherein amorphizing of said polyester is performed by heating the plastic product at or above the melting temperature (Tm) of said semi-crystalline thermoplastic polyester and further cooling the plastic product at a temperature below the glass transition temperature (Tg) of said semi-crystalline thermoplastic polyester.

3. The process of claim 1 , wherein the step of amorphizing further comprises adding at least one degrading agent selected from the group consisting of water, monomers of a polyester of the plastic product, metal alkoxides, alcohol and plasticizers.

4. The process of claim 1 , wherein the step of amorphizing is performed by use of an extruder.

5. The process of claim 4 , wherein the extruder is a single-screw extruder.

6. The process of claim 1 , wherein the plastic product is a plastic fiber provided from fabrics, textiles and/or industrial wastes.

7. The process of claim 1 , wherein the step of amorphizing leads to at least partially amorphized polyester with at most 30% of crystallinity.

8. The process of claim 1 , wherein the step of depolymerizing comprises a chemical depolymerization.

9. The process of claim 1 , wherein the step of depolymerizing is performed by contacting the plastic product with a depolymerase able to depolymerize said at least partially amorphized polyester into monomers and/or oligomers.

10. The process of claim 1 , further comprising recovering oligomers and/or monomers resulting from depolymerization of said at least partially amorphized polyester of the plastic product.

11. The process of claim 10 , wherein the recovered oligomers and/or monomers are further purified.

12. The process of claim 1 , comprising a pretreatment step to modify the plastic product mechanically and/or physically and/or chemically and/or biologically performed before the amorphizing step.

13. The process of claim 1 , wherein the plastic product comprises semi-crystalline polyesters, selected from polyethylene terephthalate (PET), polytrimethylene terephthalate (PTT), polybutylene terephthalate (PBT), polyethylene isosorbide terephthalate (PEIT), polylactic acid (PLA), polyhydroxy alkanoate (PHA), polybutylene succinate (PBS), polybutylene succinate adipate (PBSA), polybutylene adipate terephthalate (PBAT), polyethylene furanoate (PEF), polycaprolactone (PCL), poly(ethylene adipate) (PEA), polybutylene succinate terephthalate (PBST), polyethylene succinate (PES), poly(butylene succinate/terephthalate/isophthalate)-co-(lactate) (PBSTIL) and blends/mixtures of these materials.

14. The process of claim 13 , wherein the depolymerizing step is performed by contacting the plastic product with a depolymerase selected from the group consisting of cutinases, proteases, lipases, carboxylesterases and esterases.

15. The process of claim 1 , wherein the plastic product comprises at least PET, and the amorphizing step comprises heating the plastic product to a temperature above 220° C., then cooling the plastic product to a temperature below 80° C.

16. The process of claim 1 , wherein the plastic product comprises at least PET, and depolymerizing step comprises contacting the plastic product with a cutinase.

17. The process of claim 15 , wherein the depolymerizing step comprises contacting the plastic product with a cutinase.

18. A method of producing monomers and/or oligomers from a plastic product containing at least one semi-crystalline thermoplastic polyester, comprising submitting the plastic product to an amorphization step to amorphize at least partially said semi-crystalline thermoplastic polyester of the plastic product, wherein the amorphization step comprises heating the plastic product to a temperature above the crystallization temperature (Tc) of said semi-crystalline thermoplastic polyester and further cooling the product to a temperature below the glass transition temperature (Tg) of said semi-crystalline thermoplastic polyester, and to a depolymerizing step to depolymerize said at least partially amorphized polyester of the plastic product.

19. The method of claim 18 , wherein the plastic product comprises polyethylene terephthalate and the depolymerizing step comprises exposing the plastic product to a cutinase.

20. A process for degrading a plastic product comprising at least one semi-crystalline thermoplastic polyester that has been previously amorphized by heating the plastic product to a temperature above the crystallization temperature (Tc) of said semi-crystalline thermoplastic polyester and cooling the plastic product to a temperature below the glass transition temperature (Tg) of said semi-crystalline thermoplastic polyester comprising contacting said amorphized plastic product with a depolymerase able to degrade said previously amorphized polyester.

21. The process of claim 4 , wherein the extruder is a multi-screw extruder.

22. The process of claim 1 , wherein the plastic product comprises at least PET, the amorphizing step comprises heating the plastic product to a temperature above 170° C., then cooling the plastic product to a temperature below 65° C., and wherein the depolymerizing step comprises contacting the plastic product with a cutinase.

23. The process of claim 1 , wherein the plastic product comprises at least PET, the amorphizing step comprises heating the plastic product to a temperature above 240° C., then cooling the plastic product to a temperature below 65° C., and wherein the depolymerizing step comprises contacting the plastic product with a cutinase.

24. The process of claim 1 , wherein the plastic product comprises at least PET, the amorphizing step comprises heating the plastic product to a temperature above 250° C., then cooling the plastic product to a temperature below 65° C., and wherein the depolymerizing step comprises contacting the plastic product with a cutinase.

25. The process of claim 1 , wherein the plastic product comprises at least PLA, the amorphizing step comprises heating the plastic product to a temperature above 145° C., then cooling the plastic product to a temperature below 55° C., and wherein the depolymerizing step comprises contacting the plastic product with a protease.

26. The process of claim 1 , wherein the plastic product comprises at least PLA, the amorphizing step comprises heating the plastic product to a temperature above 160° C., then cooling the plastic product to a temperature below 55° C., and wherein the depolymerizing step comprises contacting the plastic product with a protease.

Assignees

• Carbios

Inventors

• Desrousseaux Marie-Laure
• Texier Helene
• Duquesne Sophie
• Marty Alain
• Aloui Dalibey Mediha
• Chateau Michel

Classifications

• C08J2367/02

  Polyesters derived from dicarboxylic acids and dihydroxy compounds; (C08J2367/06 takes precedence) · CPC title

• C08J2367/04

  Polyesters derived from hydroxy carboxylic acids, e.g. lactones (C08J2367/06 takes precedence) · CPC title

• C08J11/105 Primary

  by treatment with enzymes · CPC title

• Y02W30/62

  Plastics recycling; Rubber recycling · CPC title

• C08J11/14

  by treatment with steam or water · CPC title