Method for recycling plastic products

Patent metadata

Field	Value
Publication number	US-10124512-B2
Application number	US-201314443524-A
Country	US
Kind code	B2
Filing date	Nov 19, 2013
Priority date	Nov 20, 2012
Publication date	Nov 13, 2018
Grant date	Nov 13, 2018

Abstract

The invention relates to a method for recycling at least one plastic product, the method comprising degrading at least one polymer of the plastic product to monomers using an enzyme and recovering the resulting monomers. The method of the invention may be used for degrading, simultaneously or sequentially, at least two different polymers of the plastic product, and/or for recycling at least two plastic products.

First claim

The invention claimed is:

1. A method for recycling at least one plastic product comprising at least partially semi-crystalline polyethylene terephthalate (PET) and at least one other additive, the method comprising:
providing, without sorting, a mixture of plastic products coming from plastic waste collection and comprising said at least one plastic product;
selecting a degrading enzyme suitable for degrading the at least partially semi-crystalline PET of the at least one plastic product;
depolymerizing the at least partially semi-crystalline PET of the plastic product to monomers by contacting the at least one plastic product with the degrading enzyme;
recovering the resulting monomers; and
synthesizing polymers from the recovered monomers,

wherein the depolymerizing step is conducted in a liquid medium whose pH is adjusted to be maintained at the optimal pH of the degrading enzyme during all of the depolymerizing step.

2. The method of claim 1 , wherein the enzyme is a cutinase (EC 3.1.1.74).

3. The method of claim 1 , wherein the step of depolymerizing by the enzyme comprises contacting the plastic product with at least one microorganism expressing and excreting said enzyme.

4. The method of claim 3 , wherein the microorganism is a recombinant microorganism expressing and excreting a recombinant degrading enzyme.

5. The method of claim 1 , wherein the plastic product is pretreated prior to degradation.

6. The method of claim 5 , wherein the pretreatment includes mechanical/physical modification of the plastic product.

7. The method of claim 6 , wherein the pretreatment comprises grinding of the plastic product.

8. The method of claim 1 , wherein at least one lipophilic and/or hydrophilic agent is used together with said enzyme.

9. The method of claim 1 , wherein the plastic product further comprises at least one additional polymer chosen among amorphous and/or semi-crystalline polyesters and amorphous and/or semi-crystalline polyamides.

10. The method of claim 9 , wherein the at least one additional polyester is selected from polytrimethylene terephthalate (PTT), polybutylene terephthalate (PBT), polyethylene isosorbide terephthalate (PEIT), polylactic acid (PLA), poly(L-lactic acid) (PLLA), poly(D-lactic acid) (PDLA), poly(D,L-lactic acid) (PDLLA), stereocomplex PLA (scPLA), polyhydroxy alkanoate (PHA), poly(3-hydroxybutyrate) (P(3HB)/PHB), poly(3-hydroxyvalerate) (P(3HV)/PHV), poly(3-hydroxyhexanoate) (P(3HHx)), poly(3-hydroxyoctanoate) (P(3HO)), poly(3-hydroxydecanoate) (P(3HD)), poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (P(3 HB-co-3HV)/PHBV), poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (P(3HB-co-3HHx)/(PHBHHx)), poly(3-hydroxybutyrate-co-5-hydroxyvalerate) (PHB5HV), poly(3-hydroxybutyrate-co-3-hydroxypropionate) (PHB3HP), polyhydroxybutyrate-co-hydroxyoctonoate (PHBO), polyhydroxybutyrate-co-hydroxyoctadecanoate (PHBOd), poly(3-hydroxybutyrate-co-3-hydroxyvalerate-co-4-hydroxybutyrate) (P(3HB-co-3HV-co-4HB)), polybutylene succinate (PBS), polybutylene succinate adipate (PBSA), polybutylene adipate terephthalate (PBAT), polyethylene furanoate (PEF), Polycaprolactone (PCL), poly(ethylene adipate) (PEA) and blends/mixtures of these materials.

11. The method of claim 9 , wherein the polyamide is selected from polyamide-6, poly(β-caprolactam), polycaproamide (PA6), polyamide-6,6, poly(hexamethylene adipamide) (PA6,6), poly(11-aminoundecanoamide) (PA11), polydodecanolactam (PA12), poly(tetramethylene adipamide) (PA4,6), poly(pentamethylene sebacamide) (PA5,10), poly(hexamethylene azelaamide) (PA6,9), poly(hexamethylene sebacamide) (PA6,10), poly(hexamethylene dodecanoamide) (PA6,12), poly(m-xylylene adipamide) (PAMXD6), polyhexamethylene adipamide/polyhexamethylene terephthalamide copolymer (PA66/6T), polyhexamethylene adipamide/polyhexamethylene isophthalamide copolymer (PA66/6I) and blends/mixtures of these materials.

12. The method of claim 1 , wherein said at least one plastic product comprises at least two different plastic polymers and the at least two different plastic polymers are depolymerized sequentially.

13. The method of claim 1 , wherein the mixture of plastic products comprises at least two plastic products, and the at least two plastic products coming from plastic waste collection are recycled, simultaneously or sequentially.

14. The method of claim 1 , wherein the depolymerizing step is performed at a temperature below the Tg of the targeted polymer.

15. The method of claim 1 , wherein the depolymerizing step is performed at a temperature between 20° C. and 80° C.

16. The method of claim 1 , wherein the depolymerizing step is performed at a temperature between 25° C. and 60° C.

17. The method of claim 1 , wherein the other additive of the plastic product is selected from a plasticizer, mineral filler and organic filler.

18. The method of claim 1 , wherein the semi-crystalline PET has at least about 14.9% crystallinity.

19. The method of claim 1 , wherein the semi-crystalline PET has at least about 30% crystallinity.

20. The method of claim 1 , wherein the mixture of plastic products is selected from plastic bottles, plastic bags, plastic packaging and textile waste.

21. A method for producing terephthalic acid from a mixture of plastic products coming from plastic waste collection, wherein at least one plastic product comprises at least partially semi-crystalline polyethylene terephthalate (PET) and at least one or several other additives, wherein the method comprises the steps of:
providing a mixture of plastic products coming from plastic waste collection and comprising said at least one plastic product;
selecting a degrading enzyme suitable for degrading the semi-crystalline PET of the at least one plastic product;
depolymerizing the semi-crystalline PET of the at least one plastic product to terephthalic acid by contacting the at least one plastic product with the degrading enzyme; and
recovering the resulting terephthalic acid,
wherein the depolymerizing step is conducted in a liquid medium whose pH is adjusted to be maintained at the optimal pH of the degrading enzyme during all of the depolymerizing step.

22. The method of claim 21 , wherein at least two plastic products coming from plastic waste collection comprising semi-crystalline polyethylene terephthalate (PET) are recycled, simultaneously or sequentially.

23. The method of claim 1 , further comprising synthesizing PET from the recovered monomers and, optionally, fabricating new plastic products from the PET synthesized from the recovered monomers.

Assignees

• Carbios

Inventors

• Boisart Cédric
• Maille Emmanuel

Classifications

• C12P7/56

  Lactic acid · CPC title

• B29K2105/26

  Scrap {or recycled material} · CPC title

• C08J2377/00

  Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers · CPC title

• C08J11/105 Primary

  by treatment with enzymes · CPC title

• B29B17/0412

  to large particles, e.g. beads, granules, flakes, slices · CPC title