Polypropylene composition with excellent surface appearance

Patent metadata

Field	Value
Publication number	US-11332603-B2
Application number	US-201816622532-A
Country	US
Kind code	B2
Filing date	Jun 26, 2018
Priority date	Jun 30, 2017
Publication date	May 17, 2022
Grant date	May 17, 2022

Abstract

The present invention is directed to a polypropylene composition (C) comprising a heterophasic propylene copolymer (HECO1) having an intrinsic viscosity (IV) of the xylene soluble fraction (XCS) above 3.5 dl/g, an inorganic filler (F) and a nucleating agent (NU) being a dicarboxylic acid and/or a salt thereof. Further, the present invention is directed to the use of said polypropylene composition (C) for the production of a foamed article as well as a foamed article comprising said polypropylene composition (C). The present invention is also directed to the use of a nucleating agent (NU) being dicarboxylic acid and/or a salt thereof for the reduction of tigerskin of a polypropylene composition.

First claim

The invention claimed is:

1. A foamed article comprising a polypropylene composition (C), wherein the polypropylene composition (C) comprises:
a) 15.0 to 35.0 wt. % of a heterophasic propylene copolymer HECO1 having an intrinsic viscosity (IV) of the xylene soluble fraction (XCS) above 3.5 dl/g, wherein the xylene soluble fraction (XCS) is determined at 25° C. according to ISO 16152, said heterophasic propylene copolymer HECO1 comprising:
i) a matrix being a propylene polymer M1 and
ii) an elastomeric propylene copolymer E1 being dispersed in said matrix,

b) 5.0 to 30.0 wt. % of an inorganic filler (F),
c) 0.001 to 2.0 wt. % of a nucleating agent (NU) being a dicarboxylic acid and/or a salt thereof, and
further comprising 38.0 to 45.0 wt. % of a heterophasic propylene copolymer HECO2 having an intrinsic viscosity (IV) of the xylene soluble fraction (XCS) in the range of 1.0 to 3.3 dl/g, wherein the xylene soluble fraction (XCS) is determined at 25° C. according to ISO 16152,
said heterophasic propylene copolymer HECO2 comprising:
i) a matrix being a propylene polymer M2 and
ii) an elastomeric propylene copolymer E2 being dispersed in said matrix.

2. The foamed article according to claim 1 , wherein the heterophasic propylene copolymer HECO1 has a comonomer content of the xylene soluble fraction (XCS) below 40.0 mol %, wherein the xylene soluble fraction (XCS) is determined at 25° C. according to ISO 16152.

3. The foamed article according to claim 1 , wherein the heterophasic propylene copolymer HECO2 has a comonomer content of the xylene soluble fraction (XCS) equal or above 40.0 mol %, wherein the xylene soluble fraction (XCS) is determined at 25° C. according to ISO 16152.

4. The foamed article according to claim 1 , further comprising a high density polyethylene (HDPE) and/or a plastomer (PL) being a copolymer of ethylene and a C 4 to C 8 α-olefin.

5. The foamed article according to claim 4 , wherein the plastomer (PL) is a copolymer of ethylene and 1-octene.

6. The foamed article according to claim 1 , wherein the heterophasic propylene copolymer HECO1 has:
i) a melt flow rate MFR 2 (230° C.) determined according to ISO 1133 in the range of 1.0 to 20.0 g/10 min, and/or
ii) a comonomer content in the range of 5.0 to 30.0 mol %, and/or
iii) a xylene soluble fraction (XCS) in the range of 15.0 to 40.0 wt. %, wherein the xylene soluble fraction (XCS) is determined at 25° C. according to ISO 16152.

7. The foamed article according claim 1 , wherein the heterophasic propylene copolymer HECO2 has:
i) a melt flow rate MFR 2 (230° C.) determined according to ISO 1133 in the range of 50 to 120 g/10 min, and/or
ii) a comonomer content in the range of 4.0 to 30.0 mol %, and/or
iii) a xylene soluble fraction (XCS) in the range of 8.0 to 35.0 wt. %, wherein the xylene soluble fraction (XCS) is determined at 25° C. according to ISO 16152.

8. The foamed article according to claim 1 , wherein the propylene polymer M1 is a propylene homopolymer.

9. The foamed article according to claim 1 , wherein the elastomeric propylene copolymer E1 is a copolymer of propylene and ethylene.

10. The foamed article according to claim 1 , having a melt flow rate MFR 2 (230° C.) determined according to ISO 1133 in the range of 10.0 to 40.0 g/10 min.

11. The foamed article according to claim 1 , wherein the inorganic filler (F) is talc and/or wollastonite.

12. The foamed article according to claim 1 , wherein the nucleating agent (NU) is 1,2-cyclohexane dicarboxylic acid and/or a salt thereof.

13. The foamed article according to claim 1 , further comprising:
v) 2.0 to 10.0 wt. % of a high density polyethylene (HDPE), and
vi) 5.0 to 15.0 wt. % of a plastomer (PL) being a copolymer of ethylene and a C 4 to C 8 α-olefin,
based on the overall polypropylene composition (C).

14. The foamed article according to claim 1 , wherein the propylene polymer M2 is a propylene homopolymer.

15. The foamed article according to claim 1 , wherein the elastomeric propylene copolymer E2 is a copolymer of propylene and ethylene.

16. The foamed article according to claim 1 , wherein the polypropylene composition has a melt flow rate MFR 2 (230° C.) determined according to ISO 1133 in the range of 14.0 to 28.0 g/10 min.

17. The foamed article according to claim 1 , wherein the polypropylene composition (C) comprises:
a) 22.0 to 27.0 wt. % of the heterophasic propylene copolymer HECO1 having an intrinsic viscosity (IV) of the xylene soluble fraction (XCS) above 3.5 dl/g,
wherein the xylene soluble fraction (XCS) is determined at 25° C. according to ISO 16152,
said heterophasic propylene copolymer HECO1 comprising:
i) the matrix being a propylene polymer M1 and
ii) the elastomeric propylene copolymer E1 being dispersed in said matrix,

b) 12.0 to 16.0 wt. % of the inorganic filler (F),
c) 0.05 to 1.0 wt. % of the nucleating agent (NU) being a dicarboxylic acid and/or a salt thereof,
further comprising
38.0 to 45.0 wt. % of the heterophasic propylene copolymer HECO2 having an intrinsic viscosity (IV) of the xylene soluble fraction (XCS) in the range of 1.0 to 3.3 dl/g, wherein the xylene soluble fraction (XCS) is determined at 25° C. according to ISO 16152,
said heterophasic propylene copolymer HECO2 comprising:
i) the matrix being a propylene polymer M2 and
ii) the elastomeric propylene copolymer E2 being dispersed in said matrix,

4.0 to 6.0 wt. % of a high density polyethylene (HDPE), and
7.0 to 10.0 wt. % of a plastomer (PL) being a copolymer of ethylene and a C 4 to C 8 α-olefin, based on the overall polypropylene composition (C).

18. The foamed article according to claim 17 , wherein:
said heterophasic propylene copolymer HECO1 comprises
i) the matrix being a propylene homopolymer M1 and
ii) the elastomeric copolymer of propylene and ethylene E1 being dispersed in said matrix,

said inorganic filler (F) is talc,
said nucleating agent (NU) is selected from the group consisting of 1,2-cyclohexane dicarboxylic acid, 1,3-cyclohexane dicarboxylic acid, 1,4-cyclohexane dicarboxylic acid, 1,1-cyclobutane dicarboxylic acid, 1,2-cyclopentane dicarboxylic acid and/or salts thereof,
said heterophasic propylene copolymer HECO2 comprises
i) the matrix being a propylene homopolymer M2 and
ii) the elastomeric copolymer of propylene and ethylene E2 being dispersed in said matrix, and

said plastomer (PL) is a copolymer of ethylene and a 1-octene.

Assignees

• Borealis Ag

Inventors

• Mileva Daniela
• Kahlen Susanne
• Grestenberger Georg
• Sageder Anton
• Wurnitsch Christof
• Hartl Anna
• Rover Patrick
• Pirklbauer Erwin

Classifications

• C08F210/06

  Propene · CPC title

• C08L23/12 Primary

  Polypropene · CPC title

• C08K5/09

  Carboxylic acids; Metal salts thereof; Anhydrides thereof · CPC title

• C08L23/0815

  with aliphatic 1-olefins containing one carbon-to-carbon double bond · CPC title

• C08K5/098

  Metal salts of carboxylic acids · CPC title