Heterophasic composition

Patent metadata

Field	Value
Publication number	US-10221305-B2
Application number	US-201615765949-A
Country	US
Kind code	B2
Filing date	Oct 21, 2016
Priority date	Oct 23, 2015
Publication date	Mar 5, 2019
Grant date	Mar 5, 2019

Abstract

Modified heterophasic composition to improve the surface appearance of automobil parts.

First claim

What is claimed is:

1. A composition comprising
(a) a heterophasic composition (HECO) comprising a comonomer selected from ethylene and/or C 4 to C 12 alpha-olefin comprising
(a1) a (semi)crystalline polypropylene (PP) and
(a2) an elastomeric propylene copolymer (ESC) dispersed in said (semi)crystalline polypropylene (PP);

(b) an inorganic filler (F), and
(c) a modified heterophasic composition (mHECO) comprising a comonomer selected from ethylene and/or C 4 to C 12 alpha-olefin comprising
(c1) a (semi)crystalline polypropylene (mPP);
(c2) an elastomeric propylene copolymer (mESC) dispersed in said (semi)crystalline polypropylene (mPP);
(c3) at least one of units (D) derived from bifunctionally unsaturated monomer(s) (D′) selected from the group consisting of divinyl compounds, allyl compounds, and dienes, or multifunctionally unsaturated low molecular weight polymer (D″) being a polybutadiene or a copolymer of polybutadiene and styrene having 1,2-(vinyl) in the polymer chain and having a number average molecular weight (Mn) of equal or below 10000 g/mol,
(c4) a xylene cold soluble fraction (XCS) in the range of 15 to 30 wt.-%; and
(c5) a gel content of below 1.0 wt. %;

wherein the heterophasic composition (HECO) is different from the modified heterophasic composition (mHECO), and
the heterophasic composition (HECO), the inorganic filler (F), and the modified heterophasic composition (mHECO) make up together at least 90 wt.-%, based on a total weight of the composition.

2. The composition according to claim 1 , wherein the xylene cold soluble fraction (XCS) of the modified heterophasic composition (mHECO) has an intrinsic viscosity (IV) in the range of 1.5 to 2.6 dl/g.

3. The composition according to claim 1 , wherein the modified heterophasic composition (mHECO) has a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 from 20 to 50 g/10 min.

4. The composition according to claim 1 , wherein the modified heterophasic composition (mHECO) comprises at least one of:
(a) a comonomer content of ethylene and/or C 4 to C 12 alpha-olefin in the range of 12 to 28 mol-%;
or
(b) at least 0.1 wt.-% of units (D).

5. The composition according to claim 1 , wherein
(a) the bifunctionally unsaturated monomers (D′) used for the units (D) are selected from the group consisting of 1,3-butadiene, isoprene, dimethylbutadiene, and divinylbenzene;
or
(b) the multifunctionally unsaturated low molecular weight polymer (D″) is a polybutadiene having a number average molecular weight (Mn) of equal or below 10000 g/mol;
or
(c) both (a) and (b).

6. The composition according to claim 1 , wherein the heterophasic composition (HECO) has at least one of:
(a) a comonomer content of ethylene and/or C 4 to C 12 alpha-olefin, based on the total weight of the heterophasic composition (HECO), in the range of 10 to 30 mol-%;
or
(b) a xylene cold soluble fraction (XCS) in the range of 20 to 45 wt.-%;
or
(c) a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 from 5 to 30 g/10 min.

7. The composition according to claim 1 , wherein a xylene cold soluble fraction (XCS) of the heterophasic composition (HECO) has
(a) an intrinsic viscosity (IV) in the range of 1.5 to 4.5 dl/g;
(b) a comonomer content of ethylene and/or C 4 to C 12 alpha-olefin, based on the total weight of the xylene cold soluble fraction (XCS) of the heterophasic composition (HECO), in the range of 30 to 60 mol-%.

8. The composition according to claim 1 , wherein a xylene insoluble fraction (XCI) of the heterophasic composition (HECO) has an intrinsic viscosity (IV) in the range of 0.8 to 1.8 dl/g.

9. The composition according to claim 1 , wherein the difference of the intrinsic viscosity (IV) of a xylene insoluble fraction (XCI) of the heterophasic composition (HECO) to the intrinsic viscosity (IV) of a xylene cold soluble fraction (XCS) of the heterophasic composition (HECO) is in the range of 0.5 to 5.8.

10. The composition according to claim 1 , wherein the inorganic filler (F) is talc.

11. The composition according to claim 1 , wherein the composition comprises
(a) 45 to 85 wt.-%, based on the total weight of the composition, of the heterophasic composition (HECO);
(b) 5 to 25 wt.-%, based on the total weight of the composition, of the inorganic filler (F); and
(c) 5 to 30 wt.-%, based on the total weight of the composition, of the modified heterophasic composition (mHECO).

12. An article comprising the composition according to claim 1 .

13. The article according to claim 12 being an automotive article.

14. A process comprising: reducing tigerskin of a composition with the modified heterophasic composition (mHECO) defined in claim 1 , wherein the composition comprises a modified heterophasic composition (mHECO) and the heterophasic composition (HECO) as defined in claim 1 .

15. The process according to claim 14 , wherein the composition comprises at least one of:
(b) talc as the additional inorganic filler (F);
or
(c) (c1), (c2), and (c3) wherein:
(c1) 45 to 85 wt.-%, based on the total weight of the composition, of the heterophasic composition (HECO);
(c2) 5 to 25 wt.-%, based on the total weight of the composition, of the inorganic filler (F); and
(c3) 5 to 30 wt.-%, based on the total weight of the composition, of the modified heterophasic composition (mHECO).

Assignees

• Borealis Ag

Inventors

• Grestenberger Georg
• Kahlen Susanne
• Sandholzer Martina
• Potter Gregory

Classifications

• C08L23/12 Primary

  Polypropene · CPC title

• C08F210/16 Primary

  Copolymers of ethene with alpha-alkenes, e.g. EP rubbers · CPC title

• C08L2312/02

  with dienes · CPC title

• C08L2207/02

  Heterophasic composition · CPC title

• C08L2205/035

  containing four or more polymers in a blend · CPC title