High flow TPO composition with excellent low temperature impact

Patent metadata

Field	Value
Publication number	US-10155828-B2
Application number	US-201615772414-A
Country	US
Kind code	B2
Filing date	Nov 17, 2016
Priority date	Nov 17, 2015
Publication date	Dec 18, 2018
Grant date	Dec 18, 2018

Abstract

The present invention is directed to a heterophasic propylene copolymer (HECO), a polyolefin composition (PO) comprising the heterophasic propylene copolymer (HECO), an automotive article comprising the heterophasic propylene copolymer (HECO) and/or the polyolefin composition (PO) and a process for the preparation of the polyolefin composition (PO) as well as the use of the heterophasic propylene copolymer (HECO) for improving the mechanical properties of a polyolefin composition (PO).

First claim

The invention claimed is:

1. A heterophasic propylene copolymer (HECO) comprising
a) a propylene homopolymer (HPP) having a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 200 to 350 g/10 min, and
b) an elastomeric propylene-ethylene copolymer (E),

wherein the heterophasic propylene copolymer (HECO)
(i) has a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 15 to 35 g/10 min,
(ii) comprises a xylene cold soluble (XCS) fraction in an amount from 34 to 40 wt.-%, based on the total weight of the heterophasic propylene copolymer (HECO),

wherein further the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO) has
(iii) an intrinsic viscosity (IV) in the range of 2.8 to 3.8 dl/g measured according to DIN ISO 1628/1, and
(iv) an ethylene content (EC) of 25 to 35 wt.-%, based on the total weight of the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO).

2. The heterophasic propylene copolymer (HECO) according to claim 1 , wherein the propylene homopolymer (HPP) is unimodal with respect to the melt flow rate MFR 2 (230° C.) measured according to ISO 1133, has a xylene cold soluble (XCS) content no higher than 5 wt.-%, or is unimodal with respect to the melt flow rate MFR 2 (230° C.) measured according to ISO 1133 and has a xylene cold soluble (XCS) content of no higher than 5 wt.-%.

3. The heterophasic propylene copolymer (HECO) according to claim 1 , wherein the heterophasic propylene copolymer (HECO) has an ethylene content (EC-HECO) of 8 to 17 wt.-%, based on the total weight of the heterophasic propylene copolymer (HECO).

4. The heterophasic propylene copolymer (HECO) according to claim 1 , wherein the xylene cold soluble (XCS) fraction is unimodal with respect to the ethylene content (EC), unimodal with respect to a molecular weight distribution (MWD), or unimodal with respect to the ethylene content (EC) and with respect to the molecular weight distribution (MWD).

5. The heterophasic propylene copolymer (HECO) according to claim 1 , wherein the weight ratio of heterophasic propylene copolymer (HECO) to the polypropylene homopolymer (HPP) [HECO/HPP] is from 3.0:1.0 to 1.0:1.0.

6. The heterophasic propylene copolymer (HECO) according to claim 1 , wherein the heterophasic propylene copolymer (HECO) is α-nucleated.

7. A polyolefin composition (PO) comprising ≥95 wt.-%, based on the total weight of the composition, of the heterophasic propylene copolymer (HECO) according to claim 1 .

8. The polyolefin composition (PO) according to claim 7 , wherein the composition comprises an inorganic filler (F).

9. The polyolefin composition (PO) according to claim 7 , wherein the composition has
i) a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 15 to 35 g/10 min, and one or more of:
ii) a tensile modulus of ≥750 MPa measured according to ISO 527-2, or
iii) a Charpy Notched impact strength at 23° C. of ≥30 kJ/m 2 measured according to ISO 179-1/1eA,
iv) a Charpy Notched impact strength at −20° C. of ≥8 kJ/m 2 measured according to ISO 179-1/1eA.

10. The polyolefin composition (PO) according to claim 9 , wherein the composition has one or more of:
i) a tensile modulus in the range of 750 to 1050 MPa measured according to ISO 527-2, or
ii) a Charpy Notched impact strength at 23° C. in the range of 30 to 60 kJ/m 2 measured according to ISO 179-1/1eA, or
iii) a Charpy Notched impact strength at −20° C. in the range of 8 to 14 kJ/m 2 measured according to ISO 179-1/1eA.

11. An automotive article comprising at least one of a heterophasic propylene copolymer (HECO) and a polyolefin composition (PO),
wherein the heterophasic propylene copolymer (HECO) comprises
a) a propylene homopolymer (HPP) having a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 200 to 350 g/10 min, and
b) an elastomeric propylene-ethylene copolymer (E),

wherein the heterophasic propylene copolymer (HECO)
(i) has a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 15 to 35 g/10 min,
(ii) comprises a xylene cold soluble (XCS) fraction in an amount from 34 to 40 wt.-%, based on the total weight of the heterophasic propylene copolymer (HECO),

wherein further the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO) has
(iii) an intrinsic viscosity (IV) in the range of 2.8 to 3.8 dl/g measured according to DIN ISO 1628/1, and
(iv) an ethylene content (EC) of 25 to 35 wt.-%, based on the total weight of the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO); and

wherein the polyolefin composition (PO) comprises ≥95 wt.-%, based on the total weight of the polyolefin composition, of the heterophasic propylene copolymer (HECO).

12. The automotive article according to claim 11 , wherein the automotive article is an exterior or interior automotive article selected from bumpers, body panels, rocker panels, side trim panels, interior trims, step assists, spoilers, fenders and dash boards.

13. A process for the preparation of a polyolefin composition (PO) according to claim 8 , the process comprising extruding the heterophasic propylene copolymer (HECO) and the optional inorganic filler (F) in an extruder.

14. The process according to claim 13 , wherein the heterophasic propylene copolymer (HECO) is obtained by producing the propylene homopolymer (HPP) in at least one reactor, transferring said propylene homopolymer (HPP) in at least one subsequent reactor, and producing the elastomeric propylene-ethylene copolymer (E) in the presence of the propylene homopolymer (HPP).

15. A method comprising improving the mechanical properties of a polyolefin composition (PO) with the heterophasic propylene copolymer (HECO) according to claim 1 , wherein the improvement is achieved when the composition has
i) a melt flow rate MFR2 (230° C.) measured according to ISO 1133 in the range of 15 to 35 g/10 min, and one or more of
ii) a tensile modulus of ≥750 MPa measured according to ISO 527-2, or
iii) a Charpy Notched impact strength at 23° C. of ≥30 kJ/m 2 measured according to ISO 179-1/1eA, or
iv) a Charpy Notched impact strength at −20° C. of ≥8 KJ/m 2 .

16. The heterophasic propylene copolymer (HECO) according to claim 6 , wherein the heterophasic propylene copolymer (HECO) comprises a α-nucleating agent.

17. The polyolefin composition (PO) according to claim 8 , wherein the inorganic filler (F) is selected from the group consisting of talc, wollastonite, mica, chalk and mixtures thereof.

18. The polyolefin composition (PO) according to claim 8 , wherein the composition has
i) a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 15 to 35 g/10 min, and one or more of:
ii) a tensile modulus of ≥750 MPa measured according to ISO 527-2, or
iii) a Charpy Notched impact strength at 23° C. of ≥30 kJ/m 2 measured according to ISO 179-1/1eA, or
iv) a Charpy Notched impact strength at −20° C. of ≥8 kJ/m 2 measured according to ISO 179-1/1eA.

19. The polyolefin composition (PO) according to claim 18 , wherein the composition has one or more of:
i) a tensile modulus in the range of 750 to 1050 MPa measured according to ISO 527-2, or
ii) a Charpy Notched impact strength at 23° C. in the range of 30 to 60 kJ/m 2 measured according to ISO 179-1/1eA, or
iii) a Charpy Notched impact strength at −20° C. in the range of 8 to 14 kJ/m 2 measured according to ISO 179-1/1eA

Assignees

• Borealis Ag

Inventors

• Grestenberger Georg
• Sandholzer Martina

Classifications

• C08L2314/02

  Ziegler natta catalyst · CPC title

• C08L2308/00

  Chemical blending or stepwise polymerisation process with the same catalyst · CPC title

• C08L23/16

  Ethylene-propylene or ethylene-propylene-diene copolymers · CPC title

• C08L23/12

  Polypropene · CPC title

• C08K3/34 Primary

  Silicon-containing compounds · CPC title