Anodization architecture for electro-plate adhesion
US-9624593-B2 · Apr 18, 2017 · US
US11289357B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11289357-B2 |
| Application number | US-201916550521-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 26, 2019 |
| Priority date | Jun 27, 2019 |
| Publication date | Mar 29, 2022 |
| Grant date | Mar 29, 2022 |
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Methods and apparatus for increasing voltage breakdown levels of an electrostatic chuck in a process chamber. A soft anodization layer with a thickness of greater than zero and less than approximately 10 microns is formed on an aluminum base of the electrostatic chuck. The soft anodization layer remains thermally elastic in a temperature range of approximately −50 degrees Celsius to approximately 100 degrees Celsius. An alumina spray coating is then applied on the soft anodization layer. The soft anodization layer provides thermal stress relief between the aluminum base and the alumina spray coating to reduce/eliminate cracking caused by the thermal expansion rate differences between the aluminum base and the alumina spray coating.
Opening claim text (preview).
The invention claimed is: 1. An electrostatic chuck for holding substrates in a process chamber, the electrostatic chuck comprising: an aluminum base; an anodized layer on the aluminum base, wherein the anodized layer has a non-columnar structure and a thickness of greater than zero and less than approximately 10 microns; and an alumina layer on the anodized layer, wherein the alumina layer has a thickness of approximately 200 microns to approximately 300 microns. 2. The electrostatic chuck of claim 1 , wherein the electrostatic chuck has a breakdown voltage of approximately 2 kV or more. 3. The electrostatic chuck of claim 1 , wherein the anodized layer is a soft anodized layer. 4. The electrostatic chuck of claim 1 , wherein the anodized layer is configured to provide thermal expansion and contraction stress relief between the aluminum base and the alumina layer to reduce cracking of the alumina layer. 5. The electrostatic chuck of claim 1 , wherein the alumina layer is formed by spray coating alumina on the anodized layer. 6. The electrostatic chuck of claim 1 , wherein the anodized layer provides approximately 10 volts of insulative protection for approximately every one micron of thickness. 7. The electrostatic chuck of claim 1 , wherein the anodized layer is thermally elastic in a temperature range of approximately −50 degrees Celsius to approximately 100 degrees Celsius. 8. An electrostatic chuck for holding substrates in a process chamber, the electrostatic chuck comprising: an aluminum base; an anodized layer on the aluminum base, wherein the anodized layer is a soft anodized layer with a non-columnar structure and a thickness of greater than zero and less than approximately 10 microns; and an alumina layer on the anodized layer, wherein the alumina layer has a thickness of approximately 200 microns to approximately 300 microns, and wherein the electrostatic chuck has a breakdown voltage of approximately 2 kV or more. 9. The electrostatic chuck of claim 8 , wherein the anodized layer is configured to provide thermal expansion and contraction stress relief between the aluminum base and the alumina layer to reduce cracking of the alumina layer. 10. The electrostatic chuck of claim 8 , wherein the alumina layer is formed by spray coating alumina on the anodized layer. 11. The electrostatic chuck of claim 8 , wherein the anodized layer provides approximately 10 volts of insulative protection for approximately every one micron of thickness. 12. The electrostatic chuck of claim 8 , wherein the anodized layer is thermally elastic in a temperature range of approximately −50 degrees Celsius to approximately 100 degrees Celsius. 13. The electrostatic chuck of claim 8 , wherein the breakdown voltage is approximately 2 kV to approximately 3 kV. 14. A method for increasing voltage breakdown levels of an electrostatic chuck, comprising: forming a first layer on an aluminum base of the electrostatic chuck, the first layer being a first dielectric material with a non-columnar structure and thermally elastic properties in a temperature range of approximately −50 degrees Celsius to approximately 100 degrees Celsius; and forming a second layer on the first layer, the second layer being a second dielectric material, wherein the thermally elastic properties inhibit cracking of the second layer which has a coefficient of thermal expansion different from the aluminum base. 15. The method of claim 14 , further comprising: forming the first layer on the aluminum base using a soft anodization process that does not produce a columnar structure in the first layer. 16. The method of claim 14 , further comprising: forming the second layer by spray coating alumina on the first layer. 17. The method of claim 14 , further comprising: forming the first layer on the aluminum base with a thickness of greater than zero and less than approximately 10 microns. 18. The method of claim 14 , further comprising: forming the second layer on the first layer with a thickness of approximately 200 microns to approximately 300 microns. 19. The method of claim 14 , wherein the first dielectric material provides approximately 10 volts of insulative protection for approximately every one micron of thickness. 20. The method of claim 14 , wherein the first layer provides thermal expansion and contraction stress relief between the aluminum base and the second layer.
Details of electrostatic chucks · CPC title
characterised by a coating, a hardness or a material · CPC title
Electricity · mapped topic
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