Method of producing a silicon compound material and apparatus for producing a silicon compound material

Patent metadata

Field	Value
Publication number	US-11229893-B2
Application number	US-201916239845-A
Country	US
Kind code	B2
Filing date	Jan 4, 2019
Priority date	Jul 6, 2016
Publication date	Jan 25, 2022
Grant date	Jan 25, 2022

Abstract

Provided is a method of producing a silicon compound material, including the steps of: storing a silicon carbide preform in a reaction furnace; supplying a raw material gas containing methyltrichlorosilane to the reaction furnace to infiltrate the preform with silicon carbide; and controlling and reducing a temperature of a gas discharged from the reaction furnace at a predetermined rate to subject the gas to continuous thermal history, to thereby decrease generation of a liquid or solid by-product derived from the gas.

First claim

What is claimed is:

1. A method of producing a silicon compound material, comprising:
storing a silicon carbide preform in a reaction furnace;
supplying a raw material gas containing methyltrichlorosilane to the reaction furnace to infiltrate the preform with silicon carbide; and
reducing a temperature of a gas discharged from the reaction furnace to a predetermined temperature within a range of 500° C. or more and less than 950° C. at a predetermined rate, and subsequently retaining the temperature of the gas at the predetermined temperature, thereby decreasing generation of a liquid or solid by-product derived from the gas.

2. A method of producing a silicon compound material according to claim 1 , wherein the predetermined temperature is within a range of 600° C. or more and less than 800° C.

3. A method of producing a silicon compound material according to claim 2 , wherein the gas discharged from the reaction furnace is retained at the predetermined temperature for a predetermined time period within a range of from 0 seconds to 8 seconds.

4. A method of producing a silicon compound material according to claim 2 , wherein the temperature of the gas discharged from the reaction furnace is reduced to the predetermined temperature such that the temperature of the gas is changed to a plurality of temperatures in a stepwise manner.

5. A method of producing a silicon compound material according to claim 2 , wherein the liquid or solid by-product comprises a higher-chlorosilane.

6. A method of producing a silicon compound material according to claim 2 , wherein the reducing of the temperature of the gas discharged from the reaction furnace and the retaining of the temperature of the gas are performed such that SiCl 2 serving as a precursor of the liquid or solid by-product is converted into a stable substance.

7. A method of producing a silicon compound material according to claim 1 , wherein the gas discharged from the reaction furnace is retained at the predetermined temperature for a predetermined time period within a range of from 0 seconds to 8 seconds.

8. A method of producing a silicon compound material according to claim 1 , wherein the temperature of the gas discharged from the reaction furnace is reduced to the predetermined temperature such that the temperature of the gas is changed to a plurality of temperatures in a stepwise manner.

9. A method of producing a silicon compound material according to claim 1 , wherein the liquid or solid by-product comprises a higher-chlorosilane.

10. A method of producing a silicon compound material according to claim 1 , wherein the reducing of the temperature of the gas discharged from the reaction furnace and the retaining of the temperature of the gas are performed such that SiCl 2 serving as a precursor of the liquid or solid by-product is converted into a stable substance.

11. A method of producing a silicon compound material according to claim 10 , wherein the stable substance comprises at least one selected from the group consisting of methyltrichlorosilane, dimethyldichlorosilane, disilane, dichlorosilane, trichlorosilane, and tetrachlorosilane.

12. A method of producing a silicon compound material according to claim 1 , wherein the gas discharged from the reaction furnace contains hydrogen.

13. A method of producing a silicon compound material according to claim 1 ,
wherein the temperature of the gas discharged from the reaction furnace is retained at the predetermined temperature immediately after the temperature is reduced to the predetermined temperature,
wherein the predetermined temperature is within a range of 600° C. or more and less than 800° C., and
wherein the gas discharged from the reaction furnace is retained at the predetermined temperature for a predetermined time period which is greater than 0 second and 8 seconds or less.

14. A method of producing a silicon compound material, comprising:
storing a silicon carbide preform in a reaction furnace;
supplying a raw material gas containing methyltrichlorosilane to the reaction furnace to infiltrate the preform with silicon carbide; and
reducing a temperature of a gas discharged from the reaction furnace to a predetermined temperature at a predetermined rate while adding an additive gas to the gas discharged from the reaction furnace, and subsequently retaining the temperature of the gas to which the additive gas has been added at the predetermined temperature, thereby decreasing generation of a liquid or solid by-product derived from the gas discharged from the reaction furnace.

15. A method of producing a silicon compound material according to claim 14 , wherein the additive gas is added such that an amount of substance of the additive gas is larger than an amount of substance of the liquid or solid by-product.

16. A method of producing a silicon compound material according to claim 14 , wherein the additive gas is added such that an amount of substance of chlorine is larger than an amount of substance of silicon contained in the liquid or solid by-product.

17. A method of producing a silicon compound material according to claim 14 , wherein the temperature of the gas discharged from the reaction furnace is retained at the predetermined temperature using a reforming furnace, such that a time period for which the gas discharged from the reaction furnace is retained at the predetermined temperature is a residence time of the gas in the reforming furnace.

18. A method of producing a silicon compound material according to claim 14 , wherein the predetermined temperature is within a range of 200° C. or more and less than 1,100° C.

19. A method of producing a silicon compound material according to claim 14 , wherein the predetermined temperature is within a range of 750° C. or more and less than 850° C.

20. A method of producing a silicon compound material according to claim 14 , wherein the additive gas comprises a molecule containing chlorine.

21. A method of producing a silicon compound material according to claim 14 , wherein the additive gas comprises at least one selected from the group consisting of a nitrogen gas, a hydrogen gas, hydrogen chloride, chloromethane, tetrachloromethane, trichloroethylene, trichloroethane, ethylene, ethanol, acetone, methanol, water vapor, dichloromethane, and chloroform.

22. A method of producing a silicon compound material according to claim 14 ,
wherein the additive gas comprises chloromethane or dichloromethane, and
wherein the gas discharged from the reaction furnace to which the additive gas has been added is retained at the predetermined temperature for a time period of 0.08 second or more.

23. A method of producing a silicon compound material according to claim 14 ,
wherein the additive gas comprises chloromethane or dichloromethane, and
wherein the gas discharged from the reaction furnace to which the additive gas has been added is retained at the predetermined temperature for a time period of 1 second or more.

24. A method of producing a silicon compound material according to claim 14 ,
wherein the additive gas comprises chloromethane, and
wherein the additive gas is added such that an amount of substance of chloromethane to be added is 1.0 time or more as large as an amount of substance of methyltrichlorosilane in the raw material gas.

25. A method of producing a silicon compound material according to claim 14 ,
wherein the additive gas comprises chl

Assignees

• Ihi Corp
• Univ Tokyo

Inventors

• Fukushima Yasuyuki
• Akazaki Kozue
• Tanaka Yasutomo
• Akikubo Kazuma
• Nakamura Takeshi
• Shimogaki Yukihiro
• Momose Takeshi
• Sato Noboru
• Shima Kohei
• Funato Yuichi

Classifications

• C23C16/045

  Coating cavities or hollow spaces, e.g. interior of tubes; Infiltration of porous substrates · CPC title

• C01B32/977

  Preparation from organic compounds containing silicon · CPC title

• B01J6/008

  Pyrolysis reactions (of hydrocarbons C10G9/00) · CPC title

• C23C16/42

  Silicides · CPC title

• B01J2219/00768

  vertical · CPC title