Process for preparing a biodegradable plastic composition

Patent metadata

Field	Value
Publication number	US-11198767-B2
Application number	US-201615580735-A
Country	US
Kind code	B2
Filing date	Jun 10, 2016
Priority date	Jun 12, 2015
Publication date	Dec 14, 2021
Grant date	Dec 14, 2021

Abstract

The present invention relates to plastic composition comprising at least one polyester, biological entities having a polyester-degrading activity and at least an anti-acid filler, wherein the biological entities represent less than 11% by weight, based on the total weight of the plastic composition, and uses thereof for manufacturing biodegradable plastic articles.

First claim

The invention claimed is:

1. A method for increasing polyester degrading activity of biological entities in a plastic composition consisting of at least one polyester selected from the group consisting of polylactic acid (PLA), polycaprolactone (PCL), polybutylene adipate terephthalate (PBAT), polyhydroxyalkanoate (PHAs) and polybutylene succinate (PBS), at least one anti-acid filler, and biological entities, said method comprising the steps of:
(a) selecting the at least one polyester;
(b) selecting biological entities, said biological entities comprising an enzyme suitable for degrading the at least one polyester of step (a) and/or a microorganism expressing an enzyme suitable for degrading the polyester of step (a);
(c) selecting at least one mineral anti-acid filler;
(d) mixing said at least one polyester with said biological entities and said at least one mineral anti-acid in order to increase the degrading activity of said enzyme and to obtain said plastic composition; and
(e) manufacturing a plastic article with said plastic composition,
and wherein the plastic composition comprises between 2% and 25% by weight of said at least one mineral anti-acid filler.

2. The method of claim 1 , wherein the at least one mineral anti-acid filler is selected from carbonate salts, metals, hydroxide salts, hydrotalcite, talc, mica, and clay.

3. The method of claim 1 , wherein the at least one polyester of step (a) is selected from polylactic acid (PLA) or polycaprolactone (PCL).

4. The method of claim 1 , wherein the biological entities are selected from a depolymerase, esterase, lipase, cutinase, carboxylesterase, protease, and polyesterase.

5. The method of claim 1 , wherein mixing in step (d) is implemented at a temperature at which the polyester of said plastic composition is in a partially or totally molten state.

6. The method of claim 1 , wherein mixing in step (d) is performed by a method selected from extrusion, extrusion-compounding, extrusion blow-molding, blown film extrusion, cast film extrusion, calendering and thermoforming, injection-molding, compression molding, extrusion-swelling, rotary molding, ironing, coating, stratification, expansion, pultrusion, compression-granulation and 3 D printing.

7. The method of claim 1 , wherein mixing in step (d) is performed in an extruder selected from a twin-screw extruder, and a co-rotative twin-screw extruder.

8. The method of claim 4 , wherein the biological entities are a lipase or protease.

9. The method of claim 1 , wherein the plastic composition comprises between 2% and 15% by weight of the mineral anti-acid filler.

Assignees

• Carbios

Inventors

• Guemard Elodie
• Chateau Michel
• Marty Alain

Classifications

• B29B7/88

  Adding charges {, i.e. additives} · CPC title

• B29B7/007

  for continuous mixing · CPC title

• C12Y110/03002

  Laccase (1.10.3.2) · CPC title

• C12N11/14

  Enzymes or microbial cells immobilised on or in an inorganic carrier · CPC title

• C12N11/096

  Polyesters; Polyamides · CPC title