Feedstock material for printing three-dimensional parts with crystallization kinetics control

Patent metadata

Field	Value
Publication number	US-11148374-B2
Application number	US-201816217435-A
Country	US
Kind code	B2
Filing date	Dec 12, 2018
Priority date	Nov 21, 2012
Publication date	Oct 19, 2021
Grant date	Oct 19, 2021

Abstract

A method for printing a three-dimensional part with an additive manufacturing system, which includes providing a part material that compositionally has one or more semi-crystalline polymers and one or more secondary materials that are configured to retard crystallization of the one or more semi-crystalline polymers, where the one or more secondary materials are substantially miscible with the one or more semi-crystalline polymers. The method also includes melting the part material in the additive manufacturing system, forming at least a portion of a layer of the three-dimensional part from the melted part material in a build environment, and maintaining the build environment at an annealing temperature that is between a glass transition temperature of the part material and a cold crystallization temperature of the part material.

First claim

The invention claimed is:

1. A polymeric-based material configured for use as a feedstock in an extrusion-based additive manufacturing system, the material comprising:
a substantially uniform blend of one or more semi-crystalline polyamides and one or more amorphous polyamides, wherein the one or more amorphous polyamides are at least partially miscible with the one or more semi-crystalline polyamides that retard crystallization of the one or more semi-crystalline polyamides after the blend has been heated to a melting temperature and begins to cool wherein at least a portion of the one or more semi-crystalline polyamides comprise one or more graft semi-crystalline polyamides having a polyamide backbone and one or more impact modifiers grafted to the backbone and wherein the one or more amorphous polyamides comprises one or more graft amorphous polyamides having a polyamide backbone and one or more impact modifiers grafted to the backbone; and
one or more fillers comprising from about 1% to about 45% by weight of the total weight of the polymeric-based material.

2. The polymeric-based material of claim 1 , wherein the one or more amorphous polyamides are substantially miscible with the one or more semi-crystalline polyamides.

3. The polymeric-based material of claim 1 , wherein the one or more amorphous polyamides constitute from about 50% by weight to about 85% by weight of a combined weight of the one or more semi-crystalline polyamides and the one or more amorphous polyamides.

4. The polymeric-based material of claim 1 , wherein the blend comprises from about 55% to about 99% by weight of the total weight of the polymeric based material.

5. The polymeric-based material of claim 1 wherein the one or more fillers comprise calcium carbonate, magnesium carbonate, glass spheres, graphite, carbon black, carbon fiber, glass fiber, talc, wollastonite, mica, alumina, silica, kaolin, silicon carbide, zirconium tungstate, soluble salts, metals, ceramics, and combinations thereof.

6. The polymeric-based material of claim 1 and further comprising colorants, plasticizers, and combinations thereof.

7. The polymeric-based material of claim 1 , wherein the polyamide backbone of the one or more grafted semi-crystalline polyamides comprises polycaprolactam (PA6), polyhexamethyleneadipamide (PA6,6), polyhexamethylenenonamide (PA6,9), polyhexamethylenesebacamide (PA6,10), polyenantholactam (PA7), polyundecanolactam (PA11), polylaurolactam (PA12), and mixtures thereof and wherein the polyamide backbone of the one or more grafted amorphous polyamides comprises hexamethylenediamine, isophthalic acid, terephthalic acid, and adipic acid (PA6i/6T/66); polyamides of PA12; 3,3-dimethyl-4,4-diaminodicyclohexylmethane, and isophthalic acid (PA12/MACMI), polyamides of PA12; 3,3-dimethyl-4,4-diaminodicyclohexylmethane, and terephthalic acid (PA12/MACMT); (PA12/MACMI/MACMT); PA6i; PA12/MACM36; PA6-3-T; polyamides of PA6, trimethylhexamethylenediamine and terephthalic acid (PA6/3T); polyamides of cycloaliphaticdiamine and dodecanedioic acid; amorphous polyamides of aliphatic diamines and isophthalic acid and/or terephthalic acid and mixtures thereof.

8. The polymeric-based material of claim 1 , wherein the polyamide backbone of the one or more grafted semi-crystalline polyamide(s) include PA6; PA6,6; and mixtures thereof and wherein the polyamide backbone of the one or more grafted amorphous polyamides comprises PA6/3T, polyamides of cycloaliphaticdiamine and dodecanedioic acid, and mixtures thereof.

9. The polymeric-based material of claim 1 , wherein the one or more grafted impact modifiers comprises from about 5% to about 15% by weight of the one or more graft semi-crystalline polyamides and the one or more graft amorphous polyamides.

Assignees

• Stratasys Inc

Inventors

• Rodgers Luke M B
• Jaker Vittorio L

Classifications

• B29C64/10

  Processes of additive manufacturing · CPC title

• B33Y70/10

  Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials · CPC title

• B33Y70/00

  Materials specially adapted for additive manufacturing · CPC title

• B29C2071/022

  Annealing · CPC title

• B33Y10/00

  Processes of additive manufacturing · CPC title