Method for printing three-dimensional items wtih semi-crystalline build materials

Patent metadata

Field	Value
Publication number	US-9925714-B2
Application number	US-201514723330-A
Country	US
Kind code	B2
Filing date	May 27, 2015
Priority date	Nov 21, 2012
Publication date	Mar 27, 2018
Grant date	Mar 27, 2018

Abstract

A method for printing a three-dimensional part with an additive manufacturing system includes providing a consumable feedstock material comprising a semi-crystalline polymer containing one or more secondary materials, wherein the consumable feedstock material has a process window in which crystalline kinetics are either accelerated or retarded. The consumable feedstock material is melted in the additive manufacturing system. At least a portion of the three-dimensional part from the melted consumable feedstock material in a build environment maintained within the process window.

First claim

The invention claimed is:

1. A method for printing a three-dimensional part with an additive manufacturing system, the method comprising:
providing a consumable feedstock material comprising a semi-crystalline polymer containing one or more secondary materials wherein compositionally the consumable feedstock material is substantially uniform, wherein the consumable feedstock material has a process window in which crystalline kinetics are retarded utilizing a sufficient amount of the one or more secondary materials to be added to the build material such that an enthalpy of the build material with the secondary material is between about 2 J/g heat of fusion and about 80% of the heat of fusion of the build material that is compositionally about 100% of the semi-crystalline build material, as measured by differential scanning calorimetry (DSC) when cooling from the melting temperature to the hot crystalline temperature at a rate of 10° C./min;
melting the consumable feedstock material in the additive manufacturing system; and
forming at least a portion of the three-dimensional part from the melted consumable feedstock material in a build environment maintained within the process window.

2. The method of claim 1 and further comprising:
maintaining the build environment at an annealing temperature that within the process window.

3. The method of claim 1 and wherein the secondary material comprises a substantially amorphous polymer that is miscible with the semi-crystalline polymer.

4. The method of claim 1 and wherein a process window comprises a range between a solidification temperature below a glass transition temperature and a cold crystallization temperature of the build material with the secondary material when utilized with fused deposition modeling, out of oven fused deposition modeling, big area additive manufacturing and electrophotography additive techniques.

5. The method of claim 4 and further comprising selecting conditions within the process window to cause a selected amount of crystallinity to form within the build material and the secondary material.

6. The method of claim 1 and wherein the process window comprises a range between a melt temperature and a hot crystallization temperature of the build material with the secondary material when utilized with selective laser sintering or high speed sintering techniques wherein the hot crystallization temperature is lowered by at least three ° C. relative to neat semi-crystalline polymer such that a range of temperatures in the process window is increased.

7. The method of claim 6 and further comprising selecting conditions within the process window to cause a selected amount of crystallinity to form within the build material and the one or more secondary material.

8. The method of claim 1 and wherein the addition of the secondary material to the semi-crystalline build material such that at least a 3° C. suppression of a hot crystallization temperature is realized and the process window between the melt temperature and the hot crystallization temperature increases.

9. The method of claim 1 and wherein the addition of the secondary material to the semi-crystalline build material such that at least a 5° C. suppression of a hot crystallization temperature is realized and the process window between the melt temperature and the hot crystallization temperature increases.

10. The method of claim 1 and wherein the addition of the secondary material to the semi-crystalline build material such that at least a 10° C. suppression of a hot crystallization temperature is realized and the process window between the melt temperature and the hot crystallization temperature increases.

11. A method for printing a three-dimensional part with an additive manufacturing system, the method comprising:
providing a consumable feedstock material comprising one or more semi-crystalline polymers containing one or more secondary materials that are configured to retard crystallization of the one or more semi-crystalline polymers wherein compositionally the consumable feedstock material is substantially uniform, wherein the consumable feedstock material has a process window in which crystalline kinetics are retarded and wherein the consumable feed stock has an enthalpy of the consumable feedstock is between about 2 J/g heat of fusion and about 80% of the heat of fusion of the build material that is compositionally about 100% of the semi-crystalline build material, as measured by differential scanning calorimetry (DSC) when cooling from the melting temperature to the hot crystalline temperature at a rate of 10° C./min;
melting the consumable feedstock material in the additive manufacturing system; and
forming at least a portion of the three-dimensional part from the melted consumable feedstock material in a build environment maintained within the process window.

12. The method of claim 11 and wherein the one or more secondary materials comprises a substantially amorphous polymer that is miscible with the one or more semi-crystalline polymers.

13. The method of claim 11 and wherein a process window comprises a range between a solidification temperature below a glass transition temperature and a cold crystallization temperature of the build material with the secondary material when utilized with fused deposition modeling, out of oven fused deposition modeling, big area additive manufacturing, cool high speed sintering and electrophotography additive techniques.

14. The method of claim 11 and wherein a process window comprises a range between a melt temperature and a hot crystallization temperature of the build material with the secondary material when utilized with selective laser sintering or hot high speed sintering techniques.

15. The method of claim 11 , and wherein the hot crystallization temperature is suppressed at least about 3° C. to expand the process window relative to neat semi-crystalline polymer.

16. A method for printing a three-dimensional part with an additive manufacturing system, the method comprising:
providing a consumable feedstock material comprising a semi-crystalline polymer containing one or more secondary materials that are configured to accelerate crystallization of the one or more semi-crystalline polymers, wherein compositionally the consumable feedstock material is substantially uniform, wherein the consumable feedstock material has a process window in which crystalline kinetics are accelerated and wherein the consumable feed stock has an enthalpy of the consumable feedstock is at least 5 J/g when cooled at 10° C./min cooling as measured by differential scanning calorimetry (DSC) when cooling from the melting temperature to the hot crystalline temperature at a rate of 10° C./min;
melting the consumable feedstock material in the additive manufacturing system; and
forming at least a portion of the three-dimensional part from the melted consumable feedstock material in a build environment maintained within the process window.

17. The method of claim 16 and wherein the secondary material comprises synthetic fibers or minerals.

18. The method of claim 16 and wherein the secondary materials comprises a second polymer that is immiscible with the build material.

19. A method for printing a three-dimensional item with a powder sintering additive manufacturing system, the method comprising:
providing a consumable feedstock material in a powder form comprising a semi-crystalline polymer containing one or more secondary materials that are configured to retard crystallization of the one or

Assignees

• Stratasys Inc

Inventors

• Rodgers Luke M B
• Jaker Vittorio L

Classifications

• B29C64/112

  using individual droplets, e.g. from jetting heads · CPC title

• B29C64/165

  using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber · CPC title

• B29C64/153

  using layers of powder being selectively joined, e.g. by selective laser sintering or melting · CPC title

• B29C2071/022

  Annealing · CPC title

• G03G15/225

  using contact-printing · CPC title