Functionalized graphene comprising two or more types of amines, and preparation method therefor
US-2018079647-A1 · Mar 22, 2018 · US
US11147197B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11147197-B2 |
| Application number | US-201916659459-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 21, 2019 |
| Priority date | Oct 21, 2019 |
| Publication date | Oct 12, 2021 |
| Grant date | Oct 12, 2021 |
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Embodiments may relate to a material to provide electrostatic discharge (ESD) protection in an electrical device. The material may include first and second electrically-conductive carbon allotropes. The material may further include an electrically-conductive polymer that is chemically bonded to the first and second electrically-conductive carbon allotropes such that an electrical signal may pass between the first and second electrically-conductive carbon allotropes. Other embodiments may be described or claimed.
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The invention claimed is: 1. A material to provide electrostatic discharge (ESD) protection in an electrical device, wherein the material comprises: a first electrically-conductive carbon allotrope having a first functional group; a second electrically-conductive carbon allotrope having a second functional group; and a first electrically-conductive polymer that is chemically bonded to the first functional group and the second functional group such that an electrical signal may pass between the first and second electrically-conductive carbon allotropes. 2. The material of claim 1 , wherein the first electrically-conductive carbon allotrope is a carbon nanoribbon. 3. The material of claim 1 , wherein the first electrically-conductive polymer is polythiophene. 4. The material of claim 1 , wherein the first electrically-conductive carbon allotrope is graphene. 5. The material of claim 1 , wherein the first electrically-conductive polymer is polyacetylene or polyaniline. 6. The material of claim 1 , wherein the material further includes a non-conductive polymer matrix. 7. The material of claim 6 , wherein the non-conductive polymer matrix is bonded to the first electrically-conductive carbon allotrope by a second electrically-conductive polymer. 8. The material of claim 1 , wherein the non-conductive polymer matrix includes epoxy, acrylonitrile-butadiene-styrene copolymer, or polyimide. 9. The material of claim 1 , wherein the material is non-conductive when a voltage below a threshold voltage is applied to the material, and the material is conductive when a voltage at or above the threshold voltage is applied to the material. 10. The material of claim 9 , wherein the threshold voltage is based on a material used for the first electrically-conductive carbon allotrope, a material used for the second electrically-conductive carbon allotrope, and a material used for the first electrically-conductive polymer. 11. A microelectronic package for use in an electronic device, wherein the microelectronic package comprises: a signal path electrically positioned between, and coupled to, a die and a voltage input; a ground signal path electrically positioned between, and coupled to, a connection to ground and the signal path; and an electrostatic discharge (ESD) protection material coupled to the ground signal path, wherein the ESD protection material includes a first electrically-conductive carbon allotrope having a first functional group, a second electrically-conductive carbon allotrope having a second functional group, and an electrically-conductive polymer that chemically bonds with the first functional group and the second functional group such that the first and second electrically-conductive carbon allotropes are chemically bonded to one another within a non-conductive material. 12. The microelectronic package of claim 11 , wherein the ESD protection material is electrically positioned between the signal path and the connection to ground. 13. The microelectronic package of claim 11 , wherein the voltage input is to provide an input voltage, and wherein the ESD protection material is electrically-conductive when the input voltage is at or above a voltage threshold. 14. The microelectronic package of claim 11 , wherein the voltage input is to provide an input voltage, and wherein the ESD protection material is electrically non-conductive when the input voltage is below a voltage threshold. 15. The microelectronic package of claim 11 , wherein the first and second electrically-conductive carbon allotropes are carbon nanotubes. 16. The microelectronic package of claim 11 , wherein the electrically-conductive polymer is poly(3,4-ethylenedioxythiophene) (PEDOT), or PEDOT/poly(styrene sulphonate) (PSS). 17. A method of forming a microelectronic package for use in an electronic device, wherein the method comprises: identifying, in a substrate of the microelectronic package, a ground path that electrically couples a signal path and a ground connection; and positioning, in the ground path between the signal path and the ground connection, an electrostatic discharge (ESD) protection material that includes: two electrically-conductive carbon allotropes that are electrically coupled with one another by a first electrically-conductive polymer that is chemically functionalized with the electrically-conductive carbon allotropes; and a non-conductive polymer matrix that is chemically functionalized with the electrically-conductive carbon allotropes by a second electrically-conductive polymer. 18. The method of claim 17 , wherein positioning the ESD protection material in the ground path includes stencil printing, spray depositing, or ink-jet printing the ESD protection material to the substrate. 19. The method of claim 17 , wherein the electrically-conductive carbon allotropes are carbon fibers. 20. The method of claim 17 , wherein the first electrically-conductive polymer is polypyrrole.
Insulating or insulated package substrates; Interposers; Redistribution layers (leadframes H10W70/40) · CPC title
Applying pastes or inks, e.g. screen printing (H10W70/095 takes precedence) · CPC title
protecting against electrostatic charges or discharges, e.g. Faraday shields (integrated devices comprising arrangements for electrical protection H10D89/60) · CPC title
Carbon-based materials, e.g. fullerenes · CPC title
with a five-membered ring containing one sulfur atom in the ring · CPC title
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