System for producing a lightweight thermoplastic composite sheet

Patent metadata

Field	Value
Publication number	US-11090839-B2
Application number	US-201916460661-A
Country	US
Kind code	B2
Filing date	Jul 2, 2019
Priority date	Jul 2, 2019
Publication date	Aug 17, 2021
Grant date	Aug 17, 2021

Abstract

A thermoplastic composite sheet may be composed of a polymer material matrix and a lightweight material that is disposed throughout the polymer material matrix. The polymer material matrix may extend continuously throughout a length, width, and thickness of the thermoplastic composite sheet. The polymer material matrix may be a fully polymerized thermoplastic material. The lightweight material may be fully saturated by the thermoplastic material of the polymer material matrix. The thermoplastic composite sheet may include between 50 and 99 weight percent of the thermoplastic material and between 1 and 50 weight percent of the lightweight material. The thermoplastic composite sheet may be free of reinforcing fibers.

First claim

What is claimed is:

1. A system for manufacturing a thermoplastic composite sheet, the system comprising:
a double belt mechanism that includes an upper belt and a lower belt, the upper belt being positioned atop the lower belt and the lower belt having a longitudinal length that is substantially longer than the upper belt, the double belt mechanism being configured to compress materials that are passed through the double belt mechanism;
a lightweight material application mechanism that is positioned atop the lower belt, the lightweight material application mechanism being configured to apply a lightweight material atop the lower belt to form a layer of lightweight material atop the lower belt;
a resin applicator that is positioned atop the lower belt, the resin applicator being configured to apply a resin to the layer of lightweight material;
an oven that is configured to heat the resin as the lightweight material and the resin are moved through the oven in order to polymerize the resin or melt the resin; and
a cooling mechanism that is configured to cool the resin and lightweight material to form the thermoplastic composite sheet; wherein:
the double belt mechanism compresses the lightweight material and the resin as the lightweight material and resin are passed through the oven such that the resin is dispersed throughout the layer of lightweight material and saturates the lightweight material;
the lightweight material has a density of between 0.1 and 1.0 g/cm 3 ; and
the thermoplastic composite sheet is substantially free of reinforcing fibers.

2. The system of claim 1 , wherein the lightweight material application mechanism and the resin applicator are positioned adjacent one another so that the lightweight material and the resin are dispersed simultaneously atop the lower belt such that the resin is dispersed throughout the layer of lightweight material.

3. The system of claim 1 , wherein the resin applicator is a fiber chopper or a fiber scattering device that is configured to disperse polymer resin fibers atop the lower belt to form a web or mesh of polymer resin fibers, wherein the polymer resin fibers are configured to melt within the oven to enable the resin to be mixed with and dispersed throughout the layer of lightweight material.

4. The system of claim 3 , wherein the lightweight material application mechanism is positioned adjacent the fiber chopper or fiber scattering device so that the lightweight material is applied atop the lower belt as the polymer resin fibers are dispersed atop the lower belt, or wherein the fiber scattering device is configured to disperse the polymer resin fibers and simultaneously apply the lightweight material atop the lower belt such that the fiber scattering device functions as both the lightweight material application mechanism and the resin applicator.

5. The system of claim 1 , wherein the resin applicator is a roller about which a thermoplastic resin film is wound, and wherein the resin is applied to the lightweight material by unrolling the thermoplastic resin film atop the lower belt such that the thermoplastic resin film is positioned under the lightweight material, atop the lightweight material, or both under and atop the lightweight material.

6. The system of claim 1 , wherein the resin applicator is an extruder device that is configured to extrude a molten thermoplastic resin sheet atop the lightweight material or that is configured to extrude a molten thermoplastic resin sheet that includes the lightweight material.

7. The system of claim 1 , wherein the resin applicator is a powder application device that is configured to apply a powder thermoplastic resin to the layer of lightweight material.

8. The system of claim 7 , wherein the powder application device is configured to apply a powder lightweight material simultaneously with the powder thermoplastic resin such that the powder application device functions as both the lightweight material application mechanism and the resin applicator.

9. The system of claim 1 , wherein the resin comprises one or more of the following thermoplastic resins: polyolefins, polypropylene (PP), high-density polyethylene (HDPE), polyamides, polyethylene terephthalate (PET), polybutylene terephthalate (PBT), polycarbonate (PC), polyphthalamide (PPA), acrylonitrile-butadiene-styrene (ABS), PC/ABS, thermoplastic polyurethane (TPU), polyphenylene sulfide (PPS), acetal (polyoxymethylene or POM), polyethyleneimine (PEI), polyether ether ketone (PEEK), polyacrylonitrile, copolyacrylonitriles including poly(styrene-co-acrylonitrile) (SAN), or combinations thereof.

10. The system of claim 1 , wherein the system further comprises a drying mechanism that is configured to remove residual moisture from the lightweight material as the lightweight material is moved past the drying mechanism.

11. The system of claim 1 , wherein the resin applicator is a die that is configured to apply monomers or oligomers to the layer of lightweight material, wherein the monomers or oligomers are polymerizable via the oven to form a polymer material matrix within which the lightweight material is disposed.

12. The system of claim 11 , wherein the lightweight material is homogenously mixed with the monomers or oligomers, and wherein the die functions as both the resin applicator and the lightweight material application mechanism so that the resin and the lightweight material are simultaneously applied atop the lower belt to form the layer of lightweight material with the resin dispersed therein.

13. The system of claim 11 , wherein the system further comprises:
a drying mechanism that is configured to remove residual moisture from the lightweight material as the lightweight material is moved past the drying mechanism; and
a gas application mechanism that is positioned to blow a moisture-free gas onto one or more surfaces of the layer of lightweight material in order to substantially prevent exposure of the monomers or oligomers to ambient moisture in a surrounding environment.

14. The system of claim 11 , wherein the system further comprises a mixing component that mixes the monomers or oligomers with at least one of a catalyst and/or an activator, wherein the catalyst and/or activator facilitate in polymerizing the monomers or oligomers to form the polymer material matrix.

15. The system of claim 11 , wherein the monomers or oligomers comprises lactams, lactones, cyclic olefins, cyclic butylene terephthalate (CBT), methyl methacrylate (MMA), precursors of thermoplastic polyurethane, or mixtures thereof.

16. The system of claim 15 , wherein the lactams comprise caprolactam, laurolactam, or mixtures thereof.

17. The system of claim 1 , wherein the lightweight material includes a sizing composition having a coupling agent that promotes bonding between the lightweight material and the resin.

18. The system of claim 1 , wherein the system further comprises a cutting mechanism that cuts the thermoplastic composite sheet into individual sheets, the cutting mechanism being positioned after the oven.

19. The system of claim 1 , wherein the lightweight material comprises hollow glass microspheres, perlite, or a combination thereof.

Assignees

• Johns Manville

Inventors

• Zhang Mingfu
• Asrar Jawed

Classifications

• B29C70/58 Primary

  comprising fillers only {, e.g. particles, powder, beads, flakes, spheres (B29C70/025 takes precedence, agglomerating hollow spheres to produce synthetic foam B29C70/66; compounding ingredients per se C08K)} · CPC title

• C08J9/32

  from compositions containing microballoons, e.g. syntactic foams · CPC title

• B29C70/66 Primary

  the filler comprising hollow constituents, e.g. syntactic foam · CPC title

• B29K2509/08

  Glass · CPC title

• B29K2995/0063

  Density · CPC title