System for producing a fully impregnated thermoplastic prepreg

Patent metadata

Field	Value
Publication number	US-10683406-B2
Application number	US-201715728403-A
Country	US
Kind code	B2
Filing date	Oct 9, 2017
Priority date	Jul 8, 2015
Publication date	Jun 16, 2020
Grant date	Jun 16, 2020

Abstract

Fiber-containing polymethyl methacrylate (PMMA) prepregs are described that include a first and second plurality of fibers. The second plurality of fibers is made from a different material than the first plurality of fibers. The PMMA prepregs also contain a polymerized resin that includes polymethyl methacrylate that has been formed from a reactive resin composition that includes methyl methacrylate. Methods of making fiber-containing PMMA prepregs are also described.

First claim

What is claimed is:

1. A fiber-containing polymethyl methacrylate prepreg comprising:
a first plurality of fibers;
a second plurality of fibers made from a different material than the first plurality of fibers; and
a polymerized thermoplastic matrix resin comprising polymethyl methacrylate, wherein the polymerized thermoplastic matrix resin is formed from a reactive resin composition comprising methyl methacrylate, wherein the first plurality of fibers are formed into a first fiber mat or fabric and the second plurality of fibers are formed into a second fiber mat or fabric, and further wherein the first fiber mat or fabric and the second fiber mat or fabric are stacked on top of each other.

2. The fiber-containing polymethyl methacrylate prepreg of claim 1 , wherein at least one of the first plurality of fibers and the second plurality of fibers are reactive fibers with a reactive agent present on the surface of the reactive fibers.

3. The fiber-containing polymethyl methacrylate prepreg of claim 1 , wherein the first plurality of fibers comprises fibers selected from the group consisting of glass fibers, inorganic fibers, carbon fibers, metal fibers, organic polymer fibers, and mineral fibers.

4. The fiber-containing polymethyl methacrylate prepreg of claim 1 , wherein the second plurality of fibers comprises fibers selected from the group consisting of glass fibers, inorganic fibers, carbon fibers, metal fibers, organic polymer fibers, and mineral fibers.

5. The fiber-containing polymethyl methacrylate prepreg of claim 1 , wherein the first plurality of fibers comprises glass fibers and the second plurality of fibers comprises carbon fibers.

6. The fiber-containing polymethyl methacrylate prepreg of claim 2 , wherein the first reactive agent present on the surface of the reactive fibers comprises:
a silane coupling moiety, and
a reactive acrylate or methacrylate moiety.

7. The fiber-containing polymethyl methacrylate prepreg of claim 1 , wherein the reactive resin composition further comprises an initiator.

8. The fiber-containing polymethyl methacrylate prepreg of claim 7 , wherein the initiator comprises an organic peroxide.

9. A fiber-containing polymethyl methacrylate prepreg comprising:
a stack of fiber mats in contact with a cured reactive resin composition,
wherein the stack of fiber mats comprise layers of a first fiber mat and a second fiber mat stacked on top of each other, and wherein the first fiber mat comprises a first plurality of fibers and the second fiber mat comprises a second plurality of fibers made of a different material than the first plurality of fibers, and
wherein the cured reactive resin composition comprises a polymerized methyl methacrylate monomers.

10. The fiber-containing polymethyl methacrylate prepreg of claim 9 , wherein the cured reactive resin composition is formed in the prepreg by pressing and heating the stack of fiber mats to a polymerization temperature for the reactive resin composition.

11. The fiber-containing polymethyl methacrylate prepreg of claim 9 , wherein the first plurality of fibers comprises fibers selected from the group consisting of glass fibers, inorganic fibers, carbon fibers, metal fibers, organic polymer fibers, and mineral fibers.

12. The fiber-containing polymethyl methacrylate prepreg of claim 9 , wherein the second plurality of fibers comprises fibers selected from the group consisting of glass fibers, inorganic fibers, carbon fibers, metal fibers, organic polymer fibers, and mineral fibers.

13. The fiber-containing polymethyl methacrylate prepreg of claim 9 , wherein the first plurality of fibers comprises glass fibers and the second plurality of fibers comprises carbon fibers.

14. The fiber-containing polymethyl methacrylate prepreg of claim 9 , wherein at least one of the first plurality of fibers and the second plurality of fibers are reactive fibers that have a reactive agent present on the surface of the fibers, wherein the reactive agent comprises:
a silane coupling moiety, and
a reactive acrylate or methacrylate moiety.

15. The fiber-containing polymethyl methacrylate prepreg of claim 9 , wherein the reactive resin composition further comprises an initiator.

16. The fiber-containing polymethyl methacrylate prepreg of claim 15 , wherein the initiator comprises an organic peroxide.

17. A fiber-reinforced composite article comprising:
a fiber-containing polymethyl methacrylate prepreg comprising:
(i) a first plurality of fibers;
(ii) a second plurality of fibers made from a different material than the first plurality of fibers; and
(iii) a polymerized thermoplastic matrix resin comprising the polymethyl methacrylate, wherein the polymerized thermoplastic matrix resin is formed from a reactive resin composition comprising methyl methacrylate, wherein the first plurality of fibers are formed into a first fiber mat or fabric and the second plurality of fibers are formed into a second fiber mat or fabric, and further wherein the first fiber mat or fabric and the second fiber mat or fabric are stacked on top of each other.

18. The fiber-reinforced composite article of claim 17 , wherein at least one of the first plurality of fibers and the second plurality of fibers are reactive fibers with a reactive agent present on the surface of the reactive fibers.

19. The fiber-reinforced composite article of claim 17 , wherein the first plurality of fibers comprises fibers selected from the group consisting of glass fibers, inorganic fibers, carbon fibers, metal fibers, organic polymer fibers, and mineral fibers.

20. The fiber-reinforced composite article of claim 17 , wherein the second plurality of fibers comprises fibers selected from the group consisting of glass fibers, inorganic fibers, carbon fibers, metal fibers, organic polymer fibers, and mineral fibers.

21. The fiber-reinforced composite article of claim 17 , wherein the first plurality of fibers comprises glass fibers and the second plurality of fibers comprises carbon fibers.

Assignees

• Johns Manville

Inventors

• Zhang Mingfu
• Gleich Klaus Friedrich
• Yohannes Asheber
• Block Michael John
• Asrar Jawed
• Bristol Derek Cooper
• Sandoval Christopher P

Classifications

• C08J5/047 Primary

  with mixed fibrous material · CPC title

• C08J5/247

  using fibres of at least two types · CPC title

• C08J5/249 Primary

  characterised by the additives used in the prepolymer mixture · CPC title

• C08J5/248

  using pre-treated fibres · CPC title

• C08J2377/02

  Polyamides derived from omega-amino carboxylic acids or from lactams thereof (C08J2377/10 takes precedence) · CPC title