Neutralized vinegar concentrates and liquid food grade blends containing said neutralized vinegar concentrates

Patent metadata

Field	Value
Publication number	US-11085013-B2
Application number	US-201816057534-A
Country	US
Kind code	B2
Filing date	Aug 7, 2018
Priority date	Mar 24, 2014
Publication date	Aug 10, 2021
Grant date	Aug 10, 2021

Abstract

The present invention is directed to a process for making a concentrated vinegar product by simple evaporation, which concentrated vinegar product can also be used as intermediate in the production of products that can be listed on food labels as “vinegar”.

First claim

The invention claimed is:

1. A process of producing a liquid neutralized vinegar concentrate having a dry solids level of 50-70% (w/w), comprising:
(a) providing a liquid vinegar;
(b) adding an alkaline potassium compound to the liquid vinegar to produce a neutralized vinegar having a pH between 7.5 and 9, wherein at least 50% of the total mol amount of the cations added is potassium; and
(c) concentrating the neutralized vinegar to an acetate salt level within the range of 50-70% (w/w) by evaporation.

2. The process according to claim 1 , wherein step (c) comprises heating of the neutralized vinegar to a temperature between 20-120° C.

3. The process according to claim 2 , wherein the neutralized vinegar is heated to a temperature between 40-110° C.

4. The process according to claim 1 , wherein the neutralized vinegar is concentrated to a dry solids level of 55-70% (w/v).

5. The process according to claim 4 , wherein the neutralized vinegar is concentrated to a dry solids level of 60-70% (w/v).

6. The process according to claim 1 , further comprising (d) cooling down the neutralized vinegar to a temperature between 0-35° C.

7. The process according to claim 1 , wherein the liquid vinegar contains at least 5% (w/w) acetic acid.

8. The process according to claim 7 , wherein the alkaline potassium compound and the vinegar are combined so that the (mol/mol) ratio of potassium cations to acetate anions in the neutralized vinegar is more than 0.5:1.

9. The process according to claim 1 , wherein the alkaline potassium compound is selected from potassium hydroxide, potassium carbonate, potassium bicarbonate and combinations thereof.

10. The process according to claim 9 , wherein the alkaline potassium compound is potassium hydroxide.

11. The process according to claim 10 , wherein the process comprises addition of an aqueous solution containing at least 100 g/l of potassium hydroxide.

12. The process according to claim 11 , wherein the process comprises addition of an aqueous solution containing at least 250 g/l of potassium hydroxide.

13. The process according to claim 10 , wherein step b) comprises the addition of potassium hydroxide and sodium hydroxide in a (mol/mol) ratio within the range of 3/1-100/1.

14. A process of producing a liquid food preservation product, comprising:
(a) providing a liquid vinegar;
(b) adding an alkaline potassium compound to the liquid vinegar to produce a neutralized vinegar having a pH of at least 6, wherein at least 50% of the total mol amount of the cations added is potassium;
(c) concentrating the neutralized vinegar to a dry solids level of 50-70% (w/w) by evaporation; and
(d) combining the concentrated neutralized vinegar with
(i) a fermentation product that is obtained by fermentation of a fermentable substrate with a lactic acid producing microorganism followed by separating supernatant from biomass and other solid particles and concentrating the supernatant, and/or
(ii) a fermentation product that is obtained by fermentation of a fermentable substrate with a propionic acid producing microorganism followed by separating supernatant from biomass and other solid particles and concentrating the supernatant, and/or
(iii) lemon juice concentrate containing at least 30% (w/w) of citric acid and/or a citric acid salt,

wherein the liquid food preservation product has a total acidity of at least 32% (w/w) and a total acidity based on acetic acid of at least 5% (w/w).

15. The process according to claim 14 , wherein the composition comprises a liquid crude vinegar of 200-300 grain.

16. The process according to claim 14 , wherein the composition comprises a lactate, a propionate, and/or a citrate component.

17. The process according to claim 16 , wherein the composition is obtainable by:
(i) providing a nutrient medium comprising a solution of a fermentable substrate and a nitrogen source in an aqueous medium;
(ii) inoculating the nutrient medium with a lactic acid or propionic acid producing microorganism;
(iii) incubating the inoculated nutrient medium under conditions favorable to the growth and/or metabolic activity of the lactic acid or propionic acid producing microorganism, for a period sufficient to produce a first fermentation broth containing a lactate component and/or a propionate component;
(iv) removing wet biomass from the first fermentation broth to obtain a supernatant; and, optionally, (v) subjecting the supernatant to further purification, with the proviso that the purification does not result in a level of the lactate and/or propionate component of more than 95 wt%, on a dry solids basis.

18. The process according to claim 14 , wherein the food preservation product has a final total concentration of acetate and acetic acid above 10% (w/w).

19. The process according to claim 18 , wherein the food preservation product has a final total concentration of acetate and acetic acid above 20% (w/w).

20. A process of producing a liquid food preservation product, comprising:
(a) providing a liquid vinegar;
(b) adding an alkaline potassium compound to the liquid vinegar to produce a neutralized vinegar having a pH of at least 6, wherein at least 50% of the total mol amount of the cations added is potassium;
(c) concentrating the neutralized vinegar to an acetate salt level within the range of 50-70% (w/w/) by evaporation to produce a liquid concentrated neutralized vinegar having a dry solids level of 50-70% (w/w); and
(d) combining the liquid concentrated neutralized vinegar with liquid crude vinegar of 200-300 grain.

Assignees

• Purac Biochem Bv

Inventors

• Roozen Lambertus Henricus Elisabeth
• Hilhorst Gerrit Anthon Rene
• Neubauer Anja

Classifications

• A23B2/783

  Microorganisms; Enzymes · CPC title

• A23B2/754

  containing carboxyl groups · CPC title

• A23B2/733

  Compounds of undetermined constitution obtained from animals or plants · CPC title

• A23B2/729

  Organic compounds; Microorganisms; Enzymes · CPC title

• C12J1/00 Primary

  Vinegar; Preparation or purification thereof · CPC title