Tungsten dissolution inhibitor, and polishing composition and composition for surface treatment using the same
US-2020095468-A1 · Mar 26, 2020 · US
US11060051B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11060051-B2 |
| Application number | US-201916595594-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 8, 2019 |
| Priority date | Oct 12, 2018 |
| Publication date | Jul 13, 2021 |
| Grant date | Jul 13, 2021 |
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To provide a composition for rinsing or cleaning a surface to which ceria particles are attached and a surface treatment method for removing ceria particles from the surface using the same.The composition according to the present invention contains an anionic surfactant, an organic amine compound, and a protic organic acid molecule and has a pH of less than 6.
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What is claimed is: 1. A composition comprising: an anionic surfactant represented by the following Formula (I): C m H 2m+1 —(OCH 2 CH 2 ) n -L-R (I), wherein: 6≤m≤20; n≥5; L represents an —O—, —S—, —R 1 —, —S—R 1 — or —O—R 1 — bond (wherein R 1 represents C 1-4 alkylene); and R represents at least one selected from the group consisting of a carboxy group and a salt thereof; an organic amine compound; and a protic organic acid molecule, wherein the composition has a pH of less than 6. 2. The composition according to claim 1 , wherein: the organic amine compound is at least one selected from the group consisting of 2-(diethylamino)ethanethiol, captamine, diethylethanolamine, methylcysteamine, 2-(tert-butylamino)ethanethiol, 2,2′-dimethoxy-1,1-dimethyl-dimethylamine, 3-amino-4-octanol, 3-butoxypropylamine, N-acetylcysteamine, homocysteamine, N,N-dimethylhydroxylamine, 2-(isopropylamino)ethanol, 2-(methylthioethyl)amine, 1-aminopropane-2-thiol, leucinol, cysteamine, and N,O-dimethylhydroxylamine; and the protic organic acid molecule is at least one selected from the group consisting of glyphosin, N-(phosphonomethyl)iminodiacetic acid hydrate, hydroxyphosphonoacetic acid, citric acid, hydroxyethane-1,1-diphosphonic acid, and 2-phosphonobutane-1,2,4-tricarboxylic acid. 3. The composition according to claim 1 , wherein the organic amine compound has a sum of electronegativity gradients (SENG) of greater than −1.0, the protic organic acid molecule has at least one dissociated complexing functional group, and a density of binding modes (DBM) for the functional group(s) of the molecule is 0.013 or more. 4. The composition according to claim 1 , wherein 5≤n≤12 in the Formula (I). 5. The composition according to claim 1 , wherein the anionic surfactant is at least one selected from the group consisting of capryleth-9 carboxylic acid or a salt thereof. 6. The composition according to claim 1 , wherein the organic amine compound is at least one selected from the group consisting of 3-amino-4-octanol, cysteamine, N,N-dimethylhydroxylamine, and N,O-dimethylhydroxylamine. 7. The composition according to claim 1 , wherein the protic organic acid molecule is at least one selected from the group consisting of hydroxyethane-1,1-diphosphonic acid and 2-phosphonobutane-1,2,4-tricarboxylic acid. 8. The composition according to claim 1 , which is used for cleaning or rinsing a surface to which ceria particles are attached. 9. A surface treatment method for removing ceria particles from a surface to which the ceria particles are attached, the surface treatment method comprising a step of bringing the surface into contact with the composition according to claim 1 .
the processing being a planarisation of insulating layers · CPC title
Cleaning during device manufacture · CPC title
Phosphonates, phosphinates or phosphonites · CPC title
pH regulated compositions · CPC title
Hydroxides or bases · CPC title
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