Support material for 3D printing of polymer compounds

Patent metadata

Field	Value
Publication number	US-11001049-B2
Application number	US-201615542357-A
Country	US
Kind code	B2
Filing date	Jan 11, 2016
Priority date	Jan 12, 2015
Publication date	May 11, 2021
Grant date	May 11, 2021

Abstract

Cyclic olefin copolymer (COC) and cyclic olefin polymer (COP) are useful as support material for 3D printing of high temperature polymers, such as polyimides.

First claim

What is claimed is:

1. A scaffold built by a support material during 3D polyimide printing comprising cyclic olefin copolymer or cyclic olefin polymer.

2. The scaffold of claim 1 , wherein the cyclic olefin copolymer (COC) is a copolymer of cyclic olefin monomers with alkenes.

3. The scaffold of claim 2 , wherein the cyclic olefin copolymer is ethylene-norbornene copolymer.

4. The scaffold of claim 3 , wherein the ethylene-norbornene copolymer has the following structure:

wherein X ranges from about 40 wt. % to about 20 wt. % and wherein Y ranges from about 60 wt. % to about 80 wt. %.

5. The scaffold of claim 3 , wherein the ethylene-norbornene copolymer has the following structure:

wherein X ranges from about 25 wt. % to about 18 wt. % and wherein Y ranges from about 75 wt. % to about 82 wt. %.

6. The scaffold of claim 3 , wherein the cyclic olefin copolymer has a weight average molecular weight (Mw) ranging from about 40,000 to about 130,000, a heat deflection temperature ranging from about 30° C. to about 170° C. at 0.45 MPa (66 psi load).

7. The scaffold of claim 1 , wherein the cyclic olefin polymer (COP) are polymers which have undergone ring-opening metathesis polymerization from cyclic monomers followed by hydrogenation, wherein the cyclic monomers comprise norbornene or tetracyclododecene.

8. The scaffold of claim 1 , wherein the scaffold further comprises optical brighteners, impact modifiers, process aids, rheology modifiers, thermal and UV stabilizers, fluorescent and non-fluorescent dyes and pigments, radio-opaque tracers, conductive additives (both thermal and electrical), inductive heating additives, non-silicone releases; and combinations of them.

9. The scaffold of claim 1 , wherein the scaffold also comprises styrenic block copolymer as an impact modifier for the scaffold.

10. A 3D printed polymer article comprising polyimide as a build material and the support material of claim 1 .

11. The 3D printed polymer article of claim 10 , wherein the support material further comprises optical brighteners, impact modifiers, process aids, rheology modifiers, thermal and UV stabilizers, fluorescent and non-fluorescent dyes and pigments, radio-opaque tracers, conductive additives (both thermal and electrical), inductive heating additives, and non-silicone releases; and combinations of them.

12. The support material of claim 11 , wherein the support material also comprises styrenic block copolymer as an impact modifier for the support material.

13. A method of using the support material of claim 1 , comprising the steps of 3D printing both polyimide as a build material and the support material of claim 1 .

14. The method of claim 13 , wherein the support material further comprises optical brighteners, impact modifiers, process aids, rheology modifiers, thermal and UV stabilizers, fluorescent and non-fluorescent dyes and pigments, radio-opaque tracers, conductive additives (both thermal and electrical), inductive heating additives, and non-silicone releases; and combinations of them.

15. The method of claim 14 , wherein the support material also comprises styrenic block copolymer as an impact modifier for the support material.

16. A 3D printed polymer article comprising polyimide as a build material and the support material of claim 2 .

17. A 3D printed polymer article comprising polyimide as a build material and the support material of claim 3 .

18. A 3D printed polymer article comprising polyimide as a build material and the support material of claim 4 .

19. The 3D printed polymer article of claim 18 , wherein the support material further comprises optical brighteners, impact modifiers, process aids, rheology modifiers, thermal and UV stabilizers, fluorescent and non-fluorescent dyes and pigments, radio-opaque tracers, conductive additives (both thermal and electrical), inductive heating additives, and non-silicone releases; and combinations of them.

20. The support material of claim 18 , wherein the support material also comprises styrenic block copolymer as an impact modifier for the support material.

Assignees

• Polyone Corp
• Avient Corp

Inventors

• Avakian Roger W

Classifications

• B33Y70/00 Primary

  Materials specially adapted for additive manufacturing · CPC title

• C08F232/04 Primary

  having one carbon-to-carbon double bond · CPC title

• B33Y80/00 Primary

  Products made by additive manufacturing · CPC title

• Y10T428/24802

  Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] · CPC title

• C08L79/08

  Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors · CPC title