Semi-crystalline consumable materials for electrophotography-based additive manufacturing system

Patent metadata

Field	Value
Publication number	US-9785064-B2
Application number	US-201414905657-A
Country	US
Kind code	B2
Filing date	Jul 16, 2014
Priority date	Jul 17, 2013
Publication date	Oct 10, 2017
Grant date	Oct 10, 2017

Abstract

A part material for printing three-dimensional parts with an electrophotography-based additive manufacturing system, the part material including a composition having a semi-crystalline thermoplastic material and a charge control agent. The part material is provided in a powder form having a controlled particle size, and is configured for use in the electrophotography-based additive manufacturing system having a layer transfusion assembly for printing the three-dimensional parts in a layer-by-layer manner.

First claim

The invention claimed is:

1. A part material for printing three-dimensional parts with an electrophotography-based additive manufacturing system, the part material comprising:
a composition comprising:
a semi-crystalline thermoplastic material, wherein the semi-crystalline thermoplastic material comprises a polyamide, and wherein the polyamide comprises polycarpolactum (PA6), polyhexamethyleneaidpamide (PA6,6), polyhexamethylenenonamide (PA6,9), polyhexamethylenesebacamide (PA6,10), polyamide 6/12 (PA6,12), polyenantholactum (PA7), polyundecanolactum (PA11), polylaurolactam (PA12), or mixtures thereof; and
a charge control agent;

wherein the part material is provided in a powder form wherein the powder form also has a D90/D50 particle size distribution and a D50/D10 particle size distribution each ranging from about 1.00 to about 1.40; and
wherein the part material is configured for use in the electrophotography-based additive manufacturing system having a layer transfusion assembly for printing the three-dimensional parts in a layer-by-layer manner.

2. The part material of claim 1 , wherein the composition further comprises a heat absorber, wherein the heat absorber constitutes from about 0.5% by weight to about 10% by weight of the part material.

3. The part material of claim 1 , wherein the D50 particle size ranges from about 10 micrometers to about 20 micrometers.

4. The part material claim 1 , wherein the D50 particle size ranging from about 5 micrometers to about 30 micrometers.

5. The part material of claim 1 , wherein the charge control agent is selected from the group consisting of chromium oxy carboxylic acid complexes, zinc oxy carboxylic acid complexes, aluminum oxy carboxylic acid complexes, and mixtures thereof.

6. The part material of claim 1 , wherein the charge control agent constitutes from about 0.1% by weight to about 5% by weight of the part material.

7. The part material of claim 1 , wherein the composition further comprises a flow control agent constituting from about 0.1% by weight to about 10% by weight of the part material.

8. The part material of claim 1 , wherein the polyamide comprises PA6; PA6,6; PA6,12; PA11; polylaurolactam (PA12), or mixtures thereof.

9. A method for printing a three-dimensional part with an electrophotography-based additive manufacturing system having an electrophotography engine, a transfer medium, and a layer transfusion assembly, the method comprising:
providing a part material to the electrophotography-based additive manufacturing system, the part material compositionally comprising a charge control agent, and a semi-crystalline thermoplastic material wherein the semi-crystalline thermoplastic material comprises the polyamide, and wherein the polyamide comprises polycarpolactum (PA6), polyhexamethyleneaidpamide (PA6,6), polyhexamethylenenonamide (PA6,9), polyhexamethylenesebacamide (PA6,10), polyamide 6/12 (PA6,12), polyenantholactum (PA7), polyundecanolactum (PA11), polylaurolactam (PA12), or mixtures thereof, and has a powder form;
triboelectrically charging the part material to a Q/M ratio having a negative charge or a positive charge, and a magnitude ranging from about 5 micro-Coulombs/gram to about 50 micro-Coulombs/gram;
developing layers of the three-dimensional part from the charged part material with the electrophotography engine;
electrostatically attracting the developed layers from the electrophotography engine to the transfer medium;
moving the attracted layers to the layer transfusion assembly with the transfer medium; and
transfusing the moved layers to previously-printed layers of the three-dimensional part with the layer transfusion assembly.

10. The method of claim 9 , wherein the powder form of the part material has a D50 particle size ranging from about 5 micrometers to about 30 micrometers, and a D90/D50 particle size distribution and a D50/D10 particle size distribution each ranging from about 1.00 to about 1.40.

11. The method of claim 9 , wherein the charge control agent constitutes from about 0.1% by weight to about 5% by weight of the part material, and wherein the heat absorber constitutes from about 0.5% by weight to about 10% by weight of the part material.

12. The method of claim 9 , wherein the part material further comprises a flow control agent constituting from about 0.1% by weight to about 10% by weight of the part material.

13. The method of claim 9 , wherein the polyamide comprises PA6; PA6,6; PA6,12; PA11; polylaurolactam (PA12), or mixtures thereof.

14. A part material for printing three-dimensional parts with an electrophotography-based additive manufacturing system, the part material comprising:
a composition comprising:
a semi-crystalline thermoplastic material, wherein the semi-crystalline thermoplastic material comprises the polyaryletherketone, and wherein the polyaryletherketone comprises polyetherketone (PEK), polyetheretherketone (PEEK), polyetheretherketoneketone (PEEKK), polyetherketoneetherketoneketone (PEKEKK), or mixtures thereof; and
a charge control agent;

wherein the part material is provided in a powder form wherein the powder form also has a D90/D50 particle size distribution and a D50/D10 particle size distribution each ranging from about 1.00 to about 1.40; and
wherein the part material is configured for use in the electrophotography-based additive manufacturing system having a layer transfusion assembly for printing the three-dimensional parts in a layer-by-layer manner.

15. The part material of claim 14 , wherein the polyaryletherketone comprises polyetheretherketone (PEEK).

16. The part material of claim 14 , wherein the composition further comprises a heat absorber, wherein the heat absorber constitutes from about 0.5% by weight to about 10% by weight of the part material.

17. The part material of claim 14 , wherein the D50 particle size ranges from about 10 micrometers to about 20 micrometers.

18. The part material claim 14 , wherein the D50 particle size ranging from about 5 micrometers to about 30 micrometers.

19. The part material of claim 14 , wherein the charge control agent is selected from the group consisting of chromium oxy carboxylic acid complexes, zinc oxy carboxylic acid complexes, aluminum oxy carboxylic acid complexes, and mixtures thereof.

20. The part material of claim 14 , wherein the charge control agent constitutes from about 0.1% by weight to about 5% by weight of the part material.

21. The part material of claim 14 , wherein the composition further comprises a flow control agent constituting from about 0.1% by weight to about 10% by weight of the part material.

Assignees

• Stratasys Inc

Inventors

• Orrock James E
• Chillscyzn Steven A
• Martin Trevor I

Classifications

• B33Y70/10

  Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials · CPC title

• B33Y10/00

  Processes of additive manufacturing · CPC title

• G03G15/224

  Machines for forming tactile or three dimensional images by electrographic means, e.g. braille, 3d printing · CPC title

• G03G9/09775

  containing atoms other than carbon, hydrogen or oxygen (G03G9/09741 - G03G9/09766 take precedence) · CPC title

• G03G9/08766

  Polyamides, e.g. polyesteramides · CPC title