Magnetodielectric y-phase strontium hexagonal ferrite materials formed by sodium substitution

Patent metadata

Field	Value
Publication number	US-10984928-B2
Application number	US-201816030375-A
Country	US
Kind code	B2
Filing date	Jul 9, 2018
Priority date	Oct 24, 2014
Publication date	Apr 20, 2021
Grant date	Apr 20, 2021

Abstract

Disclosed herein are embodiments of an enhanced resonant frequency hexagonal ferrite material and methods of manufacturing. The hexagonal ferrite material can be Y-phase strontium hexagonal ferrite material. In some embodiments, sodium can be added into the crystal structure of the hexagonal ferrite material in order to achieve high resonance frequencies while maintaining high permeability.

First claim

What is claimed is:

1. A modified sodium substituted strontium hexagonal ferrite comprising:
a Y-phase strontium hexagonal ferrite crystal structure including elements strontium, sodium, cobalt, iron, oxygen and one of a tetravalent ion and a trivalent ion, the at least one of the tetravalent ion and the trivalent ion configured to charge balance for the sodium substituting at least partially for the strontium in the crystal structure; and
a permeability of between 5 and 6.

2. The modified sodium substituted strontium hexagonal ferrite of claim 1 wherein the crystal structure contains the trivalent ion.

3. The modified sodium substituted strontium hexagonal ferrite of claim 2 wherein greater than zero and less than or equal to 1.5 of the trivalent ion is included in the crystal structure.

4. The modified sodium substituted strontium hexagonal ferrite of claim 2 wherein the trivalent ion is selected from the group consisting of Al, Ga, Sc, Cr, Mn, In, Yb, Er, Y and the other lanthanide elements.

5. The modified sodium substituted strontium hexagonal ferrite of claim 4 wherein the trivalent ion is scandium.

6. The modified sodium substituted strontium hexagonal ferrite of claim 1 wherein the crystal structure contains the tetravalent ion.

7. The modified sodium substituted strontium hexagonal ferrite of claim 6 wherein greater than zero and less than or equal to 0.75 of the tetravalent ion is included in the crystal structure.

8. The modified sodium substituted strontium hexagonal ferrite of claim 6 wherein the tetravalent ion is selected from the group consisting of Si, Ge, Ti, Zr, Sn, Ce, Pr, Hf, and Tb.

9. The modified sodium substituted strontium hexagonal ferrite of claim 1 wherein the modified sodium substituted strontium hexagonal ferrite has a composition Sr 1.75 Na 0.25 Co 1.75 M 0.25 Fe 12 O 22 , M being the trivalent ion.

10. The modified sodium substituted strontium hexagonal ferrite of claim 1 wherein the modified sodium substituted strontium hexagonal ferrite has a composition Sr 1.5 Na 0.5 Co 1.5 M 0.5 Fe 12 O 22 , M being the trivalent ion.

11. An antenna comprising:
a Y-phase strontium hexagonal ferrite crystal structure including elements strontium, sodium, cobalt, iron, oxygen and one of a tetravalent ion and a trivalent ion, the at least one of the tetravalent ion and the trivalent ion configured to charge balance for the sodium substituting at least partially for the strontium in the crystal structure; and
a permeability of between 5 and 6.

12. The antenna of claim 11 wherein the modified sodium substituted strontium hexagonal ferrite has a composition Sr 1.75 Na 0.25 Co 1.75 M 0.25 Fe 12 O 22 , M being the trivalent ion.

13. The antenna of claim 11 wherein the modified sodium substituted strontium hexagonal ferrite has a composition Sr 1.5 Na 0.5 Co 1.5 M 0.5 Fe 12 O 22 , M being the trivalent ion.

14. The antenna of claim 11 wherein the trivalent ion is incorporated into the crystal structure, the trivalent ion being scandium.

15. A radiofrequency device incorporating the antenna of claim 11 .

16. A method for improving properties of a hexagonal ferrite material, the method comprising:
providing a Y-phase strontium hexagonal ferrite with a crystal structure having strontium, cobalt, iron, and oxygen;
substituting at least some of the strontium out of the crystal structure and replacing it with sodium; and
charge balancing the hexagonal ferrite material by incorporating one of a tetravalent ion and a trivalent ion into the crystal structure to form a modified hexagonal ferrite material having a permeability of between 5 and 6.

17. The method of claim 16 wherein the modified hexagonal ferrite has a composition Sr 1.75 Na 0.25 Co 1.75 M 0.25 Fe 12 O 22 , M being the trivalent ion.

18. The method of claim 16 wherein the modified hexagonal ferrite has a composition Sr 1.5 Na 0.5 Co 1.5 M 0.5 Fe 12 O 22 , M being the trivalent ion.

19. The method of claim 16 wherein the trivalent ion is incorporated into the crystal structure, the trivalent ion being scandium.

20. The method of claim 16 wherein the crystal structure contains the trivalent ion, and the trivalent ion is selected from the group consisting of Al, Ga, Sc, Cr, Mn, In, Yb, Er, Y and the other lanthanide elements. .

Assignees

• Skyworks Solutions Inc

Inventors

• Hill Michael David

Classifications

• C04B35/2683

  Other ferrites containing alkaline earth metals or lead · CPC title

• C04B35/26

  based on ferrites · CPC title

• H01F1/348 Primary

  Hexaferrites with decreased hardness or anisotropy, i.e. with increased permeability in the microwave (GHz) range, e.g. having a hexagonal crystallographic structure · CPC title

• H01F1/10

  non-metallic substances, e.g. ferrites {, e.g. [(Ba,Sr)O(Fe2O3)6] ferrites with hexagonal structure} · CPC title

• C04B35/2633

  containing barium, strontium or calcium · CPC title