Polymer composition and sterilizable articles obtainable therefrom

Patent metadata

Field	Value
Publication number	US-10961350-B2
Application number	US-201615580562-A
Country	US
Kind code	B2
Filing date	Jun 7, 2016
Priority date	Jun 10, 2015
Publication date	Mar 30, 2021
Grant date	Mar 30, 2021

Abstract

The invention relates to a composition [composition (C)] comprising a poly(biphenyl ether sulfone) polymer [polymer (P)] and selected metal oxides in specific amounts. Composition (C) can be advantageously used for the manufacture of sterilizable shaped articles.

First claim

The invention claimed is:

1. A composition (C) comprising:
(a) a poly(biphenyl ether sulfone) polymer (P) in an amount of at most 99 wt. % and at least 80 wt. % of with respect to the weight of the composition (C);
(b) calcium oxide (CaO) and/or magnesium oxide (MgO), optionally in combination with other metal oxides;
wherein:
the composition (C) does not include a polyether imide polymer;
the CaO, alone or in combination with the MgO and/or with the other metal oxides is in an amount from 1 wt. % to 6 wt. % with respect to the total weight of the composition (C); and
the MgO is in an amount from 1 wt. % to 6 wt. % with respect to the total weight of the composition (C), provided that when the composition (C) does not include the CaO, the amount of the MgO is at least 2 wt. % and up to 6 wt. % with respect to the total weight of the composition (C),

wherein the poly(biphenyl ether sulfone) polymer (P) is a homopolymer or copolymer in which substantially all recurring units of polymer (P) are recurring) selected from the group consisting of formulae (B) to (F), and mixtures thereof:

2. The composition according to claim 1 , wherein all the recurring units (R a ) of the poly(biphenyl ether sulfone) polymer (P) are of formula (B).

3. The composition according to claim 1 , further comprising a polymer selected from polyacetals, ethylvinyl acetate, polyolefins, liquid crystal polymers, polyamides, polycarbonates, poly(etherketones), poly(etheretherketones), poly(etherketoneketones), polymethyl methacrylate, polystyrene, polyurethane, polyvinyl chloride, silicone elastomers, polytetrafluoroethylene, and mixtures thereof.

4. The composition according to claim 1 comprising 4% by weight of the CaO.

5. The composition according to claim 1 comprising 2% by weight of the CaO and 2% by weight of the MgO.

6. The composition according to claim 1 comprising 1% by weight of the CaO and 1% by weight of the MgO.

7. The composition according to claim 1 comprising 4% by weight of a mixture of the MgO and Al 2 O 3 .

8. A shaped article comprising the composition of claim 1 .

9. The article according to claim 8 , which is selected from a medical article, a food handling or food preparation article, and a beverage handling or beverage preparation article.

10. A method for sterilizing the shaped article of claim 8 , which comprises submitting the article to hydrogen peroxide gas plasma sterilization.

11. The shaped article according to claim 8 , wherein the shaped article has been subjected to at least one hydrogen peroxide gas plasma sterilization process.

12. The composition of claim 1 , wherein an article made from the composition (C) and subjected to 50 hydrogen peroxide gas plasma sterilizations of 47 minutes each exhibits an overall color difference (DE) and a change in yellowness (Db) of less than 5.5, wherein DE and Db are calculated according to CIE 1976 (L*, a*, b*) color space indexes measured according to ASTM E308-08.

13. The composition of claim 1 , wherein the CaO and/or MgO in the composition (C) have an average particle size up to about 5 microns and a BET surface area of 1.5-160 m 2 /g.

14. The composition of claim 1 , wherein the polymer (P) is in an amount of at least 90 wt. % with respect to the weight of the composition (C).

15. A composition (C) comprising:
(a) a poly(biphenyl ether sulfone) polymer (P);
(b) calcium oxide (CaO) and/or magnesium oxide (MgO), optionally in combination with other metal oxides;
wherein:
the CaO, alone or in combination with the MgO and/or with the other metal oxides is in an amount from 1 wt. % to 6 wt. % with respect to the total weight of the composition (C); and
the MgO is in an amount from 1 wt % to 6 wt. % with respect to the total weight of the composition (C), provided that when the composition (C) does not include the CaO, the amount of the MgO is at least 2% wt. and up to 6 wt. % with respect to the total weight of the composition (C),

wherein the CaO and/or MgO in the composition (C) have an average particle size up to about 5 microns and a BET surface area of 1.5-160 m 2 /g,
wherein the poly(biphenyl ether sulfone) polymer (P) is a homopolymer or copolymer in which substantially all recurring units of polymer (P) are recurring units (R a ) of formula (A):
Ar 1 -(T-Ar 2 ) n —O—Ar 3 —SO 2 —[Ar 4 -(T-Ar 2 ) n —SO 2 ] m —Ar 5 —O—  (formula A)

wherein:
Ar 1 , Ar 2 , Ar 3 , Ar 4 , and Ar 5 , equal to or different from each other and at each occurrence, are independently an aromatic mono- or polynuclear cyclic group;

with the proviso that at least one Ar 1 through Ar 5 is an aromatic moiety comprising at least one biphenylene group;
each of T, equal to or different from each other, is selected from the group consisting of a bond, —CH 2 —; —O—; —SO 2 —; —S—; —C(CH 3 ) 2 —; —C(CF 3 ) 2 —; —C(═CCl 2 )—;

—C(CH 3 )(CH 2 CH 2 COOH)—; —N═N—; —R 1 C═CR 2 —; wherein each R 1 and R 2 , independently of one another, is hydrogen or a C 1 -C 12 -alkyl, C 1 -C 12 -alkoxy, or C 6 -C 18 -aryl group; —(CH 2 ) n — and —(CF2) n′ -with n′=integer from 1 to 6, or an aliphatic linear or branched divalent group of up to 6 carbon atoms;
n and m, equal to or different from each other, are independently zero or an integer of 1 to 5.

16. The composition of claim 15 , wherein the recurring units (R a ) in the poly(biphenyl ether sulfone) polymer (P) are selected from the group consisting of formulae (B) to (F), and mixtures thereof:

17. The composition according to claim 16 , wherein the recurring units (R a ) of the poly(biphenyl ether sulfone) polymer (P) are of formula (B).

18. The composition of claim 15 , wherein the polymer (P) is in an amount of at most 99 wt. % and at least 80 wt. % with respect to the weight of the composition (C).

19. A shaped article comprising the composition of claim 15 , which is selected from a medical article, a food handling or food preparation article, and a beverage handling or beverage preparation article.

20. A method for manufacturing a sterilized shaped article, which comprises submitting the shaped article of claim 18 to hydrogen peroxide gas plasma sterilization.

Assignees

• Solvay Specialty Polymers Usa
• Solvay Specialty Polymers Usa Inc

Inventors

• Momtaz Maryam
• Bushelman Corinne

Classifications

• A61L2103/15

  Laboratory, medical or dentistry appliances, e.g. catheters or sharps · CPC title

• C08L81/00 Primary

  Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers · CPC title

• C08K2003/2217

  of magnesium · CPC title

• C08K3/22

  of metals · CPC title

• C08K2201/014

  Additives containing two or more different additives of the same subgroup in C08K · CPC title