Articles comprising a resistor comprising core shell liquid metal encapsulates and method of detecting an impact

Patent metadata

Field	Value
Publication number	US-10900848-B2
Application number	US-201916580548-A
Country	US
Kind code	B2
Filing date	Sep 24, 2019
Priority date	Nov 2, 2018
Publication date	Jan 26, 2021
Grant date	Jan 26, 2021

Abstract

Articles and methods of detecting an impact on an article using a resistor containing core shell liquid metal encapsulates are disclosed. Such core shell liquid metal encapsulates enable simple but robust impact sensors as such encapsulates comprise a highly electrically resistant metal oxide shell that prevents such encapsulates from coalescing. Yet when such shell is ruptured, the highly conductive bulk liquid metal is released. Such liquid metal changes electrical properties of a sensor comprising core shell liquid metal encapsulates which in turn is evidence of the aforementioned impact.

First claim

What is claimed is:

1. A method of detecting an impact on a surface, said method comprising:
a) measuring a change in a resistor's resistance or a change in a system triggered by said change in said resistor's resistance, said resistor comprising a plurality of encapsulates that comprise a liquid metal core, and a metal oxide shell that encapsulates said core, said change in said resistor's resistance being caused at least in part by a change in the momentum of at least a portion said plurality of encapsulates as a result of an impact; and
b) using said change in said resistor's resistance and/or change in said system triggered by said change in said resistor's resistance as confirmation of said impact on said surface.

2. A method of detecting an impact according to claim 1 wherein said change in the resistance of said resistor is from about 0.00001 to about 15 orders of magnitude.

3. A method of detecting an impact according to claim 1 wherein said encapsulates are from about 5 nanometers to about 5 millimeters in diameter.

4. A method of detecting an impact according to claim 1 wherein said encapsulates have a shell thickness from about 0.5 nanometers to about 20 nanometers.

5. A method of detecting an impact according to claim 1 wherein said liquid metal core comprises a liquid metal selected from the group consisting of Hg, Pb, Sn, Sb, Cd, Bi, Ga, In, Al, Zn, Ag, Au, Tl and mixtures thereof.

6. A method of detecting an impact according to claim 1 wherein said liquid metal core comprises a liquid metal alloy selected from the group consisting of Ga/In, Ga/In/Sn, Ga/In/Sn/Sb, In/Sn/Bi, Bi/Pb/Sn, Bi/Pb/Sn/Cd, Bi/Pb/Sn/Cd/In and mixtures thereof.

7. A method of detecting an impact according to claim 1 wherein said shell comprises a metal oxide comprising a cation derived from a metal selected from the group consisting of Ga, In, Sn, Pb, Sb, Cd, Al, Zn, Tl, Bi, Ca, Sc, Ti, V, Cr, Sr, Y, Zr, Nb, Mo, Te, Gd, Hf, Pr, Nd, Pt, Sm, Eu, Dy, Ho, Er, Yb and mixtures thereof.

8. A method of detecting an impact according to claim 1 wherein said encapsulates comprise one or more ligands covalently or coordinatively bound to said shell's external surface.

9. A method of detecting an impact according to claim 1 wherein said resistor is a component of said system.

10. A method of detecting an impact according to claim 1 wherein said resistor is selected from the group consisting of:
a) a resistor comprising a composite comprising a matrix material and said plurality of encapsulates that comprise a liquid metal core, and a metal oxide shell that encapsulates said core, said encapsulates being embedded in said matrix material;
b) a resistor that is encapsulated with a protective material;
c) a resistor wherein one or more of said encapsulates are covalently bound to a matrix material through one or more ligands which are covalently or coordinatively bound to said encapsulates' shell's external surface;
d) a resistor wherein one or more of said encapsulates are chemically bound via a linkage comprising the ligands of said encapsulates to the external shell of an encapsulate other than the external shell of the encapsulate to which said ligand was originally covalently bound.

11. A method of detecting an impact according to claim 1 wherein said change in said system triggered by said change in said resistor's resistance is a change in voltage, resistance, current, impedance, and/or capacitance.

12. A method of detecting an impact according to claim 1 wherein said system comprises an antenna, a transmission line, a wave guide, an optical coating and/or a frequency selective surface.

13. A method of detecting an impact according to claim 1 wherein said resistor releases a charge in response to said impact.

14. An article comprising a resistor, said resistor comprising a plurality of encapsulates that comprise a liquid metal core, and a metal oxide shell that encapsulates said core, said encapsulates comprising one or more ligands covalently or coordinatively bound to said shell's external surface, said ligands comprising a head group that comprises a material selected from the group consisting of thiols, amines, phosphonic acids, alkoxysilanes, halosilanes, carboxylic acids, nitriles, and mixtures thereof.

15. An article according to claim 14 , wherein said resistor is selected from the group consisting of:
a) a resistor comprising a composite comprising a matrix material and said plurality of encapsulates that comprise a liquid metal core, and a metal oxide shell that encapsulates said core, said encapsulates being embedded in said matrix material;
b) a resistor wherein one or more of said encapsulates are covalently bound to a matrix material through one or more ligands which are covalently or coordinatively bound to said encapsulates' shell's external surface; or
c) a resistor wherein one or more of said encapsulates are chemically bound via a linkage comprising the ligands of said encapsulates to the external shell of an encapsulate other than the external shell of the encapsulate to which said ligand was originally covalently bound.

16. An article according to claim 14 , said article being an RFID device, a time recording device, a Bluetooth communication device, a location mapped device, or a fuze.

17. An article according to any of claim 14 , said article comprising a power source.

18. An article comprising a resistor, a power source, a communication module and a rigid surface; wherein said resistor comprises a plurality of encapsulates that comprise a liquid metal core, and a metal oxide shell that encapsulates said core, and wherein at least one of the elements in the group comprising said power source and said communication module in addition to said resistor are affixed to said rigid surface.

19. An article according to claim 18 , said article being an RFID device, a time recording device, a Bluetooth communication device, a location mapped device, or a fuze.

20. An article according to claim 18 wherein said rigid surface is conformally applied to another surface before rigidifying.

21. An article according to claim 18 said article comprising a CPU, an adhesive, a container, or an encapsulate.

Assignees

• Us Gov Air Force
• Us Air Force

Inventors

• Thrasher Carl J
• Tabor Christopher E
• Farrell Zachary J

Classifications

• H10W76/17

  characterised by their materials · CPC title

• G01R27/22

  Measuring resistance of fluids · CPC title

• G01L5/0052 Primary

  measuring forces due to impact (G01L5/0061, G01L5/14 take precedence; impact testing of structures G01M7/08; impact testing of material G01N3/00) · CPC title

• G01L1/20 Primary

  by measuring variations in ohmic resistance of solid materials or of electrically-conductive fluids (of piezo-resistive materials G01L1/18); by making use of electrokinetic cells, i.e. liquid-containing cells wherein an electrical potential is produced or varied upon the application of stress · CPC title

• H01L23/06

  Electricity · mapped topic