Method for controlling strength of carbon nanotube fiber aggregate

Patent metadata

Field	Value
Publication number	US-10889918-B2
Application number	US-201716341652-A
Country	US
Kind code	B2
Filing date	Nov 22, 2017
Priority date	Jan 4, 2017
Publication date	Jan 12, 2021
Grant date	Jan 12, 2021

Abstract

The present invention relates to a method for controlling the strength of a carbon nanotube fiber aggregate, wherein the strength of the carbon nanotube fiber aggregate can be improved by controlling the molar ratio of the carbon source to reducing gas.

First claim

What is claimed is:

1. A method for producing a carbon nanotube fiber aggregate by spinning a raw material containing a carbon source in the presence of a carrier gas containing a reducing gas, wherein the molar ratio of the carbon source to the reducing gas (carbon source/reducing gas) is 0.03 or more and 0.05 or less, and
wherein the molar ratio of the carbon source to the reducing gas (carbon source/reducing gas) satisfies the following Equation 1 or Equation 2:
y= 0.0288 e 107.58x   (Equation 1)

0.0288 e 107.58x −0.7 ≤y≤ 0.0288 e 107.58x +0.3  (Equation 2)

wherein, y is the elongation at break, and x is the molar ratio of the carbon source to the reducing gas,
to control the strength of the carbon nanotube fiber aggregate,
wherein the reducing gas comprises hydrogen gas, ammonia gas, or a mixed gas thereof.

2. The method for producing a carbon nanotube fiber aggregate according to claim 1 , wherein the value of elongation at break increases as the molar ratio of the carbon source to the reducing gas (carbon source/reducing gas) is greater.

3. The method for producing a carbon nanotube fiber aggregate according to claim 1 , wherein the carrier gas comprises an inert gas.

4. The method for producing a carbon nanotube fiber aggregate according to claim 1 , wherein the raw material for spinning is a liquid or gaseous carbon compound having the catalyst precursor dispersed therein.

5. The method for producing a carbon nanotube fiber aggregate according to claim 4 , wherein the liquid or gaseous carbon compound comprises at least one selected from the group consisting of methane, ethylene, acetylene, methyl acetylene, vinyl acetylene, ethanol, methanol, propanol, acetone, xylene, chloroform, ethyl acetate, diethyl ether, polyethylene glycol, ethyl formate, mesitylene, tetrahydrofuran (THF), dimethylformamide (DMF), dichloromethane, hexane, benzene, carbon tetrachloride and pentane.

6. The method for producing a carbon nanotube fiber aggregate according to claim 4 , wherein the catalyst precursor comprises at least one selected from the group consisting of iron, nickel, cobalt, platinum, ruthenium, molybdenum, vanadium and oxides thereof.

7. The method for producing a carbon nanotube fiber aggregate according to claim 6 , wherein the catalyst precursor is in a metallocene form.

8. The method for producing a carbon nanotube fiber aggregate according to claim 1 , wherein carbon nanotubes are formed from a raw material for spinning and continuously fused to spin carbon nanotube fibers directly.

9. The method for producing a carbon nanotube fiber aggregate according to claim 1 , wherein a feed rate of the raw material for spinning is 10 to 500 ml/min, and a feed rate of the carrier gas is 1 to 5 L/min.

10. A carbon nanotube fiber aggregate produced by the method of claim 1 .

Assignees

• Lg Chemical Ltd

Inventors

• Kim Juhan
• Oh Eugene
• Kim Ji Eun
• Lee Jaehong
• Lee Won Jae

Classifications

• D01F9/127 Primary

  by thermal decomposition of hydrocarbon gases or vapours {or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols} · CPC title

• C01P2006/90

  Other properties not specified above · CPC title

• C01B32/16 Primary

  Preparation · CPC title

• D10B2401/16

  antistatic; conductive · CPC title

• D01F1/09

  for making electroconductive or anti-static filaments · CPC title