Device for manufacturing carbon nanotube fibers and method for manufacturing carbon nanotube fibers using same

Patent metadata

Field	Value
Publication number	US-9556542-B2
Application number	US-201414421393-A
Country	US
Kind code	B2
Filing date	May 29, 2014
Priority date	Jun 18, 2013
Publication date	Jan 31, 2017
Grant date	Jan 31, 2017

Abstract

Provided is an apparatus for producing a carbon nanotube fiber. The apparatus includes: a vertical reactor having a reaction zone; an inlet through which a spinning solution is introduced into the bottom of the reaction zone of the reactor; an inlet through which a carrier gas is introduced into the bottom of the reaction zone of the reactor; heating means for heating the reaction zone; and a discharge unit disposed on the top of the reaction zone and through which a carbon nanotube fiber is discharged from the reactor. The spinning solution entering the reaction zone through the spinning solution inlet is carbonized and graphitized while ascending from the bottom of the reaction zone by the carrier gas entering through the carrier gas inlet, to form a carbon nanotube fiber consisting of continuous aggregates of carbon nanotubes. Further provided is a carbon nanotube fiber produced using the apparatus. The carbon nanotube fiber is long and exhibits high electrical conductivity, tensile strength, and elasticity. Due to these advantages, the carbon nanotube fiber is expected to find a variety of applications, including multifunctional composite materials, deformation/damage sensors, transmission cables, and electrochemical devices, for example, microelectrode materials for biological substance detection, supercapacitors, and actuators.

First claim

What is claimed is:

1. An apparatus for producing a carbon nanotube fiber, comprising:
a vertical reactor having a reaction zone;
a spinning solution inlet through which a spinning solution is introduced into the bottom of the reaction zone of the reactor;
a carrier gas inlet through which a carrier gas is introduced into the bottom of the reaction zone of the reactor;
a heater that heats the reaction zone;
a discharge unit disposed on the top of the reaction zone and through which a carbon nanotube fiber is discharged from the reactor; and
a distribution plate placed below the reaction zone of the reactor to divide the reactor into an upper reaction zone and a lower non-reaction zone in fluid communication with each other, and the spinning solution inlet and the carrier gas inlet are disposed above and below the distribution plate, respectively,
wherein the spinning solution entering the reaction zone through the spinning solution inlet is carbonized and graphitized while ascending from the bottom of the reaction zone by the carrier gas entering through the carrier gas inlet, to form a carbon nanotube fiber consisting of continuous aggregates of carbon nanotubes, and
wherein the carbon nanotube fiber discharge unit has a winder that winds and collects the carbon nanotube fiber discharged from the top of the reactor.

2. The apparatus according to claim 1 , further comprising a supply unit for supplying the spinning solution to the spinning solution inlet and a supply unit for supplying the carrier gas to the carrier gas inlet.

3. The apparatus according to claim 1 , wherein the spinning solution entering through the spinning solution inlet is supplied to the reaction zone through a spray nozzle.

4. The apparatus according to claim 2 , wherein the spinning solution supply unit comprises a mixing unit where a catalyst is dispersed in a liquid carbon compound to prepare the spinning solution and a transfer pump for supplying the spinning solution from the mixing unit to a supply nozzle.

5. The apparatus according to claim 2 , wherein the carrier gas supply unit comprises a gas control unit by which the carrier gas entering through the carrier gas inlet is supplied at such a linear velocity that laminar flows are formed.

6. The apparatus according to claim 1 , wherein the carbon nanotube fiber discharge unit has an inlet through which an inert gas is fed to form an inert gas curtain surrounding a continuous aggregate of the carbon nanotube fiber.

7. The apparatus according to claim 1 , wherein the winder is a spindle, reel, drum, or conveyor.

8. The apparatus according to claim 1 , wherein the spinning solution entering the bottom of the distribution plate through the spinning solution inlet is supplied to the reaction zone on the top of the distribution plate through a nozzle penetrating the distribution plate.

9. The apparatus according to claim 1 , wherein the spinning solution entering through the spinning solution inlet and the carrier gas entering through the carrier gas inlet are separated from each other under the distribution plate.

10. The apparatus according to claim 1 , wherein the heater is a furnace surrounding the reactor to heat the reaction zone to 1,000 to 3,000° C.

11. A method for producing a carbon nanotube fiber comprising providing the apparatus according to claim 1 , and spinning the spinning solution in the vertical reactor to produce the carbon nanotube fiber.

12. An apparatus for producing a carbon nanotube fiber, comprising:
a vertical reactor having a reaction zone;
a spinning solution inlet through which a spinning solution is introduced into the bottom of the reaction zone of the reactor;
a carrier gas inlet through which a carrier gas is introduced into the bottom of the reaction zone of the reactor;
a heater that heats the reaction zone;
a discharge unit disposed on the top of the reaction zone and through which a carbon nanotube fiber is discharged from the reactor; and
a distribution plate placed below the reaction zone of the reactor to divide the reactor into an upper reaction zone and a lower non-reaction zone in fluid communication with each other, and both the spinning solution inlet and the carrier gas inlet are disposed below the distribution plate,
wherein the spinning solution entering the reaction zone through the spinning solution inlet is carbonized and graphitized while ascending from the bottom of the reaction zone by the carrier gas entering through the carrier gas inlet, to form a carbon nanotube fiber consisting of continuous aggregates of carbon nanotubes, and
wherein the carbon nanotube fiber discharge unit has a winder that winds and collects the carbon nanotube fiber discharged from the top of the reactor.

13. The apparatus according to claim 12 , wherein the spinning solution entering through the spinning solution inlet and the carrier gas entering through the carrier gas inlet are mixed with each other and supplied to the reaction zone through the distribution plate.

Assignees

• Lg Chemical Ltd

Inventors

• Oh Eugene
• Lee Dongchul
• Yoon Kwangwoo

Classifications

• D01F9/133 Primary

  Apparatus therefor · CPC title

• D01F11/16 Primary

  by physicochemical methods · CPC title

• C01B31/0233

  Chemistry & Metallurgy · mapped topic

• C01B31/024

  Chemistry & Metallurgy · mapped topic

• C01B31/00

  Chemistry & Metallurgy · mapped topic