Increasing the specific strength of spun carbon nanotube fibers

Patent metadata

Field	Value
Publication number	US-9315385-B2
Application number	US-285307-A
Country	US
Kind code	B2
Filing date	Dec 17, 2007
Priority date	Dec 22, 2006
Publication date	Apr 19, 2016
Grant date	Apr 19, 2016

Abstract

A spun fiber of carbon nanotubes is exposed to ion irradiation. The irradiation exposure increases the specific strength of the spun fiber.

First claim

What is claimed is:

1. A method for preparing a fiber, comprising:
irradiating a spun fiber having a specific strength S1 and comprising carbon nanotubes to produce an irradiated spun fiber having a specific strength S2, wherein S2>S1; and
heating the irradiated spun fiber at about 300 degrees C. to about 700 degrees C.

2. The method of claim 1 , wherein irradiating the spun fiber comprises irradiating with protons.

3. The method of claim 1 , further comprising preparing a spun fiber from an array of carbon nanotubes.

4. The method of claim 3 , further comprising preparing an array of carbon nanotubes by heating a catalyst structure in the presence of a carbon-containing precursor.

5. The method of claim 4 , wherein the catalyst structure comprises a substrate portion having a first side and a second side, a buffer layer on the first side of the substrate, and a catalyst on the buffer layer.

6. The method of claim 5 , wherein the substrate comprises silicon, glass, metal, or combinations thereof.

7. The method of claim 5 , wherein the buffer layer comprises aluminum oxide, magnesium oxide, zinc oxide, silicon carbide, or combinations thereof.

8. The method of claim 5 , wherein the catalyst comprises metal particles chosen from iron, cobalt, nickel, molybdenum, mixtures thereof, or alloys thereof.

9. The method of claim 4 , wherein the carbon-containing precursor is chosen from hydrocarbons, alcohols, ketones, or mixtures thereof.

10. A fiber prepared by a method that comprises:
irradiating a spun fiber having a specific strength S1 and comprising carbon nanotubes to produce an irradiated spun fiber having a specific strength S2, wherein S2>S1; and
heating the irradiated spun fiber to about 300 degrees C. to about 700 degrees C. so as to reduce the number of structural defects within the carbon nanotubes of the irradiated spun fiber relative to the number of structural defects within the carbon nanotubes of the irradiated spun fiber before heating.

11. The fiber of claim 10 , wherein irradiating the spun fiber comprises irradiating with protons.

12. The fiber of claim 10 , further comprising preparing a spun fiber from an array of carbon nanotubes.

13. The fiber of claim 12 , further comprising preparing an array of carbon nanotubes by heating a catalyst structure in the presence of a carbon-containing precursor.

14. The fiber of claim 13 , wherein the catalyst structure comprises a substrate portion having a first side and a second side, a buffer layer on the first side of the substrate, and a catalyst on the buffer layer.

15. The fiber of claim 14 , wherein the substrate comprises silicon, glass, metal, or combinations thereof.

16. The fiber of claim 14 , wherein the buffer layer comprises aluminum oxide, magnesium oxide, zinc oxide, silicon carbide, or combinations thereof.

17. The fiber of claim 14 , wherein the catalyst comprises metal particles chosen from iron, cobalt, nickel, molybdenum, mixtures thereof, or alloys thereof.

18. The fiber of claim 13 , wherein the carbon-containing precursor is chosen from hydrocarbons, alcohols, ketones, or mixtures thereof.

19. The method of claim 1 , wherein the carbon nanotubes are coated with polymer.

20. The fiber of claim 10 , wherein the carbon nanotubes are coated with polymer.

Assignees

• Arendt Paul N
• Zhu Yuntian T
• Usov Igor O
• Zhang Xiefei
• Los Alamos Nat Security Llc

Inventors

• Arendt Paul N
• Zhu Yuntian T
• Usov Igor O
• Zhang Xiefei

Classifications

• D06M10/008

  Treatment with radioactive elements or with neutrons, alpha, beta or gamma rays · CPC title

• C01B2202/08

  Aligned nanotubes · CPC title

• C01B31/0233 Primary

  Chemistry & Metallurgy · mapped topic

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title

• B82Y40/00

  Manufacture or treatment of nanostructures · CPC title