Nanocrystalline high temperature machine parts

Patent metadata

Field	Value
Publication number	US-10851440-B2
Application number	US-201816130629-A
Country	US
Kind code	B2
Filing date	Sep 13, 2018
Priority date	Feb 15, 2017
Publication date	Dec 1, 2020
Grant date	Dec 1, 2020

Abstract

Novel metallic systems and methods for their fabrication provide high temperature machine parts formed of a consolidated nano-crystalline metallic material. The material comprises a matrix formed of a solvent metal having a melting point greater than 1,250° C. with crystalline grains having diameters of no more than about 500 nm, and a plurality of dispersed metallic particles formed on the basis of a solute metal in the solvent metal matrix and having diameters of no more than about 200 nm. The particle density along the grain boundary of the matrix is as high as about 2 nm2 of grain boundary area per particle so as to substantially block grain boundary motion and rotation and limit creep at temperatures above 35% of the melting point of the consolidated nano-crystalline metallic material. The machine parts formed may include turbine blades, gears, hypersonics, radiation shielding, and other high temperature parts.

First claim

We claim:

1. A high temperature machine part formed of a consolidated nano-crystalline metallic material comprising:
a matrix formed of a solvent metal having a melting point greater than 1,250° C. comprising crystalline grains having diameters of no more than about 500 nm; and
a plurality of dispersed metallic particles formed on the basis of a solute metal in the solvent metal matrix and having diameters of no more than about 200 nm,
wherein the particle density along the grain boundary of the matrix is as high as about 2 nm 2 of grain boundary area per particle so as to substantially block grain boundary motion and rotation and limit creep at temperatures above 35% of the melting point of the consolidated nano-crystalline metallic material.

2. The machine part of claim 1 , wherein the solvent metal comprises 50 to 99.9 atomic percent (at. %) of the part material, and the dispersed metallic solute metal comprise 0.1 to 50 atomic percent (at. %) of the part material.

3. The machine part of claim 1 , wherein the solvent and solute are selected such that the elastic enthalpy is 1 to 250 kJ/mol, the mixing enthalpy is −150 to +150 kJ/mol, the minimum normalized boundary energy is 1 to 40%, the boundary concentration at the free energy minimum is 10 to 100%, or any combination thereof.

4. The machine part of claim 1 , wherein the solvent metal comprises: iron (Fe), nickel (Ni), titanium (Ti), cobalt (Co), vanadium (V), niobium (Nb), tantalum (Ta), molybdenum (Mo) or tungsten (W).

5. The machine part of claim 4 , wherein the solvent metal comprises nickel (Ni) and the solute metal comprises yttrium (Y).

6. The machine part of claim 5 , wherein the part material comprises Ni-5at. % Y.

7. The machine part of claim 1 , wherein the particles number densities within the volume of material is in the range of 10 15 to 10 30 per cubic meter.

8. The machine part of claim 1 , wherein the creep rate is less than 10's −1 at greater than 35% of the melting point of the part material.

9. The machine part of claim 1 , wherein the creep rate is less than 10's −1 at greater than 20% of their respective yield point values at temperatures greater than 35% of the melting point of the part material.

10. The machine part of claim 1 , wherein at least some of the particles further comprise additional elements.

11. The machine part of claim 1 , wherein at least some of the particles comprise coherent particles having diameters less than about 5 nm.

12. The machine part of claim 1 , wherein at least some of the particles comprise semi-coherent particles having diameters between about 5 nm and about 20 nm.

13. The machine part of claim 1 , wherein at least some of the particles comprise incoherent particles having diameters in excess of about 20 nm but no more than about 200 nm.

14. The machine part of claim 1 , wherein the solute metal is at least 0.1 atomic percent of the material so as to limit rotation of grains to no more than about 45 degrees.

15. The machine part of claim 1 , wherein the material has a room temperature yield strength of at least 1 GPa.

16. The material of claim 1 , wherein the material has a room temperature compressive ductility greater than about 3% or a tensile ductility of at least about 0.5%.

17. The machine part of claim 1 , wherein the machine part comprises a turbine part, engine part, gear, hypersonic, or radiation shielding.

18. A process for forming high temperature machine part comprised of a solvent metal comprising 50 to 99.9 atomic percent (at. %) of the part material, and at least one solute metal dispersed in the solvent metal, comprising 0.1 to 50 at. % of the part material, the process comprising:
subjecting powdered metals of the solvent metal and the at least one solute metal to a non-equilibrium processing technique and/or followed by exposure to elevated temperatures so as to produce:
a matrix formed of a solvent metal or alloy having a melting point greater than 1,250° C. comprising crystalline grains having diameters of no more than about 500 nm; and
a plurality of dispersed metallic particles formed from a basis of the solute metal in the solvent metal matrix and having diameters of no more than about 200 nm,
wherein the particle density along the grain boundary of the matrix is as high as about 2 nm 2 of grain boundary area per particle so as to substantially block grain boundary motion and rotation and limit creep at temperatures above 35% of the melting point of the material; and

performing a bulk consolidation process on thus produced material to form the machine part.

19. The process of claim 18 , wherein the non-equilibrium processing technique comprises: milling, melt spinning, spray atomization, inert gas condensation, solution precipitation, physical vapor deposition, or electrodeposition.

20. The process of claim 19 , wherein the milling is high energy milling or low energy milling.

21. The process of claim 18 , wherein the bulk consolidation process comprises: pressure-less sintering, hot isostatic pressing, cold isostatic pressing, hot pressing, powder injection molding, friction stir weld processing, cold and thermal spray, laser and non-laser based additive manufacturing techniques, ultrasonic consolidation techniques, vacuum arc melting, field assisted sintering, dynamic compaction using explosives or forging-like operations, hot extrusion, cold extrusion, swaging or equal channel angular extrusion.

Assignees

• U S Govt As Represented By Sec Of Army
• Us Army

Inventors

• Darling Kristopher Allen
• Grendahl Scott Martin
• Kecskes Laszlo John
• Solanki Kiran N
• Murdoch Heather Ann
• Luckenbaugh Thomas Lee
• Roberts Anthony James
• Hornbuckle Billy Chad

Classifications

• C22C1/0433

  Nickel- or cobalt-based alloys · CPC title

• C22C1/045

  Alloys based on refractory metals · CPC title

• B22F3/10

  Sintering only · CPC title

• B22F2999/00

  Aspects linked to processes or compositions used in powder metallurgy · CPC title

• B22F5/008

  of engine cylinder parts or of piston parts other than piston rings (of piston rings B22F5/02) · CPC title