Method for making In2O3 nanoarray and use for splitting water

Patent metadata

Field	Value
Publication number	US-10844511-B2
Application number	US-201916554890-A
Country	US
Kind code	B2
Filing date	Aug 29, 2019
Priority date	Jun 6, 2018
Publication date	Nov 24, 2020
Grant date	Nov 24, 2020

Abstract

A method of forming a one-dimensional nanoarray of In2O3 nanowires on indium foil is disclosed. The nanowires of In2O3 have diameters of 30 nm-50 nm and lengths of 100 nm-200 nm, and are attached to and substantially perpendicular to the surface of the indium foil. The In2O3 nanoarray may have a nanowire density of 200-300 nanowires per μm2 indium foil and a band gap energy of 2.63-3.63 eV. The In2O3 nanoarray may be formed by anodization of indium foil in an electrochemical cell subjected to a voltage of 15-25 V at room temperature.

First claim

The invention claimed is:

1. A method for making an In 2 O 3 nanoarray photo-electrochemical cell and splitting water to form H 2 and O 2 , comprising:
subjecting an electrochemical cell to 15-25 V to anodize an indium foil, the electrochemical cell comprising:
a working electrode comprising indium foil in contact with an electrolyte solution,

a reference electrode, and
a counter electrode in contact with the electrolyte solution,
wherein nanowires of In 2 O 3 are grown on the indium foil, forming the In 2 O 3 nanoarray,
wherein an end of each nanowire is attached to the indium foil, and
wherein the longitudinal axis of each nanowire is substantially perpendicular to the indium foil, then

placing the In 2 O 3 nanoarray in a photo-electrochemical cell to make the photo-electrochemical cell and adding water; and
irradiating the photo-electrochemical cell containing the water and the In 2 O 3 nanoarray to form H 2 and O 2 by splitting the water.

2. The method of claim 1 , wherein the In 2 O 3 nanoarray has a band gap energy of 2.63-3.63 eV.

3. The method of claim 1 , wherein the electrolyte solution has a temperature of 20-30° C.

4. The method of claim 1 , wherein the electrolyte solution comprises polyethylene glycol at a weight percentage of 1-8 wt % relative to a total weight of the electrolyte solution.

5. The method of claim 1 , wherein the electrolyte solution comprises one or more electrolytes at a concentration of 0.2-1.0 M.

6. The method of claim 1 , wherein the electrolyte solution comprises at least one electrolyte selected from the group consisting of chromic acid, oxalic acid, sulfuric acid, phosphoric acid, ammonium fluoride, and sodium fluoride.

7. The method of claim 1 , wherein before the subjecting, the electrolyte solution is substantially free of an aqueous form of In.

8. The method of claim 1 , wherein the electrochemical cell is subjected to a voltage that does not vary by more than 5% of an average value throughout the subjecting.

9. The method of claim 1 , wherein the indium foil in contact with the electrolyte solution has a length to width ratio of 1:1-2.5:1.

Assignees

• Univ King Fahd Pet & Minerals

Inventors

• Qurashi Ahsanulhaq
• Khan Ibrahim

Classifications

• C30B7/12 Primary

  by electrolysis · CPC title

• C30B29/60

  characterised by shape · CPC title

• C30B29/16

  Oxides · CPC title