Molten salt electrolyzer, and method for producing metal magnesium using the same and method for producing a titanium sponge

Patent metadata

Field	Value
Publication number	US-10837084-B2
Application number	US-201615741197-A
Country	US
Kind code	B2
Filing date	Jul 27, 2016
Priority date	Jul 28, 2015
Publication date	Nov 17, 2020
Grant date	Nov 17, 2020

Abstract

A molten salt electrolyzer having a metal collection chamber, an electrolysis chamber, and two or more electrolytic cell units positioned in the electrolysis chamber. Each electrolytic cell unit has a cathode having an inner space in a prism form; at least one bipolar electrode in a rectangular cylinder form and disposed in the cathode inner space; and an anode in a prism form and disposed in an inner space of the bipolar electrode. At least part of individual planes forming an outer side of the bipolar electrode closest to the cathode faces a plane forming the prism-form inner space of the cathode. At least part of individual planes forming the inner side of the bipolar electrode closest to the anode faces a plane forming the prism of the anode. At least one plane of the cathode constitutes one plane of a cathode of another electrolytic cell unit.

First claim

The invention claimed is:

1. A molten salt electrolyzer having a metal collection chamber and an electrolysis chamber, the molten salt electrolyzer having two or more electrolytic cell units in the electrolysis chamber,
wherein each electrolytic cell unit has a cathode having a space in a prism form, an anode in a prism form, and at least one bipolar electrode in a rectangular cylinder form,
wherein the bipolar electrode is disposed in an inner space of the cathode, and the anode being disposed in an inner space of the bipolar electrode,
wherein at least part of individual planes forming an outer side of the rectangular cylinder of the bipolar electrode closest to the cathode faces a plane forming the prism-form space of the cathode,
wherein at least part of individual planes forming an inner side of the rectangular cylinder of the bipolar electrode closest to the anode faces a plane forming the prism of the anode,
wherein at least one plane of the cathode constitutes one plane of the cathode of another electrolytic cell unit, and
wherein the anode is disposed to be shifted from a middle of a space surrounded by the cathode to a side opposite to the metal collection chamber.

2. The molten salt electrolyzer according to claim 1 , wherein at least one of a distance between the cathode plane on the side opposite to the metal collection chamber and a bipolar electrode plane closest to the cathode plane, a distance between the bipolar electrode plane on the side opposite to the metal collection chamber and another bipolar electrode plane closest to the bipolar electrode plane, and a distance between the bipolar electrode plane on the side opposite to the metal collection chamber and an anode plane closest to the bipolar electrode plane is shorter than a distance between a corresponding cathode plane on the metal collection chamber side and the bipolar electrode plane closest to the cathode plane, a distance between a corresponding bipolar electrode plane on the metal collection chamber side and another bipolar electrode plane closest to the bipolar electrode plane, or a distance between the corresponding bipolar electrode plane on the metal collection chamber side and the anode plane closest to the bipolar electrode plane.

3. The molten salt electrolyzer according claim 1 , wherein the anode has a horizontal cross-section in which a ratio of the long side and the short side is 1:1 to 10:1.

4. A method for producing metal magnesium, comprising subjecting magnesium chloride to fusion electrolysis using the molten salt electrolyzer according to claim 1 to produce metal magnesium.

5. A method for producing a titanium sponge, comprising reducing titanium tetrachloride using the metal magnesium obtained by the method according to claim 4 to produce a titanium sponge.

6. The molten salt electrolyzer according to claim 1 ,
wherein a level of an electrolytic bath in the metal collection chamber is substantially the same as a level of an electrolytic bath in the electrolysis chamber, and
wherein an upper end of the cathode is disposed to be lower than the level of the electrolytic bath in the metal collection chamber.

7. The molten salt electrolyzer according to claim 1 ,
wherein materials for an inner wall and a barrier in the molten salt electrolyzer are at least one selected from a brick having an Al 2 O 3 content of 90% or more, a brick having a SiO 2 content of 90% or more, a brick having a Si 3 N 4 content of 90% or more, a brick having a MgO content of 90% or more, and a brick having a combination of at least two of Al 2 O 3 , SiO 2 , Si 3 N 4 and MgO content of 90% or more.

Assignees

• Toho Titanium Co Ltd

Inventors

• Horikawa Matsuhide
• Suzuki Daisuke

Classifications

• C25C7/025

  used in cells for the electrolysis of melts · CPC title

• C25C7/005

  of cells for the electrolysis of melts (C25C7/02 - C25C7/06 take precedence) · CPC title

• C25C3/00

  Electrolytic production, recovery or refining of metals by electrolysis of melts (C25C5/00 takes precedence) · CPC title

• C22B34/12

  Obtaining titanium {or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08} · CPC title

• C22B26/22 Primary

  Obtaining magnesium · CPC title