System and method for parallel solution extraction of one or more metal values from metal-bearing materials

Patent metadata

Field	Value
Publication number	US-10793958-B2
Application number	US-201816020333-A
Country	US
Kind code	B2
Filing date	Jun 27, 2018
Priority date	Dec 20, 2011
Publication date	Oct 6, 2020
Grant date	Oct 6, 2020

Abstract

A process and system is provided for recovery of one or more metal values using solution extraction techniques and for metal value recovery. In an exemplary embodiment, the solution extraction system comprises a first solution extraction circuit and a second solution extraction circuit. A first metal-bearing solution is provided to the first and second circuit, and a second metal-bearing solution is provided to the first circuit. The first circuit produces a first rich electrolyte solution, which can be forwarded to primary metal value recovery, and a low-grade raffinate, which is forwarded to secondary metal value recovery. The second circuit produces a second rich electrolyte solution, which is also forwarded to primary metal value recovery. The first and second solution extraction circuits have independent organic phases and each circuit can operate independently of the other circuit.

First claim

What is claimed is:

1. A system for extracting metal value comprising:
a solution extraction system comprising a first circuit and a second circuit,
wherein the first circuit is configured to receive a first portion of a first metal bearing solution comprising copper and cobalt, and to produce a first copper-rich electrolyte;
wherein the second circuit is configured to receive a second portion of the first metal bearing solution and to produce a second copper-rich electrolyte; and
wherein the first circuit is configured to receive a second metal bearing solution comprising copper and cobalt and to produce a cobalt-containing raffinate;

a primary metal value recovery system configured to extract copper from the first copper-rich electrolyte and the second copper-rich electrolyte; and
a secondary metal value recovery system configured to extract cobalt from the cobalt-containing raffinate.

2. The system of claim 1 , wherein the primary metal value recovery system comprises one of an electrowinning circuit, a sulphidation system, a precipitation system, and an ion exchange system.

3. The system of claim 2 , wherein the primary metal value recovery system comprises an electrowinning circuit.

4. The system of claim 1 , wherein the first circuit is configured to produce a high-grade raffinate.

5. The system of claim 3 , wherein the secondary metal value recovery system further comprises a secondary electrowinning circuit configured to extract cobalt from the second copper-rich electrolyte.

6. The system of claim 4 , wherein the high-grade raffinate is recycled to a reactive processing system.

7. A system for extracting metal value comprising:
a solution extraction system comprising a first circuit and a second circuit,
wherein the first circuit is configured to receive a first metal bearing solution and to produce a first copper-rich electrolyte;
wherein the second circuit is configured to receive the first metal bearing solution and to produce a second copper-rich electrolyte; and
wherein the first circuit is configured to receive a second metal bearing solution and to produce a low-grade raffinate;

a primary metal recovery circuit configured to extract a copper value from the first copper-rich electrolyte and the second copper-rich electrolyte; and
a secondary metal value recovery system configured to extract a secondary metal value from the low-grade raffinate.

8. The system of claim 7 , wherein the low-grade raffinate comprises at least one of silver, platinum group metals, molybdenum, zinc, nickel, cobalt, uranium, rhenium, rare earth and actinide metals.

9. The system of claim 7 , wherein the secondary metal value recovery system is configured to perform a selective precipitation process to precipitate a metal ion.

10. The system of claim 9 , wherein the metal ion comprises uranium.

11. The system of claim 7 , wherein the secondary metal value recovery system comprises a secondary electrowinning circuit.

12. The system of claim 7 , wherein the secondary metal value comprises cobalt.

13. The system of claim 7 , wherein the second metal bearing solution is a low-grade pregnant leach solution.

Assignees

• Freeport Minerals Corp

Inventors

• Raman Anand
• Morgan Jason M
• Savage Barbara J
• Meadows David G
• Hazen Wayne W

Classifications

• C22B3/26

  by liquid-liquid extraction using organic compounds · CPC title

• C22B34/34

  Obtaining molybdenum {(treatment or purification of solutions by adsorption on solids C22B3/24, by liquid-liquid extraction C22B3/26, by ion-exchange extraction C22B3/42; preparation of molybdenum involving liquid-liquid extraction, adsorption or ion-exchange C01G39/003)} · CPC title

• C22B3/44

  by chemical processes (treatment or purification of solutions by liquid-liquid extraction C22B3/26, by ion-exchange extraction C22B3/42) · CPC title

• B01D11/0488

  Flow sheets · CPC title

• C25C1/22 Primary

  of metals not provided for in groups C25C1/02 - C25C1/20 · CPC title