System and method for parallel solution extraction of one or more metal values from metal-bearing materials

Patent metadata

Field	Value
Publication number	US-10036096-B2
Application number	US-201514832742-A
Country	US
Kind code	B2
Filing date	Aug 21, 2015
Priority date	Dec 20, 2011
Publication date	Jul 31, 2018
Grant date	Jul 31, 2018

Abstract

The present disclosure relates to a process and system for recovery of one or more metal values using solution extraction techniques and to a system for metal value recovery. In an exemplary embodiment, the solution extraction system comprises a first solution extraction circuit and a second solution extraction circuit. A first metal-bearing solution is provided to the first and second circuit, and a second metal-bearing solution is provided to the first circuit. The first circuit produces a first rich electrolyte solution, which can be forwarded to primary metal value recovery, and a low-grade raffinate, which is forwarded to secondary metal value recovery. The second circuit produces a second rich electrolyte solution, which is also forwarded to primary metal value recovery. The first and second solution extraction circuits have independent organic phases and each circuit can operate independently of the other circuit.

First claim

What is claimed is:

1. A process comprising:
feeding a first metal-bearing solution to a first solution extraction circuit and a second solution extraction circuit;
feeding a second metal-bearing solution to the first solution extraction circuit;
producing a low-grade raffinate from the first solution extraction circuit; and
subjecting the low-grade raffinate to a selective precipitation process to precipitate a metal ion.

2. The process of claim 1 , wherein the metal ion is uranium.

3. The process of claim 2 , wherein the low-grade raffinate comprises a secondary metal value.

4. The process of claim 3 , wherein the secondary metal value is cobalt.

5. The process of claim 2 , wherein the uranium precipitates as a solid and further comprising recycling the solid to a reactive process.

6. The process of claim 3 , wherein the subjecting the low-grade raffinate to the selective precipitation process yields an electrolyte containing a secondary metal value.

7. The process of claim 6 , further comprising forwarding the electrolyte to a secondary metal recovery process.

8. The process of claim 7 , wherein the secondary metal value comprises at least one of silver, platinum group metals, molybdenum, zinc, nickel, cobalt, uranium, rhenium, rare earth and actinide metals.

9. The process of claim 1 , wherein the first metal-bearing solution is a high-grade pregnant leach solution.

10. The process of claim 1 , wherein the second metal-bearing solution is a low-grade pregnant leach solution.

11. A process comprising:
feeding a first metal-bearing solution to a first solution extraction circuit and a second solution extraction circuit;
feeding a second metal-bearing solution to the first solution extraction circuit; producing a low-grade raffinate from the first solution extraction circuit;
subjecting the low-grade raffinate to a secondary metal value recovery process.

12. The process of claim 11 , wherein the low-grade raffinate comprises a secondary metal value comprising at least one of silver, platinum group metals, molybdenum, zinc, nickel, cobalt, uranium, rhenium, rare earth and actinide metals.

13. The process of claim 12 , wherein the secondary metal value recovery process comprises a selective precipitation process to precipitate a metal ion.

14. The process of claim 13 , wherein the metal ion comprises uranium.

15. A method for extracting metal value comprising:
performing a solution extraction process comprising feeding a first stream of a first metal-bearing solution to a first circuit of a solution extraction system,
feeding a second stream of the first metal-bearing solution to a second circuit of the solution extraction system,
feeding a second metal-bearing solution to the first circuit of the solution extraction system,
producing a first rich electrolyte solution with a stripping unit of the first circuit of the solution extraction system,
producing a second rich electrolyte solution with a stripping unit of the second circuit of the solution extraction system; and
producing a low-grade raffinate from an extractor of the first circuit of the solution extraction system;
performing a primary metal value recovery process on the first rich electrolyte solution and the second rich electrolyte solution; and
subjecting the low-grade raffinate to a selective precipitation process to precipitate a metal ion.

16. The method of claim 15 , wherein the metal ion is uranium.

17. The method of claim 16 , wherein the low-grade raffinate comprises a secondary metal value.

18. The method of claim 17 , wherein the secondary metal value comprises cobalt.

19. The method of claim 16 , wherein the uranium precipitates as a solid and further comprising recycling the solid to a reactive process.

20. The method of claim 17 , wherein the subjecting the low-grade raffinate to the selective precipitation process yields an electrolyte containing the secondary metal value.

Assignees

• Freeport Minerals Corp

Inventors

• Raman Anand
• Morgan Jason M
• Savage Barbara J
• Meadows David G
• Hazen Wayne W

Classifications

• C22B23/0453

  Treatment or purification of solutions, e.g. obtained by leaching (C22B23/0407 takes precedence) · CPC title

• C22B3/02

  Apparatus therefor · CPC title

• C22B60/0221

  by leaching · CPC title

• C25C7/00

  Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells (for the production of aluminium C25C3/06 - C25C3/22) · CPC title

• C25C1/22 Primary

  of metals not provided for in groups C25C1/02 - C25C1/20 · CPC title