Iron particle passivation

Patent metadata

Field	Value
Publication number	US-10774218-B2
Application number	US-201715803561-A
Country	US
Kind code	B2
Filing date	Nov 3, 2017
Priority date	Nov 3, 2017
Publication date	Sep 15, 2020
Grant date	Sep 15, 2020

Abstract

The present disclosure provides a coated iron particle, or reaction product thereof, comprising an iron particle and a thiol coating disposed on the iron particle. The present disclosure further provides compositions comprising a coated iron particle and a polymer or adhesion promoter. The present disclosure further provides components having a surface and a composition of the present disclosure disposed on the surface. Methods for passivating an iron particle can include introducing a passivation agent having one or more sulfur moieties into a solvent to form a passivation solution; and contacting an iron particle with the passivation solution to form a coated iron particle. Methods for passivating an iron particle can include introducing an iron particle into a solvent to form an iron particle solution; and contacting a passivation agent having one or more sulfur moieties with the iron particle solution to form a coated iron particle.

First claim

What is claimed is:

1. A coated iron particle, or reaction product thereof, comprising:
an iron particle having a diameter of from about 0.5 micron to about 1,000 microns; and
a thiol coating disposed on the iron particle, wherein:
the thiol coating has a thickness of from about 10 Angstroms to about 1,000 Angstroms.

2. The coated iron particle of claim 1 , wherein the iron particle has a diameter of from about 1 micron to about 1,000 microns.

3. The coated iron particle of claim 2 , wherein the iron particle has an iron content of about 99 wt % or greater.

4. The coated iron particle of claim 1 , wherein the coated iron particle has a thiol coating content of from about 1 wt % to about 10 wt % based on the total weight of the thiol coated iron particle, as determined by the difference in the weight of the particle before and after coating the particle.

5. The coated iron particle of claim 4 , wherein the coated iron particle has a thiol coating content of from about 2 wt % to about 5 wt % based on the total weight of the thiol coated iron particle, as determined by the difference in the weight of the particle before and after coating the particle.

6. The coated iron particle of claim 1 , wherein the coated iron particle has a ratio of χ s to particle diameter of from about 0.5:1 to about 1.5:1.

7. The coated iron particle of claim 1 , wherein the coated iron particle has a thiol coating content of from about 1 vol % to about 10 vol % based on the total volume of the thiol coated iron particle, as determined by the difference in the weight and density of the particle before and after coating the particle.

8. The coated iron particle of claim 1 , wherein the thiol coating comprises, or is the reaction product of, a thiol compound selected from the group consisting of a heterocyclic thiol, a disulfide compound, a thiolate compound, and an alkyl polythiol.

9. The coated iron particle of claim 1 , wherein the thiol coating comprises, or is the reaction product of, an alkyl polythiol selected from the group consisting of ethane dithiol, propane dithiol, butane dithiol, pentane dithiol, hexane dithiol, octane dithiol, nonane dithiol, and decane dithiol.

10. The coated iron particle of claim 1 , wherein the thiol coating comprises, or is the reaction product of, a heterocyclic thiol that is 2,5-dimercapto-1,3,4-thiadiazole.

11. A coated iron particle, or reaction product thereof, comprising:
an iron particle having a diameter of from about 0.5 micron to about 1,000 microns; and
a thiol coating disposed on the iron particle, wherein:
the thiol coating has a thickness of from about 10 Angstroms to about 1,000 Angstroms, and
the coated iron particle has a thiol coating content of from about 1 vol % to about 10 vol % based on the total volume of the thiol coated iron particle, as determined by the difference in the weight and density of the particle before and after coating the particle.

12. The coated iron particle of claim 11 , wherein the thiol coating comprises, or is the reaction product of, a thiol compound selected from the group consisting of a heterocyclic thiol, a disulfide compound, a thiolate compound, and an alkyl polythiol.

13. The coated iron particle of claim 11 , wherein the thiol coating comprises, or is the reaction product of, an alkyl polythiol selected from the group consisting of ethane dithiol, propane dithiol, butane dithiol, pentane dithiol, hexane dithiol, octane dithiol, nonane dithiol, and decane dithiol.

14. The coated iron particle of claim 11 , wherein the thiol coating comprises, or is the reaction product of, a heterocyclic thiol that is 2,5-dimercapto-1,3,4-thiadiazole.

15. A coated iron particle, or reaction product thereof, comprising:
an iron particle having a diameter of from about 0.5 micron to about 1,000 microns; and
a thiol coating disposed on the iron particle, wherein the thiol coating comprises, or is the reaction product of, an alkyl polythiol selected from the group consisting of ethane dithiol, propane dithiol, butane dithiol, pentane dithiol, hexane dithiol, octane dithiol, nonane dithiol, and decane dithiol.

16. A coated iron particle, or reaction product thereof, comprising:
an iron particle having a diameter of from about 0.5 micron to about 1,000 microns; and
a thiol coating disposed on the iron particle,
wherein the thiol coating comprises, or is the reaction product of, a heterocyclic thiol that is 2,5-dimercapto-1,3,4-thiadiazole.

17. A composition, or reaction product thereof, comprising:
the coated iron particle of claim 1 ; and
a polymer or an adhesion promoter.

18. The composition of claim 17 , wherein the composition comprises a polymer selected from the group consisting of an epoxy, a bismaleimide, a polyimide, a polyaryletherketone, a sol-gel, a polyurethane, a silicone, and a magneto rheological particle fluid.

19. A component comprising a surface and the composition of claim 17 disposed on the surface.

20. A composition, or reaction product thereof, comprising:
a polymer or an adhesion promoter; and
a coated iron particle, or reaction product thereof, the coated iron particle comprising:
an iron particle having a diameter of from about 0.5 micron to about 1,000 microns; and
a thiol coating disposed on the iron particle,

wherein the composition comprises a polymer selected from the group consisting of an epoxy, a bismaleimide, a polyimide, a polyaryletherketone, a sol-gel, a polyurethane, a silicone, and a magneto rheological particle fluid,
wherein the composition has a coated iron particle content of from about 0.5 wt % to about 10 wt %.

21. A method for passivating an iron particle comprising:
introducing a passivation agent having one or more sulfur moieties into a solvent to form a passivation solution; and
contacting an iron particle having a diameter of from about 0.5 micron to about 1,000 microns with the passivation solution to form a coated iron particle,
wherein introducing a passivation agent into a solvent comprises introducing the passivation agent into a solvent selected from the group consisting of an alcohol, an alkylcarbonate, an ether, a glycol ether, tetrahydrofuran, N-methyl-2-pyrrolidone, dimethyl sulfoxide, and mixtures thereof,
wherein a concentration of the passivation agent in the passivation solution is from about 1 M to about 2 M.

22. The method of claim 21 , further comprising filtering the coated iron particle and drying the coated iron particle by curing the coated iron particle at a temperature of from about 30° C. to about 70° C.

23. A method for passivating an iron particle comprising:
introducing a passivation agent having one or more sulfur moieties into a solvent to form a passivation solution; and
contacting an iron particle having a diameter of from about 0.5 micron to about 1,000 microns with the passivation solution to form a coated iron particle,
wherein the passivation agent is selected from the group consisting of a heterocyclic thiol, a disulfide compound, a thiolate compound, and an alkyl polythiol.

24. The method of claim 23 , wherein contacting the iron particle with the passivation solution comprises introducing the iron particle to the passivation solution to form a solution comprising the passivation agent and the iron particle.

25. The method of claim 24 , further comprising stirring the solution comprising the passivation agent and the iron particle.

26. The

Assignees

• Boeing Co

Inventors

• Kinlen Patrick J

Classifications

• B22F1/102

  Metallic powder coated with organic material · CPC title

• B22F1/145

  Chemical treatment, e.g. passivation or decarburisation · CPC title

• C23C22/02 Primary

  using non-aqueous solutions · CPC title

• C09C1/22 Primary

  Compounds of iron {(C09C1/0009, C09C1/0015, C09C1/0078 take precedence)} · CPC title

• C01P2006/42

  Magnetic properties · CPC title