Method of controllably coating a fiber preform during ceramic matrix composite (CMC) fabrication

Patent metadata

Field	Value
Publication number	US-10759711-B2
Application number	US-201815995537-A
Country	US
Kind code	B2
Filing date	Jun 1, 2018
Priority date	Jun 1, 2018
Publication date	Sep 1, 2020
Grant date	Sep 1, 2020

Abstract

A method of controllably coating a fiber preform has been developed. The method includes infiltrating a fiber preform with a first solvent to form a solvent-filled preform. After the infiltration, a slurry is applied to one or more outer surfaces of the solvent-filled preform to form a slurry coating thereon. The slurry coating comprises particulate solids dispersed in a second solvent having a vapor pressure higher than that of the first solvent. The slurry coating and the solvent-filled preform are dried. During drying, the second solvent evaporates from the slurry coating before the first solvent evaporates from the solvent-filled preform. The slurry coating dries to form a porous surface coating comprising the particulate solids on the one or more outer surfaces of the solvent-filled preform. The drying of the solvent-filled preform continues after formation of the porous surface coating to remove the first solvent.

First claim

The invention claimed is:

1. A method of controllably coating a fiber preform during ceramic matrix composite (CMC) fabrication, the method comprising:
infiltrating a fiber preform with a first solvent to form a solvent-filled preform;
after the infiltration, applying a slurry to one or more outer surfaces of the solvent-filled preform to form a slurry coating thereon, the slurry coating comprising particulate solids dispersed in a second solvent having a vapor pressure higher than that of the first solvent; and
drying the slurry coating and the solvent-filled preform, the second solvent being evaporated from the slurry coating before the first solvent is evaporated from the solvent-filled preform,
wherein the slurry coating dries to form a porous surface coating comprising the particulate solids on the one or more outer surfaces of the solvent-filled preform, and
wherein drying of the solvent-filled preform continues after formation of the porous surface coating to evaporate the first solvent.

2. The method of claim 1 , wherein the vapor pressure of the second solvent is from about two times to about 100 times greater than that of the first solvent.

3. The method of claim 1 , wherein the first solvent comprises a vapor pressure of no greater than about 30 hPa at 20° C.

4. The method of claim 3 , wherein the first solvent is selected from the group consisting of: water and glycerin.

5. The method of claim 1 , wherein the second solvent comprises a vapor pressure of at least about 40 hPa at 20° C.

6. The method of claim 5 , wherein the second solvent is selected from the group consisting of: acetone, ethyl alcohol, and isopropyl alcohol.

7. The method of claim 1 , wherein the slurry coating further comprises a polymeric binder and/or one or more reactive elements.

8. The method of claim 1 , wherein infiltrating the fiber preform with the first solvent comprises dipping a portion of the fiber preform in the first solvent, submerging the fiber preform in the first solvent, or spraying the fiber preform with the first solvent.

9. The method of claim 1 , further comprising, during the infiltration of the fiber preform with the first solvent, exerting a vacuum on the fiber preform to remove entrapped air.

10. The method of claim 1 , wherein applying the slurry to the one or more outer surfaces comprises spreading, dipping, and/or spraying.

11. The method of claim 1 , wherein drying of the slurry coating and the solvent-filled preform is carried out at room temperature over a time duration from about two hours to about 48 hours.

12. The method of claim 1 , wherein drying of the slurry coating and the solvent-filled preform comprises heating.

13. The method of claim 1 , wherein the porous surface coating comprises a thickness in a range from about 10 microns to about 1,000 microns.

14. The method of claim 1 , wherein, prior to infiltrating the fiber preform with the first solvent, the fiber preform undergoes slurry infiltration followed by drying and/or heating to remove infiltrated carrier liquid and to deposit particulate matter therein, the fiber preform being an impregnated fiber preform.

15. The method of claim 14 , wherein the particulate matter of the impregnated fiber preform includes ceramic particles selected from the group consisting of: silicon carbide particles, alumina particles, aluminosilicate particles, silicon nitrocarbide particles, silicon nitride particles, and boron carbide particles.

16. The method of claim 1 , wherein the particulate solids of the slurry coating and the porous surface layer include ceramic particles selected from the group consisting of: silicon carbide particles, alumina particles, aluminosilicate particles, silicon nitrocarbide particles, silicon nitride particles, and boron carbide particles.

17. The method of claim 1 , further comprising, after evaporating the first solvent, infiltrating the porous surface coating and the fiber preform with a molten metal or alloy,
wherein, upon cooling, a CMC component with a uniform surface layer thereon is formed.

18. The method of claim 17 , wherein the uniform surface layer follows contours of the CMC component and is substantially devoid of unintended surface features having a depth in a range from about 10 microns to about 250 microns.

19. The method of claim 17 , wherein the molten metal or alloy comprises silicon or a silicon alloy, wherein the fiber preform comprises silicon carbide fibers, and wherein the particulate solids comprise silicon carbide particles.

20. The method of claim 17 , wherein the CMC component is a gas turbine engine component selected from the group consisting of: blade, vane, seal segment, and combustor liner.

Assignees

• Rolls Royce High Temperature Composites Inc
• Rolls Royce High Temperature Composites

Inventors

• Harris Stephen

Classifications

• C04B35/80 Primary

  Fibres, filaments, whiskers, platelets, or the like · CPC title

• C04B35/573

  obtained by reaction sintering {or recrystallisation} · CPC title

• C04B41/5059

  Silicon carbide · CPC title

• C04B2235/3821

  Boron carbides · CPC title

• C04B35/565

  based on silicon carbide · CPC title