Method of melt infiltration utilizing a non-wetting coating for producing a ceramic matrix composite

Patent metadata

Field	Value
Publication number	US-10138168-B2
Application number	US-201715404424-A
Country	US
Kind code	B2
Filing date	Jan 12, 2017
Priority date	Jan 12, 2017
Publication date	Nov 27, 2018
Grant date	Nov 27, 2018

Abstract

A method of melt infiltration for producing a ceramic matrix composite comprises applying a non-wetting coating onto one or more outer surfaces of a porous fiber preform. The non-wetting coating comprises a non-wetting material with which molten silicon has a contact angle of at least about 45°. After applying the non-wetting coating, an uncoated portion of the porous fiber preform is immersed into a molten material comprising silicon, and the molten material is infiltrated into the porous fiber preform through the uncoated portion. The non-wetting coating serves as a barrier to inhibit or prevent the molten material from penetrating the one or more outer surfaces. After infiltration of the molten material into the porous fiber preform, the molten material is cooled to form a ceramic matrix composite, and the non-wetting coating is removed.

First claim

The invention claimed is:

1. A method of melt infiltration for producing a ceramic matrix composite, the method comprising:
applying a coating onto one or more outer surfaces of a porous fiber preform, the coating comprising a material with which molten silicon comprises a contact angle of at least about 45°;
after applying the coating, immersing an uncoated portion of the porous fiber preform into a molten material comprising silicon, the molten material being infiltrated into the porous fiber preform through the uncoated portion, the coating serving as a barrier to inhibit or prevent the molten material from penetrating the one or more outer surfaces;
after infiltration of the molten material into the porous fiber preform, cooling the molten material to form a ceramic matrix composite; and
removing the coating.

2. The method of claim 1 , wherein, after removing the coating, the ceramic matrix composite is substantially free of silicon surface nodules.

3. The method of claim 1 , wherein the contact angle is at least about 60°.

4. The method of claim 1 , wherein the material is selected from the group consisting of boron nitride, aluminum nitride and silicon nitride.

5. The method of claim 1 , wherein applying the coating comprises depositing a coating formulation using a deposition method selected from the group consisting of: spray coating, dip coating, brushing on, and rolling on, followed by drying the coating formulation.

6. The method of claim 1 , wherein the coating has a thickness in a range from about 1 micron to about 25 microns.

7. The method of claim 6 , wherein the thickness is in the range from about 1 micron to about 5 microns.

8. The method of claim 1 , wherein removing the coating comprises abrasive grit blasting.

9. The method of claim 1 , further comprising, prior to infiltration of the molten material, applying a high emissivity coating comprising a non-reflective material onto the coating.

10. The method of claim 9 , wherein the non-reflective material comprises carbon.

11. The method of claim 10 , wherein the carbon is selected from the group consisting of: carbon black and graphite.

12. The method of claim 9 , wherein applying the high emissivity coating comprises depositing a coating formulation by a deposition method selected from the group consisting of: spray coating, dip coating, brushing on, and rolling on, followed by drying the coating formulation.

13. The method of claim 1 , further comprising, prior to applying the coating:
applying a surface slurry onto the one or more outer surfaces of the porous fiber preform, the surface slurry comprising a solvent and particulate solids; and
drying the surface slurry to form a porous external layer comprising the particulate solids on the one or more outer surfaces.

14. The method of claim 13 , wherein the porous external layer comprises a thickness of from about 0.1 mm to about 1 mm.

15. The method of claim 13 , further comprising machining the porous external layer.

16. The method of claim 13 , wherein the particulate solids comprise a ceramic selected from the group consisting of: silicon carbide, silicon nitride and boron carbide, and one or more reactive elements comprising carbon.

17. The method of claim 1 , wherein the molten material comprises a silicon-rich alloy.

18. The method of claim 1 , wherein the molten material consists essentially of silicon.

19. The method of claim 1 , wherein the ceramic matrix composite includes ceramic fibers comprising silicon carbide in a ceramic matrix comprising silicon carbide.

20. The method of claim 1 , wherein a component of a gas turbine engine comprises the ceramic matrix composite, the component being selected from the group consisting of: seal segment, blade, vane and combustor liner.

Assignees

• Rolls Royce High Temperature Composites Inc

Inventors

• Shim Sungbo

Classifications

• C04B35/657

  for manufacturing refractories (C04B35/05, C04B35/107, C04B35/484 take precedence) · CPC title

• F05D2300/2261

  of silicon · CPC title

• C04B2235/616

  Liquid infiltration of green bodies or pre-forms · CPC title

• B05D1/02

  performed by spraying · CPC title

• C04B2235/3826

  Silicon carbides · CPC title