Protective layer for a ceramic matrix composite article

Patent metadata

Field	Value
Publication number	US-2019185384-A1
Application number	US-201715845612-A
Country	US
Kind code	A1
Filing date	Dec 18, 2017
Priority date	Dec 18, 2017
Publication date	Jun 20, 2019
Grant date	—

Abstract

A method including infiltrating a porous fiber preform with a slurry including a carrier fluid and a first plurality of solid particles wherein the first plurality of solid particles includes at least a first ceramic material, drying the slurry to form a greenbody preform, machining the greenbody preform to a target dimension, depositing a protective layer precursor including a second plurality of solid particles on the machined greenbody preform wherein the second plurality of solid particles includes at least a second ceramic material, and infiltrating the machined greenbody preform with a molten infiltrant to form a composite article including an integral protective layer.

First claim

What is claimed is:

1 . A method comprising:
infiltrating a porous fiber preform with a slurry comprising a carrier fluid and a first plurality of solid particles, wherein the first plurality of solid particles comprises at least a first ceramic material; drying the slurry to form a greenbody preform; after drying the slurry, machining the greenbody preform to a target dimension; after machining the greenbody preform, depositing a protective layer precursor comprising a second plurality of solid particles on the machined greenbody preform, wherein the second plurality of solid particles comprises at least a second ceramic material; and infiltrating the machined greenbody preform with a molten infiltrant to form a composite article including an integral protective layer.

2 . The method of claim 1 , wherein the second plurality of solid particles comprises a plurality of fine ceramic particles defining a fine particle average size, a plurality of coarse ceramic particles defining a coarse particle average size, and a plurality of carbon particles, wherein the fine particle average size is less than the coarse particle average size.

3 . The method of claim 1 , wherein the first plurality of solid particles is different than the second plurality of solid particles.

4 . The method of claim 1 , wherein the first plurality of solid particles is the same as the second plurality of solid particles.

5 . The method of claim 1 , wherein depositing the protective layer precursor comprises:
forming a ceramic tape comprising the second plurality of solid particles; and positioning the ceramic tape on an exterior surface of the machined greenbody preform.

6 . The method of claim 1 , wherein the first plurality of solid particles or the second plurality of solid particles comprise particles of at least one of boron carbide, silicon carbide, silicon nitride, or molybdenum carbide.

7 . The method of claim 1 , wherein the porous fiber preform comprises a plurality of fibrous layers, each fibrous layer comprising a plurality of silicon carbide fibers.

8 . The method of claim 1 , wherein machining the greenbody preform to the target dimension comprises exposing at least some fibers of the porous fiber preform.

9 . The method of claim 1 , wherein the molten infiltrant comprises elemental silicon or a silicon alloy.

10 . The method of claim 1 , wherein depositing the protective layer precursor comprises:
depositing a slurry comprising a carrier fluid and the second plurality of solid particles on an exterior surface of the machined greenbody preform; and drying the slurry comprising the carrier fluid and the second plurality of solid particles to remove substantially all the carrier fluid and form the protective layer precursor.

11 . The method of claim 10 , further comprising mechanically smoothing the slurry comprising the carrier fluid and the second plurality of solid particles before the slurry has dried.

12 . The method of claim 1 , wherein the protective layer defines a thickness between about 25 micrometers (μm) and about 750 μm.

13 . The method of claim 1 , wherein the protective layer defines a thickness between about 25 micrometers (μm) and about 250 μm.

14 . A method comprising:
infiltrating a porous fiber preform with a slurry comprising a carrier fluid and a first plurality of solid particles, wherein the first plurality of solid particles comprises at least a first ceramic material; drying the slurry to form a greenbody preform; after drying the slurry, infiltrating the greenbody preform with a molten infiltrant to form a composite article; depositing a protective layer precursor comprising a second plurality of solid particles on the composite article, wherein the second plurality of solid particles comprises at least a second ceramic material and silicon particles; and heating the composite article to reflow the molten infiltrant into the protective layer precursor to form a protective layer.

15 . The method of claim 14 , wherein the second plurality of solid particles comprises a plurality of fine ceramic particles defining a fine particle average size, a plurality of coarse ceramic particles defining a coarse particle average size, and a plurality of carbon particles, wherein the fine particle average size is less than the coarse particle average size.

16 . The method of claim 14 , wherein depositing the protective layer precursor comprises:
forming a ceramic tape comprising the second plurality of solid particles; and positioning the ceramic tape on an exterior surface of the composite article.

17 . The method of claim 14 , wherein depositing the protective layer precursor comprises:
depositing a slurry comprising a carrier fluid and the second plurality of solid particles on an exterior surface of the composite article; and drying the slurry comprising the carrier fluid and the second plurality of solid particles to remove substantially all the carrier fluid and form the protective layer precursor.

18 . The method of claim 17 , further comprising mechanically smoothing the slurry comprising the carrier fluid and the second plurality of solid particles before the slurry has dried.

19 . The method of claim 14 , wherein the first plurality of solid particles or the second plurality of solid particle comprise particles of at least one of boron carbide, silicon carbide, silicon nitride, or molybdenum carbide.

20 . The method of claim 14 , further comprising after drying the slurry and before depositing the protective layer precursor, machining the greenbody preform or the composite article to a target dimension.

Assignees

• Rolls Royce High Temperature Composites Inc

Inventors

• Shim Sungbo
• Abbott Michael

Classifications

• C04B35/62894

  with more than one coating layer · CPC title

• C04B35/62863

  Silicon carbide · CPC title

• C04B35/6286

  Carbides · CPC title

• C04B35/62892

  with a coating layer consisting of particles · CPC title

• C04B2235/428

  Silicon · CPC title