Shape memory ceramic particles and structures formed thereof

Patent metadata

Field	Value
Publication number	US-10696599-B2
Application number	US-201716075350-A
Country	US
Kind code	B2
Filing date	Feb 10, 2017
Priority date	Feb 12, 2016
Publication date	Jun 30, 2020
Grant date	Jun 30, 2020

Abstract

There is provided a shape memory ceramic structure including an aggregate population of crystalline particles. Each crystalline particle in the population, of crystalline particles comprises a shape memory ceramic particle material. Each crystalline particle in the population of crystalline particles has a crystalline particle extent that is between about 0.5 microns and about fifty microns. At least a portion of the population of crystalline particles has a crystalline structure that is either oligocrystalline or monocrystalline.

First claim

We claim:

1. A shape memory ceramic structure comprising:
an aggregate population of crystalline particles;
each crystalline particle in the population of crystalline particles comprising a shape memory ceramic particle material and having a crystalline particle extent between about 0.5 microns and about fifty microns; and
at least a portion of the population of crystalline particles having a crystalline structure selected from the group consisting of oligocrystalline structure including no more than five grains and monocrystalline structure having an extent that is no more than about 5 microns.

2. The shape memory ceramic structure of claim 1 wherein the shape memory ceramic material comprises an element selected from the group consisting of zirconium, cerium, and oxygen.

3. The shape memory ceramic structure of claim 1 wherein the shape memory ceramic material comprises ZrO 2 .

4. The shape memory ceramic structure of claim 1 wherein the shape memory ceramic material comprises ZrO 2 doped with at least one dopant selected from the group consisting of Ce, Y, Ca, Mg, Ti, Ge, La, Pb, Nb, Ta, Mn.

5. The shape memory ceramic structure of claim 1 wherein the shape memory ceramic material comprises a shape memory ceramic material selected from the group consisting of Al 2 SiO 5 , Ca 2 SiO 4 , and Mg 2 SiO 4 .

6. The shape memory ceramic structure of claim 1 wherein each crystalline particle in the population of crystalline particles has a particle geometry selected from the group consisting of solid spherical, hollow spherical, tabular, equant, polyhedral, and hollow spherical with at least one pore geometries.

7. The shape memory ceramic structure of claim 1 wherein each crystalline particle in the population of crystalline particles has a particle geometry selected from the group consisting of cuboid, cubic, tetragonal, and trapezoidal geometries.

8. The shape memory ceramic structure of claim 1 wherein each crystalline particle in the population of crystalline particles has a particle geometry including a plurality of surface faces, with two of the surface faces being parallel to each other.

9. The shape memory ceramic structure of claim 1 wherein each crystalline particle in the population of crystalline particles has a symmetric polyhedral geometry.

10. The shape memory ceramic structure of claim 1 wherein each crystalline particle in the population of crystalline particles has a crystalline particle extent that is between about 1 micron and about 10 microns.

11. The shape memory ceramic structure of claim 1 wherein each crystalline particle in the population of crystalline particles has a crystalline particle extent that is no more than about 5 microns.

12. A shape memory ceramic structure comprising:
an aggregate population of crystalline particles;
each crystalline particle in the population of crystalline particles comprising a shape memory ceramic particle material and having a crystalline particle extent between about 0.5 microns and about fifty microns; and
each crystalline particle in the population of crystalline particles having a spherical geometry with a spherical particle diameter and an oligocrystalline structure having an average grain size, and wherein the spherical particle diameter is no more than about ten times the average grain size.

13. The shape memory ceramic structure of claim 1 wherein the population of crystalline particles is arranged as an aggregation of loose particles contained in a vessel.

14. The shape memory ceramic structure of claim 1 wherein the population of crystalline particles is arranged as a coating of crystalline particles on a surface.

15. The shape memory ceramic structure of claim 1 wherein the population of crystalline particles is arranged as a bulk compact comprising the population of crystalline particles and a polymer binder.

16. The shape memory ceramic structure of claim 1 wherein the population of crystalline particles is arranged as a bulk compact comprising the population of crystalline particles, the bulk compact being wrapped in a fabric.

17. A shape memory ceramic structure comprising:
an aggregate population of crystalline particles;
each crystalline particle in the population of crystalline particles comprising a shape memory ceramic particle material and having a crystalline particle extent between about 0.5 microns and about fifty microns;
at least a portion of the population of crystalline particles having a crystalline structure selected from the group consisting of oligocrystalline and monocrystalline; and
wherein the population of crystalline particles is arranged as a bulk compact comprising the population of crystalline particles, the bulk compact being coated with a layer of metal.

18. The shape memory ceramic structure of claim 1 wherein the population of crystalline particles is arranged in a bulk composite comprising the population of crystalline particles and a matrix material selected from the group consisting of polymer matrix and metal matrix.

19. The shape memory ceramic structure of claim 18 wherein the bulk composite further comprises fibers selected from the group consisting of carbon fibers, Kevlar fibers, glass fibers, carbon nanotube twisted fibers, and graphene twisted fibers.

20. The shape memory ceramic structure of claim 1 wherein the population of crystalline particles is arranged as a cubic bulk composite.

21. The shape memory ceramic structure of claim 1 wherein the population of crystalline particles is formed by spray drying a slurry including a shape memory ceramic particle powder and a polymer binder.

22. The shape memory ceramic structure of claim 21 wherein the polymer binder comprises polyvinyl alcohol with a molecular weight of about 35,000.

23. The shape memory ceramic structure of claim 21 wherein the spray drying is carried out at an inlet temperature between about 130° C. and about 160° C.

24. The shape memory ceramic structure of claim 1 wherein the population of crystalline particles is formed by sintering a mixture of the shape memory ceramic particle material powder and a polymer powder, with a weight percentage of the polymer powder to the shape memory ceramic powder in the mixture being between about 1 wt % and about 15 wt %.

25. The shape memory ceramic structure of claim 24 wherein the polymer powder comprises a powder of a polymer containing six-membered aromatic rings.

26. The shape memory ceramic structure of claim 24 wherein sintering comprises heating the mixture at a sintering temperature between about 1000° C. and about 1600° C.

27. The shape memory ceramic structure of claim 26 wherein sintering comprises ramping temperature of the mixture to the sintering temperature at a ramp rate of between about 5° C./min and about 20° C./min.

Assignees

• Massachusetts Inst Technology
• Univ Nanyang Tech

Inventors

• Du Zehui
• Yu Hang
• Schuh Christopher A
• Gan Chee Lip

Classifications

• C01P2004/61

  Micrometer sized, i.e. from 1-100 micrometer · CPC title

• C04B2235/528

  Spheres · CPC title

• C04B2235/5296

  with a defined aspect ratio, e.g. indicating sphericity · CPC title

• C04B35/62655

  Drying, e.g. freeze-drying, spray-drying, microwave or supercritical drying · CPC title

• C04B35/62675

  characterised by the treatment temperature · CPC title