Molecules having pesticidal utility, and intermediates, compositions, and processes, related thereto

Patent metadata

Field	Value
Publication number	US-10638756-B2
Application number	US-201815939341-A
Country	US
Kind code	B2
Filing date	Mar 29, 2018
Priority date	Mar 31, 2017
Publication date	May 5, 2020
Grant date	May 5, 2020

Abstract

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”).

First claim

The invention claimed is:

1. A molecule having the following formula

wherein:
(A) R 1 is selected from the group consisting of H, F, Cl, Br, I, CN, NO 2 , (C 1 -C 6 )alkyl, (C 1 -C 6 )haloalkyl, (C 1 -C 6 )alkoxy, (C 1 -C 6 )haloalkoxy, (C 2 -C 6 )alkenyl, (C 2 -C 6 )alkenyl-O-(C 1 -C 6 )alkyl, (C 2 -C 6 )alkynyl, (C 3 -C 6 )cycloalkyl, C(═O)H, SR x , SOR x , SO 2 R x , wherein R x is selected from the group consisting of (C 1 -C 6 )alkyl and (C 1 -C 6 )haloalkyl;
(B) R 2 is selected from the group consisting of H, F, Cl, Br, I, CN, NO 2 , (C 1 -C 6 )alkyl, (C 1 -C 6 )haloalkyl, (C 1 -C 6 )alkoxy, (C 1 -C 6 )haloalkoxy, (C 2 -C 6 )alkenyl, (C 2 -C 6 )alkenyl-O-(C 1 -C 6 )alkyl, (C 2 -C 6 )alkynyl, (C 3 -C 6 )cycloalkyl, C(═O)H, SR x , SOR x , SO 2 R x , wherein R x is selected from the group consisting of (C 1 -C 6 )alkyl, (C 1 -C 6 )haloalkyl, and (C 3 -C 6 )cycloalkyl;
(C) R 3 is selected from the group consisting of H, F, Cl, Br, I, CN, NO 2 , (C 1 -C 6 )alkyl, (C 1 -C 6 )haloalkyl, (C 1 -C 6 )alkoxy, (C 1 -C 6 )haloalkoxy, (C 2 -C 6 )alkenyl, (C 2 -C 6 )alkenyl-O-(C 1 -C 6 )alkyl, (C 2 -C 6 )alkynyl, (C 3 -C 6 )cycloalkyl, C(═O)H, SR x , SOR x , SO 2 R x , wherein R x is selected from the group consisting of (C 1 -C 6 )alkyl, (C 1 -C 6 )haloalkyl, and (C 3 -C 6 )cycloalkyl;
(D) R 4 is selected from the group consisting of H, F, Cl, Br, I, CN, NO 2 , (C 1 -C 6 )alkyl, (C 1 -C 6 )haloalkyl, (C 1 -C 6 )alkoxy, (C 1 -C 6 )haloalkoxy, (C 2 -C 6 )alkenyl, (C 2 -C 6 )alkenyl-O-(C 1 -C 6 )alkyl, (C 2 -C 6 )alkynyl, (C 3 -C 6 )cycloalkyl, C(═O)H, SR x , SOR x , SO 2 R x , wherein R x is selected from the group consisting of (C 1 -C 6 )alkyl, (C 1 -C 6 )haloalkyl, and (C 3 -C 6 )cycloalkyl;
(E) R 5 is selected from the group consisting of H, F, Cl, Br, I, CN, NO 2 , (C 1 -C 6 )alkyl, (C 1 -C 6 )haloalkyl, (C 1 -C 6 )alkoxy, (C 1 -C 6 )haloalkoxy, (C 2 -C 6 )alkenyl, (C 2 -C 6 )alkenyl-O-(C 1 -C 6 )alkyl, (C 2 -C 6 )alkynyl, (C 3 -C 6 )cycloalkyl, C(═O)H, SR x , SOR x , SO 2 R x , wherein R x is selected from the group consisting of (C 1 -C 6 )alkyl and (C 1 -C 6 )haloalkyl;
(F) R 6 is selected from the group consisting of H, F, Cl, Br, I, CN, NO 2 , (C 1 -C 6 )alkyl, (C 1 -C 6 )haloalkyl, (C 1 -C 6 )alkoxy, (C 1 -C 6 )haloalkoxy;
(G) R 7 is (C 1 -C 6 )haloalkyl;
(H) R 8 is F;
(I) R 9 is selected from the group consisting of (O), H, F, Cl, Br, I, CN, NO 2 , (C 1 -C 6 )alkyl, (C 1 -C 6 )haloalkyl, (C 1 -C 6 )alkoxy, (C 1 -C 6 )haloalkoxy, (C 2 -C 6 )alkenyl, (C 2 -C 6 )alkenyl-O-(C 1 -C 6 )alkyl, (C 2 -C 6 )alkynyl, (C 3 -C 6 )cycloalkyl, C(═O)H, SR x , SOR x , SO 2 R x , wherein R x is selected from the group consisting of (C 1 -C 6 )alkyl, (C 1 -C 6 )haloalkyl, and (C 3 -C 6 )cycloalkyl;
(J) R 10 is selected from the group consisting of (O), F, Cl, Br, I, CN, NO 2 , (C 1 -C 6 )alkyl, (C 1 -C 6 )haloalkyl, (C 1 -C 6 )alkoxy, (C 1 -C 6 )haloalkoxy, (C 2 -C 6 )alkenyl, (C 2 -C 6 )alkenyl-O-(C 1 -C 6 )alkyl, (C 2 -C 6 )alkynyl, (C 3 -C 6 )cycloalkyl, C(═O)H, SR x , SOR x , SO 2 R x , wherein R x is selected from the group consisting of (C 1 -C 6 )alkyl, (C 1 -C 6 )haloalkyl, and (C 3 -C 6 )cycloalkyl;
(K) R 11 is selected from the group consisting of H, F, Cl, Br, I, CN, NO 2 , (C 1 -C 6 )alkyl, (C 1 -C 6 )haloalkyl, (C 1 -C 6 )alkoxy, (C 1 -C 6 )haloalkoxy, (C 2 -C 6 )alkenyl, (C 2 -C 6 )alkenyl-O-(C 1 -C 6 )alkyl, (C 2 -C 6 )alkynyl, (C 3 -C 6 )cycloalkyl, C(═O)H, SR x , SOR x , SO 2 R x , wherein R x is selected from the group consisting of (C 1 -C 6 )alkyl, (C 1 -C 6 )haloalkyl, and (C 3 -C 6 )cycloalkyl;
(L) R 12 is selected from the group consisting of H, F, Cl, Br, I, CN, NO 2 , (C 1 -C 6 )alkyl, (C 1 -C 6 )haloalkyl, (C 1 -C 6 )alkoxy, (C 1 -C 6 )haloalkoxy, (C 2 -C 6 )alkenyl, (C 2 -C 6 )alkenyl-O-(C 1 -C 6 )alkyl, (C 2 -C 6 )alkynyl, (C 3 -C 6 )cycloalkyl, C(═O)H, SR x , SOR x , SO 2 R x , wherein R x is selected from the group consisting of (C 1 -C 6 )alkyl, (C 1 -C 6 )haloalkyl, and (C 3 -C 6 )cycloalkyl;
(M) Q 1 is selected from the group consisting of O and S;
(N) X 1 is selected from (1), (2), (3), and (4) wherein
(1) N(R 13 )N(R 14 )(R 15 ) wherein
(a) said R 13 is selected from the group consisting of H, (C 1 -C 6 )alkyl, (C 1 -C 6 )alkyl nitrile, (C 1 -C 6 )alkylC(═O)N(H)((C 1 -C 6 )alkyl), (C 1 -C 6 )alkylC(═O)N(H)((C 1 -C 6 )haloalkyl), (C 1 -C 6 )alkyl-O-(C 1 -C 6 )alkyl, (C 1 -C 6 )alkyl(C 3 -C 6 )cycloalkyl, (C 2 -C 6 )alkenyl, (C 2 -C 6 )alkynyl, (C 1 -C 6 )haloalkyl, (C 1 -C 6 )alkoxy, (C 1 -C 6 )haloalkoxy, (C 3 -C 6 )cycloalkyl, phenyl, heterocyclyl, substituted phenyl, and substituted heterocyclyl, wherein said substituted phenyl and substituted heterocyclyl are substituted with one or more substituents independently selected from the group consisting of F, Cl, Br, CN, NO 2 , NH 2 , OH, (C 1 -C 6 )alkyl, (C 1 -C 6 )haloalkyl, (C 3 -C 6 )cycloalkyl, (C 1 -C 6 )alkoxy, (C 1 -C 6 )haloalkoxy, C(═O)O(C 1 -C 6 )alkyl, oxo, C(═O)NH(C 1 -C 6 )alkyl, C(═O)NH(C 1 -C 6 )haloalkyl, S(C 1 -C 6 )alkyl, S(O) 2 (C 1 -C 6 )alkyl, S(O)(C 1 -C 6 )alkyl, and N((C 1 -C 6 )alkyl) 2 ,
(b) said R 14 is selected from the group consisting of H, (C 1 -C 6 )alkyl, (C 1 -C 6 )alkyl nitrile, (C 1 -C 6 )alkylC(═O)N(H)((C 1 -C 6 )alkyl), (C 1 -C 6 )alkylC(═O)N(H)((C 1 -C 6 )haloalkyl), (C 1 -C 6 )alkyl-O-(C 1 -C 6 )alkyl, (C 1 -C 6 )alkyl(C 3 -C 6 )cycloalkyl, (C 2 -C 6 )alkenyl, (C 2 -C 6 )alkynyl, (C 1 -C 6 )haloalkyl, (C 1 -C 6 )alkoxy, (C 1 -C 6 )haloalkoxy, (C 3 -C 6 )cycloalkyl, phenyl, heterocyclyl, substituted phenyl, and substituted heterocyclyl, wherein said substituted phenyl and substituted heterocyclyl are substituted with one or more substituents independently selected from the group consisting of F, Cl, Br, CN, NO 2 , NH 2 , OH, (C 1 -C 6 )alkyl, (C 1 -C 6 )haloalkyl, (C 3 -C 6 )cycloalkyl, (C 1 -C 6 )alkoxy, (C 1 -C 6 )haloalkoxy, C(═O)O(C 1 -C 6 )alkyl, oxo, C(═O)NH(C 1 -C 6 )alkyl, C(═O)NH(C 1 -C 6 )haloalkyl, S(C 1 -C 6 )alkyl, S(O) 2 (C 1 -C 6 )alkyl, S(O)(C 1 -C 6 )alkyl, and N((C 1 -C 6 )alkyl) 2 ,
(c) said R 15 is selected from the group consisting of
(i) H, (C 1 -C 6 )alkyl, (C 1 -C 6 )haloalkyl, (C 1 -C 6 )alkyl nitrile, (C 2 -C 6 )alkenyl, (C 2 -C 6 )alkynyl, (C 1 -C 6 )alkoxy, (C 1 -C 6 )haloalkoxy, wherein each of which may be substituted with, F, Cl, Br, I, CN, NO 2 , NH 2 , OH, (C 1 -C 6 )haloalkyl, (C 3 -C 6 )cycloalkyl, O(C 1 -C 6 )alkyl, O(C 1 -C 6 )haloalkyl, C(═O)O(C 1 -C 6 )alkyl, S(C 1 -C 6 )alkyl, S(O) 2 (C 1 -C 6 )alkyl, S(O)(C 1 -C 6 )alkyl, and N((C 1 -C 6 )alkyl) 2 ,
(ii) (C 1 -C 6 )alkyl(C 3 -C 6 )cycloalkyl, (C 1 -C 6 )alkylphenyl, (C 3 -C 6 )cycloalkyl, phenyl, and heterocyclyl, wherein each of which may be substituted with, H to saturate an unsaturation, F, Cl, Br, I, CN, NO 2 , NH 2 , OH, (C 1 -C 6 )alkyl, (C 1 -C 6 )haloalkyl, O(C 1 -C 6 )alkyl, O(C 1 -C 6 )haloalkyl, C(═O)O(C 1 -C 6 )alkyl, oxo, S(C 1 -C 6 )alkyl, S(O) 2 (C 1 -C 6 )alkyl, S(O)(C 1 -C 6 )alkyl, and N((C 1 -C 6 )alkyl) 2 ,

(2) N(R 16 )N═C(R 17 )(R 18 ) wherein R 16 and R 17 are H, and R 18 is selected from the group consisting of substituted or unsubstituted phenyl, and substituted or unsubstituted heterocyclyl, wherein said substituents on said substituted phenyl and substituted heterocyclyl are selected from the group consisting of wherein each of which may be substituted with, H to saturate an unsaturation, F, Cl, Br, I, CN, NO 2 , NH 2 , OH, (C 1 -C 6 )alkyl, (C 1 -C 6 )haloalkyl, O(C 1 -C 6 )alkyl, oxo, S(O) 2 (C 1 -C 6 )alkyl, S(O)(C 1 -C 6 )alkyl, and N((C 1 -C 6 )alkyl) 2 ,
(3) N═N(R 19 ) wherein said R 19 is selected from the group consisting of substituted or unsubstituted phenyl, and substituted or unsubstituted heterocyclyl, wherein said substituents on said substituted phenyl and substituted heterocyclyl are selected from the group consist

Assignees

• Dow Agrosciences Llc

Inventors

• Leplae Jr Paul R
• Barton Thomas
• Gao Xin
• Hunter James E
• Lo William C
• Boruwa Joshodeep
• Tangirala Raghuram
• Watson Gerald B
• Herbert John
• Demeter David A
• Joshi Hemant

Classifications

• A01N43/66

  1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms · CPC title

• A01N43/38

  condensed with carbocyclic rings · CPC title

• A01N43/58

  1,2-Diazines; Hydrogenated 1,2-diazines · CPC title

• A01N37/46 Primary

  N-acyl derivatives · CPC title

• A01N37/10

  Aromatic or araliphatic carboxylic acids, or thio analogues thereof; Derivatives thereof · CPC title