Pesticidal compositions and processes related thereto

Patent metadata

Field	Value
Publication number	US-9226500-B2
Application number	US-201314133080-A
Country	US
Kind code	B2
Filing date	Dec 18, 2013
Priority date	Dec 19, 2012
Publication date	Jan 5, 2016
Grant date	Jan 5, 2016

Abstract

This document discloses molecules having the following formula (“Formula One”):

and processes associated therewith.

First claim

We claim:

1. A molecule according to Formula One:

wherein:
(a) R1 is selected from the group consisting of
(1) H, F, CI, Br, I, CN, NO 2 , (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 ) alkoxy, halo(C 1 -C 8 )alkoxy, S(C 1 -C 8 )alkyl, S(halo(C 1 -C 8 )alkyl), S(O)(C 1 -C 8 )alkyl, S(O)(halo(C 1 -C 8 )alkyl), S(O) 2 (C 1 -C 8 )alkyl, S(O) 2 (halo(C 1 -C 8 )alkyl), N(R14)(R15),
(2) substituted (C 1 -C 8 )alkyl, wherein said substituted (C 1 -C 8 )Alkyl has one or more substituents selected from the group consisting of CN and NO 2 ,
(3) substituted halo(C 1 -C 8 )alkyl, wherein said substituted halo(C 1 -C 8 ) alkyl, has one or more substituents selected from the group consisting of CN and NO 2 ,
(4) substituted (C 1 -C 8 )alkoxy, wherein said substituted (C 1 -C 8 ) alkoxy has one or more substituents selected from the group consisting of CN and NO 2 , and
(5) substituted halo(C 1 -C 8 )alkoxy, wherein said substituted halo(C 1 -C 8 )alkoxy has one or more substituents selected from the group consisting of CN and NO 2 ;

(b) R2 is selected from the group consisting of
(1) H, F, CI, Br, I, ON, NO 2 , (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 ) alkoxy, halo(C 1 -C 8 )alkoxy, S(C 1 -C 8 )alkyl, S(halo(C 1 -C 8 )alkyl), S(O)(C 1 -C 8 )alkyl, S(O)(halo(C 1 -C 8 )alkyl), S(O) 2 (C 1 -C 8 )alkyl, S(O) 2 (halo(C 1 -C 8 )alkyl), N(R14)(R15),
(2) substituted (C 1 -C 8 )alkyl, wherein said substituted (C 1 -C 8 )alkyl has one or more substituents selected from the group consisting of CN and NO 2 ,
(3) substituted halo(C 1 -C 8 )alkyl, wherein said substituted halo(C 1 -C 8 ) alkyl, has one or more substituents selected from the group consisting of CN and NO 2 ,
(4) substituted (C 1 -C 8 )alkoxy, wherein said substituted (C 1 -C 8 ) alkoxy has one or more substituents selected from the group consisting of CN and NO 2 , and
(5) substituted halo(C 1 -C 8 )alkoxy, wherein said substituted halo(C 1 -C 8 )alkoxy has one or more substituents selected from the group consisting of CN and NO 2 ;

(c) R3 is selected from the group consisting of
(1) H, F, CI, Br, I, CN, NO 2 , (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C-C 8 ) alkoxy, halo(C 1 -C 8 )alkoxy, S(C 1 -C 8 )alkyl, S(halo(C 1 -C 8 )alkyl), S(O)(C 1 -C 8 )alkyl, S(O)(halo(C 1 -C 8 )alkyl), S(O) 2 (C 1 -C 8 )alkyl, S(O) 2 (halo(C 1 -C 8 )alkyl), N(R14)(R15),
(2) substituted (C 1 -C 8 )alkyl, wherein said substituted (C 1 -C 8 )alkyl has one or more substituents selected from the group consisting of CN and NO 2 ,
(3) substituted halo(C 1 -C 8 )alkyl, wherein said substituted halo(C 1 -C 8 ) alkyl, has one or more substituents selected from the group consisting of CN and NO 2 ,
(4) substituted (C 1 -C 8 )alkoxy, wherein said substituted (C 1 -C 8 ) alkoxy has one or more substituents selected from the group consisting of CN and NO 2 , and
(5) substituted halo(C 1 -C 8 )alkoxy, wherein said substituted halo(C 1 -C 8 )alkoxy has one or more substituents selected from the group consisting of CN and NO 2 ;

(d) R4 is selected from the group consisting of
(1) H, F, CI, Br, I, CN, NO 2 , (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 ) alkoxy, halo(C 1 -C 8 )alkoxy, S(C 1 -C 8 )alkyl, S(halo(C 1 -C 8 )alkyl), S(O)(C 1 -C 8 )alkyl, S(O)(halo(C 1 -C 8 )alkyl), S(O) 2 (C 1 -C 8 )alkyl, S(O) 2 (halo(C 1 -C 8 )alkyl), N(R14)(R15),
(2) substituted (C 1 -C 8 )alkyl, wherein said substituted (C 1 -C 8 )alkyl has one or more substituents selected from the group consisting of CN and NO 2 ,
(3) substituted halo(C 1 -C 8 )alkyl, wherein said substituted halo(C 1 -C 8 ) alkyl, has one or more substituents selected from the group consisting of CN and NO 2 ,
(4) substituted (C 1 -C 8 )alkoxy, wherein said substituted (C 1 C 8 )alkoxy has one or more substituents selected from the group consisting of CN and NO 2 , and
(5) substituted halo(C 1 -C 8 )alkoxy, wherein said substituted halo(C 1 -C 8 )alkoxy has one or more substituents selected from the group consisting of CN and NO 2 ;

(e) R5 is selected from the group consisting of
(1) H, F, CI, Br, I, CN, NO 2 , (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 ) alkoxy, halo(C 1 -C 8 )alkoxy, S(C 1 -C 8 )alkyl, S(halo(C 1 -C 8 )alkyl), S(O)(C 1 -C 8 )alkyl, S(O)(halo(C 1 -C 8 )alkyl), S(O) 2 (C 1 -C 8 )alkyl, S(O) 2 (halo(C 1 -C 8 )alkyl), N(R14)(R15),
(2) substituted (C 1 -C 8 )alkyl, wherein said substituted (C 1 -C 8 )alkyl has one or more substituents selected from the group consisting of CN and NO 2 ,
(3) substituted halo(C 1 -C 8 )alkyl, wherein said substituted halo(C 1 -C 8 ) alkyl, has one or more substituents selected from the group consisting of CN and NO 2 ,
(4) substituted (C 1 -C 8 )alkoxy, wherein said substituted (C 1 -C 8 )alkoxy has one or more substituents selected from the group consisting of CN and NO 2 , and
(5) substituted halo(C 1 -C 8 )alkoxy, wherein said substituted halo(C 1 -C 8 )alkoxy has one or more substituents selected from the group consisting of CN and NO 2 ;

(f) R6 is a (C 1 -C 8 )haloalkyl;
(g) R7 is selected from the group consisting of H, F, CI, Br, I, OH, (C 1 -C 8 ) alkoxy, and halo(C 1 -C 8 )haloalkoxy;
(h) R8 is selected from the group consisting of H, (C 1 -C 8 )alkyl, halo(C 1 -C 8 ) alkyl, OR14, and N(R14)(R15);
(i) R9 is selected from the group consisting of H, F, CI, Br, I, (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 )alkoxy, halo(C 1 -C 8 )alkoxy, OR14, and N(R14)(R15);
(j) R10 is selected from the group consisting of
(1) H, F, CI, Br, I, CN, NO 2 , (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 ) alkoxy, halo(C 1 -C 8 )alkoxy, cyclo(C 3 -C 6 )alkyl, S(C 1 -C 8 )alkyl, S(halo(C 1 -C 8 )alkyl), S(O)(C 1 -C 8 )alkyl, S(O)(halo(C 1 -C 8 )alkyl), S(O) 2 (C 1 -C 8 )alkyl, S(O) 2 (halo(C 1 -C 8 )alkyl), NR14R15, C(═O)H, C(═O)N(R14)(R15), CN(R14)(R15)(═NOH), (C═O)O(C 1 -C 8 )alkyl, (C═O)OH, heterocyclyl, (C 2 -C 8 )alkenyl, halo(C 2 -C 8 )alkenyl, (C 2 -C 8 )alkynyl,
(2) substituted (C 1 -C 8 )alkyl, wherein said substituted (C 1 -C 8 )alkyl has one or more substituents selected from the group consisting of OH, (C 1 C 8 )alkoxy, S(C 1 -C 8 )alkyl, S(O)(C 1 -C 8 )alkyl, S(O) 2 (C 1 -C 8 )alkyl, NR14R15, and
(3) substituted halo(C 1 -C 8 )alkyl, wherein said substituted halo(C 1 -C 8 ) alkyl, has one or more substituents selected from the group consisting of (C 1 C 8 )alkoxy, S(C 1 -C 8 )alkyl, S(O)(C 1 -C 8 )alkyl, S(O) 2 (C 1 -C 8 )alkyl, and N(R14)(R15);

(k) R11 is selected from C(═X5)N(R14)((C 1 -C 8 )alkylC(═X5)N(R14)(R15)) wherein each X5 is independently selected from the group consisting of O, and S;
(I) R12 is selected from the group consisting of (v), H, F, CI, Br, I, CN, (C 1 -C 8 ) alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 )alkoxy, halo(C 1 -C 8 )alkoxy, and cyclo(C 3 -C 6 )alkyl;
(m) R13 is selected from the group consisting of (v), H, F, CI, Br, I, CN, (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, (C 1 -C 8 )alkoxy, and halo(C 1 -C 8 )alkoxy;
(n) each R14 is independently selected from the group consisting of H, (C1-C8)alkyl, (C 2 -C 8 )alkenyl, substituted (C 1 -C 8 )alkyl, halo(C 1 -C 8 )alkyl, substituted halo(C 1 -C 8 )alkyl), (C 1 -C 8 )alkoxy, cyclo(C 3 -C 6 )alkyl, aryl, substituted-aryl, (C 1 -C 8 )alkyl-aryl, (C 1 -C 8 )alkyl-(substituted-aryl), O—(C 1 -C 8 )alkyl-aryl, O—(C 1 -C 8 )alkyl-(substituted-aryl), heterocyclyl, substituted-heterocyclyl, (C 1 -C 8 )alkyl-heterocyclyl, (C 1 -C 8 )alkyl-(substituted-heterocyclyl), O—(C 1 -C 8 )alkyl-heterocyclyl, O—(C 1 -C 8 )alkyl-(substituted-heterocyclyl), N(R16)(R17), (C 1 -C 8 )alkyl-C(═O)N(R16)(R17), C(═O)(C 1 -C 8 )alkyl, C(═O)(halo(C 1 -C 8 )alkyl),C(═O)(C 3 -C 6 )cycloalkyl, (C 1 -C 8 )alkyl-C(═O)O(C 1 -C 8 )alkyl, C(═O)H.
wherein each said substituted (C 1 -C 8 )alkyl has one or more substituents selected from the group consisting of CN, and NO 2 ,

Assignees

• Dow Agrosciences Llc

Inventors

• Lo William C
• Hunter James E
• Watson Gerald B
• Patny Akshay
• Iyer Pravin S
• Boruwa Joshodeep

Classifications

• A61P33/14

  Ectoparasiticides, e.g. scabicides · CPC title

• A61P33/10

  Anthelmintics · CPC title

• A01N53/00

  Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof · CPC title

• C07C243/34

  to carbon atoms of a carbon skeleton further substituted by nitrogen atoms · CPC title

• C07D295/073

  with the ring nitrogen atoms and the substituents separated by carbocyclic rings or by carbon chains interrupted by carbocyclic rings · CPC title