Hydrocarbon conversion catalyst composition

Patent metadata

Field	Value
Publication number	US-10543479-B2
Application number	US-201113881070-A
Country	US
Kind code	B2
Filing date	Oct 20, 2011
Priority date	Oct 25, 2010
Publication date	Jan 28, 2020
Grant date	Jan 28, 2020

Abstract

A hydrocarbon conversion catalyst composition which comprises ZSM-48 and/or EU-2 zeolite particles and refractory oxide binder essentially free of alumina in which the average aluminium concentration of the ZSM-48 and/or EU-2 zeolite particles is at least 1.3 times the aluminium concentration at the surface of the particles, processes for preparing such catalyst compositions and processes for converting hydrocarbon feedstock with the help of such compositions.

First claim

What is claimed is:

1. A hydrocarbon conversion catalyst composition, which comprises: a dealuminated extrudate and a catalytic metal selected from the group consisting of platinum, palladium, and nickel; wherein said dealuminated extrudate includes an extrudate comprising ZSM-48 and/or EU-2 zeolite particles present in an amount to provide a zeolite content of said hydrocarbon conversion catalyst composition of at least 20 wt % and at most 70 wt % and silica binder that includes both silica sol and silica powder containing silica particles having a mean diameter between 10 μm and 200 μm, and wherein said ZSM-48 and/or EU-2 zeolite particles in said extrudate before its dealumination have a bulk silica-to-alumina molar ratio (SAR) of at least 150 and at most 210, and wherein said silica binder is essentially free of alumina; and wherein said extrudate is dried and calcined before its dealumination, wherein said extrudate is dealuminated after being dried and calcined to provide said dealuminated extrudate that is followed by incorporation of said catalytic metal into said dealuminated extrudate; and wherein the average aluminium concentration of the ZSM-48 and/or EU-2 zeolite particles is at least 1.1 times the aluminium concentration at the surface of the particles.

2. A hydrocarbon conversion catalyst composition according to claim 1 , wherein the zeolite content of the hydrocarbon conversion catalyst composition, on a dry basis, is in the range of from 25 to 65 wt %, as calculated on the total finished catalyst composition.

3. A hydrocarbon conversion catalyst composition according to claim 2 , wherein the average aluminium concentration of the ZSM-48 and/or EU-2 zeolite particles is at least 1.2 times the aluminium concentration at the surface of the particle.

4. A hydrocarbon conversion catalyst composition, according to claim 2 , wherein the zeolite content, on a dry basis, is of from 30 to 60 wt % as calculated on the total finished catalyst composition.

5. A hydrocarbon conversion catalyst composition according to claim 4 , further comprising zeolite ZSM-12, wherein the zeolite ZSM-12 content in the hydrocarbon conversion catalyst composition is an amount of at most 50% wt based on the ZSM-48 and/or EU-2 zeolite present in the hydrocarbon conversion catalyst composition, and wherein the average aluminum concentration of the ZSM-48 and/or EU-2 zeolite particles is at least 1.5 times the aluminium concentration at the surface of the particle.

6. A hydrocarbon conversion catalyst composition according to claim 5 , wherein the average aluminium concentration of the ZSM-48 and/or EU-2 zeolite particles is at least 2 times the aluminium concentration at the surface of the particle.

Assignees

• Domokos Laszlo
• Huve Laurent Georges
• Jongkind Hermanus
• Klazinga Aan Hendrik
• Rigutto Marcello Stefano
• Shell Oil Co

Inventors

• Domokos László
• Huve Laurent Georges
• Jongkind Hermanus
• Klazinga Aan Hendrik
• Rigutto Marcello Stefano

Classifications

• B01J2229/42

  Addition of matrix or binder particles · CPC title

• B01J2229/16

  to increase the Si/Al ratio; Dealumination · CPC title

• B01J2229/32

  Reaction with silicon compounds, e.g. TEOS, siliconfluoride · CPC title

• C10G45/64

  containing crystalline alumino-silicates, e.g. molecular sieves · CPC title

• C10G49/08

  containing crystalline alumino-silicates, e.g. molecular sieves · CPC title