Processes using molecular sieve SSZ-91

Patent metadata

Field	Value
Publication number	US-9920260-B2
Application number	US-201514837108-A
Country	US
Kind code	B2
Filing date	Aug 27, 2015
Priority date	Aug 27, 2015
Publication date	Mar 20, 2018
Grant date	Mar 20, 2018

Abstract

Uses for a family of new crystalline molecular sieves designated SSZ-91 are disclosed. Molecular sieve SSZ-91 is structurally similar to sieves falling within the ZSM-48 family of molecular sieves, and is characterized as: (1) having a low degree of faulting, (2) a low aspect ratio that inhibits hydrocracking as compared to conventional ZSM-48 materials having an aspect ratio of greater than 8, and (3) is substantially phase pure.

First claim

What is claimed is:

1. A process for converting hydrocarbons, comprising contacting a hydrocarbonaceous feed under hydrocarbon converting conditions with a catalyst comprising a molecular sieve, the molecular sieve belonging to the ZSM-48 family of zeolites, wherein the molecular sieve comprises:
a silicon oxide to aluminum oxide mole ratio of 40 to 200,
at least 70% polytype 6 of the total ZSM-48 family material present in the product, and
an additional EUO framework molecular sieve phase in an amount of between 0 and 3.5 percent by weight of the total product; and
wherein the molecular sieve has a morphology characterized as polycrystalline aggregates comprising crystallites collectively having an average aspect ratio of between 1 and 8.

2. The process of claim 1 , wherein the molecular sieve has, in its as-synthesized form, an X-ray diffraction pattern substantially as shown in the following Table:

2-Theta (a)
d-spacing (nm)
Relative Intensity (b)

 7.55 ± 0.20
1.170
W

 8.71 ± 0.20
1.015
W

12.49 ± 0.20
0.708
W

15.12 ± 0.20
0.586
W

21.18 ± 0.20
0.419
VS

22.82 ± 0.20
0.390
VS

24.62 ± 0.20
0.361
W

26.39 ± 0.20
0.337
W

29.03 ± 0.20
0.307
W

31.33 ± 0.20
0.285
 W.

3. The process of claim 1 , wherein the molecular sieve has a silicon oxide to aluminum oxide mole ratio of 70 to 160.

4. The process of claim 1 , wherein the molecular sieve has a silicon oxide to aluminum oxide mole ratio of 80 to 140.

5. The process of claim 1 , wherein the crystallites collectively have an average aspect ratio of between 1 and 5.

6. The process of claim 1 , wherein the molecular sieve comprises between 0.1 and 2 wt. % EU-1.

7. The process of claim 1 , wherein the molecular sieve comprises at least 80% polytype 6 of the total ZSM-48 family material present in the product.

8. The process of claim 7 , wherein the crystallites collectively have an average aspect ratio of between 1 and 5.

9. The process of claim 8 , wherein the molecular sieve comprises between 0.1 and 2 wt. % EU-1.

10. The process of claim 1 , wherein the molecular sieve comprises at least 90% polytype 6 of the total ZSM-48 family material present in the product.

11. The process of claim 10 , wherein the crystallites collectively have an average aspect ratio of between 1 and 5.

12. The process of claim 11 , wherein the molecular sieve comprises between 0.1 and 2 wt. % EU-1.

13. The process of claim 1 , wherein the crystallites collectively have an average aspect ratio of between 1 and 5.

14. The process of claim 13 , wherein the molecular sieve comprises at least 90% polytype 6 of the total ZSM-48 family material present in the product.

15. The process of claim 1 , wherein the crystallites collectively have an average aspect ratio of between 1 and 3.

16. The process of claim 1 , wherein the process is a process selected from the group consisting of hydrocracking, dewaxing, catalytic cracking, aromatics formation, isomerization, alkylation and transalkylation, conversion of paraffins to aromatics, isomerization of olefins, xylene isomerization, oligomerization, condensation of alcohols, methane upgrading and polymerization of 1-olefins.

17. The process of claim 16 , wherein the process is a dewaxing process comprising contacting the catalyst with a hydrocarbon feedstock under dewaxing conditions.

18. The process of claim 1 , wherein the process is a process for producing a C 20+ lube oil from a C 20+ olefin feed comprising isomerizing the olefin feed under isomerization conditions over the catalyst.

Assignees

• Chevron Usa Inc

Inventors

• Ojo Adeola Florence
• Xie Dan
• Zhang Yihua
• Lei Guan-Dao

Classifications

• C07C9/22

  with more than fifteen carbon atoms · CPC title

• B01J29/7446

  EUO-type, e.g. EU-1, TPZ-3 or ZSM-50 · CPC title

• C07C5/2737

  with crystalline alumino-silicates, e.g. molecular sieves · CPC title

• B01J29/80

  Mixtures of different zeolites · CPC title

• B01J29/7461

  MRE-type, e.g. ZSM-48 · CPC title