Urea finishing process with acid scrubbing

Patent metadata

Field	Value
Publication number	US-10486125-B2
Application number	US-201515526190-A
Country	US
Kind code	B2
Filing date	Aug 13, 2015
Priority date	Nov 12, 2014
Publication date	Nov 26, 2019
Grant date	Nov 26, 2019

Abstract

A process for the finishing of urea comprising: (a) removing water from an aqueous urea solution in a first evaporation and condensation section, obtaining a urea melt; (b) subjecting said urea melt to a finishing treatment comprising granulation and resulting in solid urea and air contaminated with urea dust and ammonia; (c) subjecting said contaminated air to acid scrubbing, producing an aqueous solution comprising urea and ammonium salts; (d) subjecting at least part of said aqueous solution to evaporation in a second evaporation section, obtaining a liquid stream comprising urea and ammonium salts and a gaseous stream; (e) condensing said gaseous stream in a second condensation section, obtaining a recycle aqueous stream; (f) using at least a part of said recycle aqueous stream for the scrubbing of contaminated air; (g) converting at least a portion of said liquid stream comprising urea and ammonium salts into solid particles, and (h) using said solid particles as seeds for the granulation; a corresponding urea plant and method of revamping a urea plant are also disclosed.

First claim

The invention claimed is:

1. A process for the finishing of urea comprising the steps of:
(a) removing water from an aqueous urea solution via evaporation and condensation in a first evaporation and condensation section, obtaining a urea melt;
(b) subjecting at least a first part of said urea melt to a finishing treatment comprising a step of granulation, said finishing treatment resulting in solid urea and contaminated air containing urea dust and ammonia;
(c) subjecting at least part of said contaminated air to a scrubbing treatment in at least one scrubbing unit, said treatment comprising an acid scrubbing treatment with water and an acid, and a dust scrubbing, said acid scrubbing treatment producing an aqueous solution comprising urea and ammonium salts;
(d) subjecting at least part of said aqueous solution comprising urea and ammonium salts to evaporation in a second evaporation section, obtaining a liquid stream comprising urea and ammonium salts and a gaseous stream;
(e) subjecting said gaseous stream to condensation in a second condensation section, obtaining a recycle aqueous stream,
(f) using at least a part of said recycle aqueous stream for the scrubbing of contaminated air of point c) above,
(g) converting at least a portion of said liquid stream comprising urea and ammonium salts into solid particles, and
(h) using said solid particles as seeds for said step of granulation.

2. The process according to claim 1 , wherein said step of granulation is carried out in a granulation unit and the formation of said solid particles of urea is carried out in at least one of a seeding section and a prilling tower, upstream said granulation unit and separate from said granulation unit.

3. The process according to claim 2 , wherein said at least part of urea melt is directly subjected to said step of granulation.

4. The process according to claim 3 , wherein a first part of urea melt is sent directly to said granulation unit, and a second part of urea melt is sent to said seeding section or prilling tower.

5. The process according to claim 4 , wherein said second part is not greater than 20% in weight of the urea melt.

6. The process according to claim 1 , wherein formation of at least part of said solid particles of urea is carried out in a prilling tower and said contaminated air stream comprises an air stream drawn off said granulation unit and cooling air drawn off said prilling tower, the air from the granulation unit and the air from the prilling tower being scrubbed in the same scrubbing unit or in in respective and separate scrubbing units.

7. The process according to claim 1 , process further comprising sending a first portion of said liquid stream comprising urea and ammonium salts to said at least one seeding section or prilling tower, and sending a second portion of said stream to said granulation unit.

8. The process according to claim 1 , the process further comprising entirely sending said liquid stream comprising urea and ammonium salts to said seeding section or prilling tower.

9. The process according to claim 1 , the process further comprising sending said aqueous solution comprising urea and ammonium salts directly to said second evaporation section from said scrubbing unit.

10. The process according to claim 1 , wherein acid scrubbing is carried out with an acid selected in the group of sulphuric acid, nitric acid and phosphoric acid.

11. An apparatus for the finishing of urea comprising:
(a) an evaporation and condensation section removing water from an aqueous urea solution and producing a urea melt;
(b) a finishing section comprising at least a granulation unit, and optionally a prilling tower upstream said granulation unit, and converting at least a first part of said urea melt in solid urea in the presence of air, and discharging a contaminated air containing urea dust and ammonia;
(c) at least one scrubbing unit for the scrubbing of said contaminated air, producing an aqueous solution;
(d) a second evaporation section receiving said aqueous solution comprising urea and ammonium salts, and producing a liquid stream comprising urea and ammonium salts, and a gaseous stream;
(e) a second condensation section receiving said gaseous stream and producing a recycle aqueous stream recycled back to said at least one scrubbing unit;
(f) at least one seeding unit or prilling tower wherein at least a portion of said liquid stream ( 14 ) comprising urea and ammonium salts is converted into solid particles;
(g) the plant also comprising a seeding line for introducing said solid particles into said granulation unit.

12. A method for revamping a urea plant, said plant comprising:
a synthesis section and a recovery section, producing aqueous urea solution;
an evaporation and condensation section removing water from said aqueous urea solution and producing a urea melt;
a finishing section converting at least a first part of said urea melt in solid urea and releasing a stream of contaminated air containing urea dust and ammonia, said finishing section comprising a granulation unit or a prilling tower;
a scrubbing section operating a dust scrubbing of said contaminated air stream;
said method being characterized in that:
modifying said scrubbing section to perform an acid scrubbing treatment besides said dust scrubbing, thus removing ammonia from said contaminated air and producing an aqueous solution comprising urea and ammonium salts;
adding a second evaporation section and a second condensation section to said plant;
arranging a liquid output line to carry at least part of said aqueous solution with urea and ammonium salts to said second evaporation section, so that said second evaporation section produces a liquid stream containing urea and ammonium salts and a gaseous stream comprising water vapour;
wherein said second condensation section is arranged to condense said gaseous stream from the second evaporation section, obtaining an aqueous stream, and providing a flow line to recycle said aqueous stream to said scrubbing section,
whereby the plant is modified so that at least part of said liquid stream containing urea and ammonium salts is converted into solid particles, and said solid particles are directed to said granulation unit of the plant, or a new granulation unit installed downstream of said prilling tower and acting as a fattener of the solid prills produced by said prilling tower.

13. The method according to claim 12 , wherein:
the plant originally comprises a granulation unit;
adding a seeding section to said plant;
conversion of said liquid stream containing urea and ammonium salts into solid particles is carried out in said seeding section.

14. The method according to claim 12 , wherein:
the plant originally comprises a prilling tower;
adding a granulation unit downstream of the existing prilling tower;
conversion of said liquid stream containing urea and ammonium salts into solid particles is carried out in said prilling tower.

15. The method according to claim 14 , the method further comprising:
increasing the flowrate of the urea melt by revamping the synthesis section and/or the recovery section of the urea plant;
sending a first portion of the urea melt to the prilling tower and sending a second portion to the newly installed granulation unit.

16. The method according to claim 14 , the method further comprising adding a seeding section to said plant, said seeding section being arranged to receive at least part of said liquid stream containing urea and ammonium salts and to convert it into solid particles.

Assignees

• Casale Sa

Inventors

• Scotto Andrea
• Bertini Paolo

Classifications

• B01D2258/06

  Polluted air · CPC title

• B01J2/003 Primary

  followed by coating of the granules (to prevent the granules sticking together B01J2/30) · CPC title

• C07C273/16 Primary

  Separation; Purification · CPC title

• B01D53/14

  by absorption · CPC title

• B01D47/02

  by passing the gas or air or vapour over or through a liquid bath · CPC title